Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 2.5, Problem 2.11P
Draw a chair conformation of 1,4-dimethylcyclohexane in which one methyl group is equatorial and the other is axial. Draw the alternative chair conformation and calculate the ratio of the two conformations at 25°C.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
4.
a) Give a suitable rationale for the following cyclization, stating the type of process involved
(e.g. 9-endo-dig), clearly showing the mechanistic details at each step.
H
CO₂Me
1) NaOMe
2) H3O®
CO₂Me
2. Platinum and other group 10 metals often act as solid phase hydrogenation catalysts for
unsaturated hydrocarbons such as propylene, CH3CHCH2. In order for the reaction to be
catalyzed the propylene molecules must first adsorb onto the surface. In order to completely
cover the surface of a piece of platinum that has an area of 1.50 cm² with propylene, a total
of 3.45 x 10¹7 molecules are needed. Determine the mass of the propylene molecules that
have been absorbed onto the platinum surface.
Chem 141, Dr. Haefner
2. (a) Many main group oxides form acidic solutions when added to water. For example solid
tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced
chemical equation for this reaction.
(b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures
to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-)
and carbon monoxide. Write a balanced chemical equation for this reaction.
Chapter 2 Solutions
Organic Chemistry
Ch. 2.2 - Do the line-angle formulas in each pair represent...Ch. 2.2 - Draw line-angle formulas for the three...Ch. 2.3 - Write IUPAC names for these alkanes.Ch. 2.4 - Combine the proper prefix, infix, and suffix and...Ch. 2.4 - Write the molecular formula, IUPAC name, and...Ch. 2.4 - Write molecular formulas for each bicycloalkane,...Ch. 2.4 - Prob. 2.7PCh. 2.5 - For 1,2-dichloroethane: (a) Draw Newman...Ch. 2.5 - Following is a chair conformation of cyclohexane...Ch. 2.5 - Draw the alternative chair conformation for the...
Ch. 2.5 - Draw a chair conformation of...Ch. 2.6 - Which cycloalkanes show cis, trans isomerism? For...Ch. 2.6 - Following is a planar hexagon representation for...Ch. 2.6 - Here is one cis,trans isomer of...Ch. 2.6 - Prob. AQCh. 2.6 - Prob. BQCh. 2.6 - Prob. CQCh. 2.7 - Arrange the alkanes in each set in order of...Ch. 2 - Write a line-angle formula for each condensed...Ch. 2 - Write the molecular formula of each alkane.Ch. 2 - Using parentheses and subscripts, provide an even...Ch. 2 - Which statements are true about constitutional...Ch. 2 - Prob. 2.20PCh. 2 - Each member of the following set of compounds is...Ch. 2 - Each of the following compounds is an amine...Ch. 2 - Each of the following compounds is either an...Ch. 2 - Draw structural formulas and write IUPAC names for...Ch. 2 - Draw structural formulas for all of the following....Ch. 2 - Write IUPAC names for these alkanes and...Ch. 2 - Write structural formulas and line-angle formulas...Ch. 2 - Explain why each is an incorrect IUPAC name and...Ch. 2 - For each IUPAC name, draw the corresponding...Ch. 2 - Write the IUPAC name for each compound.Ch. 2 - Prob. 2.31PCh. 2 - Torsional strain resulting from eclipsed CH bonds...Ch. 2 - How many different staggered conformations are...Ch. 2 - Consider 1-bromopropane, CH3CH2CH2Br. (a) Draw a...Ch. 2 - Consider 1-bromo-2-methylpropane and draw the...Ch. 2 - trans-1,4-Di-tert-butylcyclohexane exists in a...Ch. 2 - From studies of the dipole moment of...Ch. 2 - Prob. 2.38PCh. 2 - Following are the alternative chair conformations...Ch. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Draw line-angle formulas for the cis and trans...Ch. 2 - Name and draw structural formulas for all...Ch. 2 - Using a planar pentagon representation for the...Ch. 2 - Gibbs free energy differences between...Ch. 2 - Prob. 2.46PCh. 2 - Calculate the difference in Gibbs free energy in...Ch. 2 - Draw the alternative chair conformations for the...Ch. 2 - Use your answers from Problem 2.48 to complete the...Ch. 2 - There are four cis,trans isomers of...Ch. 2 - Draw alternative chair conformations for each...Ch. 2 - 1,2,3,4,5,6-Hexachlorocyclohexane shows cis,trans...Ch. 2 - Prob. 2.53PCh. 2 - What generalization can you make about the...Ch. 2 - What unbranched alkane has about the same boiling...Ch. 2 - Complete and balance the following combustion...Ch. 2 - Following are heats of combustion per mole for...Ch. 2 - Following are structural formulas and heats of...Ch. 2 - Without consulting tables, arrange these compounds...Ch. 2 - Which would you predict to have the larger (more...Ch. 2 - Following are structural formulas for 1,4-dioxane...Ch. 2 - Following is a planar hexagon representation of...Ch. 2 - On the left is a stereorepresentation of glucose...Ch. 2 - Prob. 2.64PCh. 2 - Prob. 2.65P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Problem Set 4a Chem 1411. A latex balloon is filled with a total of carbon dioxide gas so that its volume reaches 1.352 L. The balloon whose weight was originally 0.753 g, now weighs 2.538 g. How many molecules of carbon dioxide have been added to the balloon?arrow_forwardQ18. 30 minutes left please help!!arrow_forwardQ35. Please help wth these drawings! I only have an hour left!!arrow_forward
- Briefly indicate and with examples the differences between metallic cluster and cage compound.arrow_forwardIndicate the correct answer.a) In boranes, the B-B bonds are the most reactive.b) The B-H-B bonds are the reactive centers in the B2H6 molecule.arrow_forwardIn boranes, the B-B bonds are the most reactive.arrow_forward
- The B-H-B bonds are the reactive centers in the B2H6 molecule. Correct?arrow_forwardPlease help me choose! {Apparently B is wrong}arrow_forward13) Which of the following configurations corresponds to the structure below? С соон SH Br 8H H CHBrCH3 a) (2S, 3S) (2S, 3R) c) (2R,3S) d) (2R, 3R)arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License