Among the given amines , the amine which cannot be prepared by reduction of an amide is to be deteremined. Concept Introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

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Answer 1

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Chapter 25, Problem 25.12P

Interpretation Introduction

Interpretation: Among the given amines, the amine which cannot be prepared by reduction of an amide is to be deteremined.

Concept Introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

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What amide(s) can be used to prepare each amine by reduction?

In general, amines are nucleophilic due to: Select one: a. Existence of negative charge in amine group b. Amines are more electronegative than other functional groups C. Lone pairs in the amine group available for donation d. None of the above

What amine is formed by reduction of each amide?

Answer 2

Question

Chapter 25, Problem 25.12P

Interpretation Introduction

Interpretation: Among the given amines, the amine which cannot be prepared by reduction of an amide is to be deteremined.

Concept Introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

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Answer 3

Question

Chapter 25, Problem 25.12P

Interpretation Introduction

Interpretation: Among the given amines, the amine which cannot be prepared by reduction of an amide is to be deteremined.

Concept Introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

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Answer 4

Question

Chapter 25, Problem 25.12P

Interpretation Introduction

Interpretation: Among the given amines, the amine which cannot be prepared by reduction of an amide is to be deteremined.

Concept Introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

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Answer 5

Chapter 25, Problem 25.12P

Interpretation Introduction

Interpretation: Among the given amines, the amine which cannot be prepared by reduction of an amide is to be deteremined.

Concept Introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Answer 6

Chapter 25, Problem 25.12P

Interpretation Introduction

Interpretation: Among the given amines, the amine which cannot be prepared by reduction of an amide is to be deteremined.

Concept Introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Answer 7

Chapter 25, Problem 25.12P

Interpretation Introduction

Interpretation: Among the given amines, the amine which cannot be prepared by reduction of an amide is to be deteremined.

Concept Introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Answer 8

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Answer 10

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Answer 11

Ch. 25 - Prob. 25.1P Ch. 25 - Prob. 25.2P Ch. 25 - Prob. 25.3P Ch. 25 - Prob. 25.4P Ch. 25 - Prob. 25.5P Ch. 25 - Prob. 25.6P Ch. 25 - Problem 25.7 Draw the product of each...Ch. 25 - Prob. 25.8P Ch. 25 - Prob. 25.9P Ch. 25 - Prob. 25.10P

Solution Summary: The author explains that nitro compounds, nitriles, and amides can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid.

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