Concept explainers
Interpretation:
The molecular formula of the given bicycloalkanes has to be written and among the bicycloalkanes the constitutional isomers has to be identified.
Concept Introduction:
Bicycloalkanes:
Bicycloalkanes are
The general formula of a bicycloalkane is
Constitutional isomers:
Constitutional isomers compounds having same molecular formula but differ in structural formulas. These isomers differ in the connectivity of their atoms in the chain or in the kind of bonds they have (single bond, double bond or triple bond).
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Chapter 2 Solutions
Organic Chemistry
- Summarize the nomenclature rules for alkanes, alkenes, alkynes, and aromatic compounds. Correct the following false statements regarding nomenclature of hydrocarbons. a. The root name for a hydrocarbon is based on the shortest continuous chain of carbon atoms. b. The suffix used to name all hydrocarbons is -ane. c. Substituent groups are numbered so as to give the largest numbers possible. d. No number is required to indicate the positions of double or triple bonds in alkenes and alkynes. e. Substituent groups get the lowest number possible in alkenes and alkynes. f. The ortho- term in aromatic hydrocarbons indicates the presence of two substituent groups bonded to carbon- 1 and carbon-3 in benzene.arrow_forwardDistinguish between isomerism and resonance. Distinguish between structural and geometric isomerism. When writing the various structural isomers, the most difficult task is identifying which are different isomers and which are identical to a previously written structurethat is, which are compounds that differ only by the rotation of a carbon single bond. How do you distinguish between structural isomers and those that are identical? Alkenes and cycloalkanes are structural isomers of each other. Give an example of each using C4H8. Another common feature of alkenes and cycloalkanes is that both have restricted rotation about one or more bonds in the compound, so both can exhibit cis- trans isomerism. What is required for an alkene or cycloalkane to exhibit cis-trans isomerism? Explain the difference between cis and trans isomers. Alcohols and ethers are structural isomers of each other, as are aldehydes and ketones. Give an example of each to illustrate. Which functional group in Table 21-4 can be structural isomers of carboxylic acids? What is optical isomerism? What do you look for to determine whether an organic compound exhibits optical isomerism? 1-Bromo-1-chloroethane is optically active whereas 1-bromo-2-chloroethane is not optically active. Explain.arrow_forwardWhat is the difference in bonding and in general molecular formula between an alkene and a cycloalkane with the same number of carbon atoms?arrow_forward
- Which of the following cycloalkanes could show geometric isomerism? For each that could, draw structural formulas, and name both the cis- and the trans- isomers. a. c. b. d.arrow_forwardname and draw structural formulas for all cyclo-alkanes with the molecular formula C5H10. Be certain to include cis-trans isomers, as well as constitutional isomersarrow_forwardWrite Lewis structures and IUPAC names for all isomers of C4H9Cl.arrow_forward
- Determine whether the following formula is exclusive for aliphatic alkanes, exclusive for cycloalkanes or can be either of them or it can also be neither of them. Consider the the possibility of isomerism. C7H14 C6H14 C7H15 C6H12 C8H16 C5H12 C2H6 C2H4 C4H9 C3H8arrow_forwardDraw skeletal structures for the cyclopropane (three-membered ring) isomers with a formula of C₅H₁₀. Note: cyclopropane is a carbon-carbon ring with three carbons. Three isomersarrow_forward1. a. Draw and name the five cycloalkane structures of formula C5H10. Can any of these structures give rise to geometric (cis-trans) isomerism? If so, show the cis and trans stereoisomers. b. Draw and name the eight cycloalkane structures of formula C6H12 that do not show geometric isomerism. c. Draw and name the four cycloalkanes of formula C6H12 that do have cis-trans isomers. 2. Each of the following descriptions applies to more than one alkane. In each case, draw and name two structures that match the description. (a) an isopropylheptane (b) a diethyldecane (c) a cis-diethylcyclohexane (d) a trans-dihalocyclopentane (e) a (2,3-dimethylpentyl)cycloalkane (f) a bicyclononane 3. 2. refer to the photo attached and answer the ff.3-33, 3-34arrow_forward
- Natural gas and petroleum deposits make up the world’s largest source of alkanes. Refinement of petroleum followed by distillation produces fuels for vehicles where the fuels undergo combustion. However, not all fuels are judged as “good fuel”, some are “poor fuel”. Hence, the “octane number” was developed to determine the type of fuel. Why is the straight-chain alkane octane considered as poor fuel with an octane number = 0 and a branched-chain alkane 2,2,4-Trimethylpentane with an octane number = 100?arrow_forwardidentify each functional group in the molecules shownarrow_forwardDraw the condensed or line-angle structure for an alkene with the formula C5H10. Name 6 Structural isomers of C5H10. They should three alkene and two cycloalkanearrow_forward
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