Chemistry the Central Science 13th Edition Custom for Lamar University
13th Edition
ISBN: 9781269962667
Author: Theodore L. Brown, H. Eugene LeMay Jr., Bruce E. Bursten, Batherine J. Murphy, Patrick M. Woodward, Matthew W. Stoltzfus
Publisher: Pearson Learning Center
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Chapter 24, Problem 40E
In each pair, choose the compound that gives the more acidic (or less basic) solution:
- HBr, HF;
- PH3, H2S;
- HNO2, HNO3;
- H2SO3, H2SeO3.
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Students have asked these similar questions
5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 24 Solutions
Chemistry the Central Science 13th Edition Custom for Lamar University
Ch. 24.2 - Prob. 24.1.1PECh. 24.2 - The equilibrium constant Kc for C(s) +CO2 2CO(g)...Ch. 24.2 - Prob. 24.2.1PECh. 24.2 - Le Chatelier noted that many industrial processes...Ch. 24.3 - Prob. 24.3.1PECh. 24.3 - Prob. 24.3.2PECh. 24.3 - [15.91] An equilibrium mixture of H2, I2, and HI...Ch. 24.3 - Consider the hypothetical reaction A(g) + 2B(g) 2...Ch. 24.3 - Prob. 24.5.1PECh. 24.3 - Prob. 24.5.2PE
Ch. 24.4 - Prob. 24.6.1PECh. 24.4 - The following equilibria were measured at 823 K:...Ch. 24.7 - Prob. 24.7.1PECh. 24.7 - Prob. 24.7.2PECh. 24.7 - At 800 K, the equilibrium constant for the...Ch. 24.7 - Prob. 24.8.2PECh. 24 - Practice Exercise 1 A solution at 25° C has pOH =...Ch. 24 - Prob. 1ECh. 24 - Prob. 2ECh. 24 - Practice Exercise 2 Predict whether the...Ch. 24 - Prob. 4ECh. 24 - Prob. 5ECh. 24 - Prob. 6ECh. 24 - Prob. 7ECh. 24 - Prob. 8ECh. 24 - Prob. 9ECh. 24 - Prob. 10ECh. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - Practice Exercise 2 For each reaction, use Figure...Ch. 24 - Practice Exercise 1 In a certain acidic solution...Ch. 24 - Prob. 15ECh. 24 - Prob. 16ECh. 24 - Prob. 17ECh. 24 - Practice Exercise 1 A solution at 250C has [OH-] =...Ch. 24 - Practice Exercise 2 In a sample of lemon juice,...Ch. 24 - Prob. 20ECh. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Practice Exercise 2 Niacin, one of the B vitamins,...Ch. 24 - Prob. 25ECh. 24 - Practice Exercise 2 A 0.020 M solution of niacin...Ch. 24 - Practice Exercise 1 What is the pH of a 0.40 M...Ch. 24 - Practice Exercise 2 The Ka for niacin (Sample...Ch. 24 - Prob. 29ECh. 24 - Practice Exercise 2 Calculate the pH of a 0.020 M...Ch. 24 - Prob. 31ECh. 24 - Practice Exercise 2 Which of the following...Ch. 24 - Prob. 33ECh. 24 - Practice Exercise 2 What is the morality of an...Ch. 24 - Practice Exercise 1 By using information from...Ch. 24 - Practice Exercise 2 Based on information in...Ch. 24 - Prob. 37ECh. 24 - Prob. 38ECh. 24 - Practice Exercise 1 How many of the following...Ch. 24 - In each pair, choose the compound that gives the...Ch. 24 - Prob. 41ECh. 24 - a. Identify the Br ted-Lowry acid and base in the...Ch. 24 - Prob. 43ECh. 24 - Prob. 44ECh. 24 - Prob. 45ECh. 24 - 16.5 The following diagrams represent aqueous...Ch. 24 - Prob. 47ECh. 24 - Which of these statements about how the percent...Ch. 24 - 16.8 Each of the three molecules shown here...Ch. 24 - Prob. 50ECh. 24 - Prob. 51ECh. 24 - Prob. 52ECh. 24 - 16.14 Which of the following statements is...Ch. 24 - Prob. 54ECh. 24 - Prob. 55ECh. 24 - Identify the Bronsted-Lowry acid and the...Ch. 24 - Prob. 57ECh. 24 - Prob. 58ECh. 24 - Prob. 59ECh. 24 - Prob. 60ECh. 24 - Prob. 61ECh. 24 - Prob. 62ECh. 24 - Prob. 63ECh. 24 - Prob. 64ECh. 24 - Prob. 65ECh. 24 - 16.29 Calcualte [H +] for each of the following...Ch. 24 - Prob. 67ECh. 24 - 16.31 At the freezing point of water (0 o C), K10...Ch. 24 - Prob. 69ECh. 24 - 16.35 Complete the following table by calculating...Ch. 24 - Prob. 71ECh. 24 - Prob. 72ECh. 24 - 16.38 Carbon dioxide in the atmosphere dissolves...Ch. 24 - Prob. 74ECh. 24 - Prob. 75ECh. 24 - Prob. 76ECh. 24 - Prob. 77ECh. 24 - Prob. 78ECh. 24 - Prob. 79ECh. 24 - Prob. 80ECh. 24 - Prob. 81AECh. 24 - Prob. 82AECh. 24 - write the chemical equation and the Ka expression...Ch. 24 - Prob. 84AECh. 24 - Prob. 85AECh. 24 - Prob. 86AECh. 24 - Prob. 87AECh. 24 - Prob. 88AECh. 24 - Prob. 89AECh. 24 - Prob. 90AECh. 24 - Prob. 91AECh. 24 - Prob. 92AECh. 24 - Prob. 93AECh. 24 - Calculate the percent ionization of hydrazoic acid...Ch. 24 - Prob. 95IECh. 24 - Prob. 96IECh. 24 - Prob. 97IECh. 24 - Prob. 98IECh. 24 - 16.68 The hypochlorite ion, CIO- , acts as a weak...Ch. 24 - Prob. 100IECh. 24 - Practice Exercise 1 Consider the following...Ch. 24 - Prob. 102IE
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