Chemistry for Today: General Organic and Biochemistry
9th Edition
ISBN: 9781337514576
Author: Seager
Publisher: Cengage
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Chapter 25, Problem 25.29E
Hemoglobin
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Which of the following is the reaction that occurs when a small amount of strong acid, H+, is added to a CH3COOH/NaCH3COO buffer solution?
CH3COO− + OH− → CH3COOH + O2−
H+ + CH3COOH → CH3COOH2+
CH3COOH + OH− → H2O + CH3COO−
H+ + Na+ → NaH2+
H+ + CH3COO− → CH3COOH
Classify each of the following substances as either a strong or weak acid, strong or weak base, or a soluble or insoluble salt.
Cal2
Hclo
HNO2
NaOH
NH3
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strong acid
weak acid
strong base
weak base
soluble salt
insoluble salt
The Ka of formic acid (HCO2H) is 1.8x10-4. What would the pH of a solution containing equal concentrations of formic acid and sodium formate be? Use the H-H equation for buffers to solve this. This is true in general for solutions where the acid and conjugate base are present in equal concentrations.
Chapter 25 Solutions
Chemistry for Today: General Organic and Biochemistry
Ch. 25 - Prob. 25.1ECh. 25 - Prob. 25.2ECh. 25 - Prob. 25.3ECh. 25 - Prob. 25.4ECh. 25 - Prob. 25.5ECh. 25 - What is the principal anion found in the...Ch. 25 - Prob. 25.7ECh. 25 - Prob. 25.8ECh. 25 - Prob. 25.9ECh. 25 - Prob. 25.10E
Ch. 25 - What term is given to the reversible flow of...Ch. 25 - Prob. 25.12ECh. 25 - Prob. 25.13ECh. 25 - Prob. 25.14ECh. 25 - Prob. 25.15ECh. 25 - Prob. 25.16ECh. 25 - Prob. 25.17ECh. 25 - Prob. 25.18ECh. 25 - Prob. 25.19ECh. 25 - Prob. 25.20ECh. 25 - Prob. 25.21ECh. 25 - Prob. 25.22ECh. 25 - Prob. 25.23ECh. 25 - Prob. 25.24ECh. 25 - Prob. 25.25ECh. 25 - Prob. 25.26ECh. 25 - Prob. 25.27ECh. 25 - Prob. 25.28ECh. 25 - Hemoglobin (HHb) is a weak acid that forms the Hb...Ch. 25 - Prob. 25.30ECh. 25 - Prob. 25.31ECh. 25 - Prob. 25.32ECh. 25 - Prob. 25.33ECh. 25 - Prob. 25.34ECh. 25 - Prob. 25.35ECh. 25 - What ionic shift maintains electron charge balance...Ch. 25 - Prob. 25.37ECh. 25 - Prob. 25.38ECh. 25 - Prob. 25.39ECh. 25 - Prob. 25.40ECh. 25 - Prob. 25.41ECh. 25 - Prob. 25.42ECh. 25 - Prob. 25.43ECh. 25 - Prob. 25.44ECh. 25 - Prob. 25.45ECh. 25 - Prob. 25.46ECh. 25 - Prob. 25.47ECh. 25 - Prob. 25.48ECh. 25 - Prob. 25.49ECh. 25 - Prob. 25.50ECh. 25 - Prob. 25.51ECh. 25 - Prob. 25.52ECh. 25 - Prob. 25.53ECh. 25 - Explain how uncontrolled diarrhea can lead to...Ch. 25 - Prob. 25.55ECh. 25 - Prob. 25.56ECh. 25 - Prob. 25.57ECh. 25 - Prob. 25.58ECh. 25 - Prob. 25.59ECh. 25 - The liquid portion of the blood is called: a....Ch. 25 - Prob. 25.61ECh. 25 - Prob. 25.62ECh. 25 - The hormone most responsible for the renal...Ch. 25 - Prob. 25.64ECh. 25 - Prob. 25.65E
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- Write a chemical equation to describe the proton transfer that occurs when each of these acids is added to water. (a) HCO3 (b) HCl (c) CH3COOH (d) HCNarrow_forwardMethyl orange, HMO, is a common acid-base indicator. In solution it ionizes according to the equation: HMOaqH+aq+MO-aqredyellow If methyl orange is added to distilled water, the solution turns yellow. If 1 drop or two of 6 M HCl is added to the yellow solution, it turns red. If to that solution one adds a few