Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 24.3, Problem 24.3CYU
Interpretation Introduction

Interpretation:

The sequence of amino acids encoded by the DNA sequence TTG TGC TTT has to be determined.

Concept introduction: The nucelotide triplet that encodes an amino acids is called codon. Each group of three nucleotides encodes one amino acid. There are 20 amino acid present which are encoded by differnet codon. DNA sequence is always synthesized in 5' to 3' direction. The information present in DNA is transcribe into mRNA then translated by tRNA into desired sequence.

The rule of base pairing are: A purine base Adenine (A) always pair with pyrimidine base Thymine (T) and the pyrimidine base Cytosine (C) always pair with purine base Guanine (G). The complementary strand of DNA synthesized in 3' to 5' direction.

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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z) is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra are provided. Draw the structure of the product as the resonance contributor lacking any formal charges. 13C NMR DEPT 90 200 160 120 80 40 0 200 160 120 80 40 0 DEPT 135 T 200 160 120 80 40 0 Draw the unknown amide. Select Dow Templates More Frage

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