Organic Chemistry, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134074580
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Textbook Question
Chapter 24.5, Problem 5P
Why does the OH group add to the β-carbon rather than to the α-carbon in the second reaction in the β-oxidation of fats? (Hint: See Section 16.15.)
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Chapter 24 Solutions
Organic Chemistry, Books a la Carte Edition (8th Edition)
Ch. 24.3 - Prob. 2PCh. 24.5 - Prob. 3PCh. 24.5 - Prob. 4PCh. 24.5 - Why does the OH group add to the -carbon rather...Ch. 24.5 - Prob. 6PCh. 24.5 - How many molecules of NADH are formed from the...Ch. 24.6 - Prob. 8PCh. 24.6 - The oxidation of glyceraldehyde-3-phosphate to...Ch. 24.6 - Prob. 10PCh. 24.7 - Prob. 11P
Ch. 24.7 - Prob. 12PCh. 24.7 - Prob. 13PCh. 24.7 - Propose a mechanism for the reduction of...Ch. 24.8 - Prob. 15PCh. 24.9 - Acid-catalyzed dehydration reactions are normally...Ch. 24.9 - Prob. 17PCh. 24.9 - Prob. 18PCh. 24.9 - Acid-catalyzed dehydration reactions are normally...Ch. 24.9 - Prob. 20PCh. 24.9 - Prob. 21PCh. 24.10 - Prob. 22PCh. 24.12 - a. What is the name of the enzyme that converts...Ch. 24.14 - Prob. 24PCh. 24 - Prob. 25PCh. 24 - Prob. 26PCh. 24 - Prob. 27PCh. 24 - S-Adenosylmethionine (SAM) is formed from the...Ch. 24 - Prob. 29PCh. 24 - Prob. 30PCh. 24 - Prob. 31PCh. 24 - Prob. 32PCh. 24 - Prob. 33PCh. 24 - Prob. 34PCh. 24 - Prob. 35PCh. 24 - Prob. 36PCh. 24 - Prob. 37PCh. 24 - Prob. 38PCh. 24 - Prob. 39PCh. 24 - Prob. 40PCh. 24 - Prob. 41PCh. 24 - Prob. 42PCh. 24 - Prob. 43PCh. 24 - Prob. 44PCh. 24 - Prob. 45PCh. 24 - Prob. 46PCh. 24 - Prob. 47PCh. 24 - Prob. 48PCh. 24 - Prob. 49PCh. 24 - Prob. 50PCh. 24 - Prob. 51PCh. 24 - UDP-galactose-4-epimerase converts UDP-galactose...Ch. 24 - A student is trying to determine the mechanism for...Ch. 24 - What would be the results of the experiment in...
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- What are the similarities between β oxidations of heptadecanoic acids (C 17:0), and cis-Δ9-heptadencanoic acids (C 17:1).arrow_forwardExplain the mechanism (step-by-step) for the synthesis of aspirinarrow_forwardYou are given 150 mL of an oil made up of a mixture of 3 fatty acids: palmitoleic acid (C 16:1 (n-7)) erucic acid (C 22:1 (n-9)) stearidonic acid (C 18:4 (n-3)) You know that the 150 mL sample of this oil was prepared by adding 60 mL of palmitoleic acid to 90 mL of a mixture of erucic acid and stearidonic acid. Using a hydrometer you carefully measure the density of the 150 mL sample of oil and your analysis indicates that it has a density of 0.900 g/cm3. The densities of the individual fatty acids are: palmitoleic acid = 0.894 g/cm3 erucic acid = 0.860 g/cm3 stearidonic acid = 0.9334 g/cm3 Can you determine the volumes (in mL) of erucic acid and stearidonic acid in the total volume (150 mL) of the oil mixture?arrow_forward
- Why does the OH group add to the b-carbon rather than to the α-carbon in the second reaction in the β-oxidation of fats?arrow_forward2arrow_forwardRefer to the structure 1. The metabolic pathway is an example of a. Oxidative dealkylation b. Reduction c. Oxidative deamination d. Hydrolysis 2. This pathway is true for what kind of drugs a. Endogenous amides b. Endogenous amines c. Radical species d. Endogenous amino acidsarrow_forward
- The number of ATP molecules consumed and produced during glycolysis under anaerobic conditions are summarized in the following diagram (the ATP hydrolysis and synthesis reactions are shown in green). Phosphate Carbon atom 2 ATP 2 ADP ●●●●●● Glucose I Energy-Investing Phase O 2 ATP O 6 ATP O 1 ATP 8 ATP NADH + NAD* +H* O 4 ATP ●●●● 2 ADP 2 ATP NADH + NAD +H Based on the diagram above, for each glucose molecule broken down, what is the net energy yield of glycolysis in terms of ATP under anaerobic conditions? Pyruvate 2 ADP 2 ATP ●●●●● Energy-Generating Phase Pyruvatearrow_forwardWhy does the OH group add to the beta-carbon rather than to the alpha-carbon in the second reaction in the beta-oxidation of fats?arrow_forward19-46 In a dietary context, classify each of the following fatty acids as an essential fatty acid or as a nonessential fatty acid. a. Stearic acid (18:0) b. Linolenic acid (18:3) c. Oleic acid (18:1) d. Arachidic acid (20:0) 10 /7 Earrow_forward
- 2 A reaction is completed on oleic acid that removes its double bond and saturates its fatty acid chain to become completely saturated. What is true about the product? a) The melting point of the product will be greater than that of the starting material. Ob) The intermolecular forces between molecules of the product will be less than those between molecules of starting material. c) The number of kinks in the fatty acid chain will increase.arrow_forwardTruo or falsarrow_forwardAlbert Szent-Gyorgi, a pioneer in early pho-tosynthesis research, stated, “What drives life is a little electric current, kept up by the sunshine.” What did he mean by this?arrow_forward
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