drops of 6 M NaOH, the color reverts to yellow. a. Why does adding 6 M HCl to the yellow solution of methyl orange tend to cause the color to change to red? Note that in solution HCl exists as H+ and Cl- ions. b. Why does adding 6 M NaOH to the red solution tend to make it turn back to yellow? Note that in solution NaOH exists as Na+ and OH- ions. How does increasing OH- shift Reaction 3 in the discussion section? How would the resulting change in H+ affect the dissociation reaction of HMO?arrow_forwardWrite an equation for each of the following buffering actions. a. the response of a HPO42/PO43 buffer to the addition of OH ions b. the response of a HF/F buffer to the addition of OH ions c. the response of a HCN/CN buffer to the addition of H3O+ ions d. the response of a H3PO4/H2PO4 buffer to the addition of H3O+ ionsarrow_forward
- Identify the buffer system(s)the conjugate acidbase pair(s)present in a solution that contains equal molar amounts of the following: a. HF, KC2H3O2, NaC2H3O2, and NaF b. HNO3, NaOH, H3PO4, and NaH2PO4arrow_forwardBriefly describe how a buffer solution can control the pH of a solution when strong acid is added and when strong base is added. Use NH3/NH4Cl as an example of a buffer and HCl and NaOH as the strong acid and strong base.arrow_forwardAn aqueous solution contains formic acid and formate ion. Determine the direction in which the pH will change if each of the following chemicals is added to the solution. (a) HCl (b) NaHSO4 (c) CH3COONa (d) KBr (e) H2Oarrow_forward
- Identify each pair that could form a buffer. (a) HCl and CH3COOH (b) NaH2PO4 and Na2HPO4 (c) H2CO3 and NaHCO3arrow_forwardEstimate the pH that results when the following two solutions are mixed. a) 50 mL of 0.3 M CH3COOH and 50 mL of 0.4 M KOH b) 100 mL of 0.3 M CH3COOH and 50 mL of 0.4 M NaOH c) 150 mL of 0.3 M CH3COOH and 100 mL of 0.3 M Ba(OH)2 d) 200 mL of 0.3 M CH3COOH and 100 mL of 0.3 M Ba(OH)2arrow_forwardUse the same symbols as in Question 61 ( = anion, =OH) for the box below. (a) Fill in a similar box (representing one liter of the same solution) after 2 mol of H+ (2) have been added. Indicate whether the resulting solution is an acid, base, or buffer. (b) Follow the directions of part (a) for the resulting solution after 2 mol of OH- (2 ) have been added. (c) Follow the directions of part (a) for the resulting solution after 5 mol of OH- (5 ) have been added. (Hint: Write the equation for the reaction before you draw the results.)arrow_forward
- Calculate the pH of each of the following solutions. (a) 10.0 mL of 0.300 M hydrofluoric acid plus 30.0 mL of 0.100 M sodium hydroxide (b) 100.0 mL of 0.250 M ammonia plus 50.0 mL of 0.100 M hydrochloric acid (c) 25.0 mL of 0.200 M sulfuric acid plus 50.0 mL of 0.400 M sodium hydroxidearrow_forwardUsing the diagrams shown in Problem 10-117, which of the solutions would have the greatest buffer capacity, that is, greatest protection against pH change, when the following occurs? a. A strong acid is added to the solution. b. A strong base is added to the solution.arrow_forwardWrite the chemical equation and the expression for the equilibrium constant, and calculate Kb for the reaction of each of the following ions as a base. (a) sulfate ion (b) citrate ionarrow_forward
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