
Loose Leaf for Chemistry: The Molecular Nature of Matter and Change
8th Edition
ISBN: 9781260151749
Author: Silberberg Dr., Martin; Amateis Professor, Patricia
Publisher: McGraw-Hill Education
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Question
Chapter 24, Problem 24.95P
Interpretation Introduction
Interpretation:
Time period of the campfire burning has to be determined using the given information.
Concept Introduction:
Radioactive decay is a first order reaction.
Decay rate can be calculated using the given equation as follows,
The half–life period for first order reaction is as follows:
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 24 Solutions
Loose Leaf for Chemistry: The Molecular Nature of Matter and Change
Ch. 24.1 - Prob. 24.1AFPCh. 24.1 - Prob. 24.1BFPCh. 24.1 - Prob. 24.2AFPCh. 24.1 - Why is stable but unstable?
Ch. 24.1 - Prob. 24.3AFPCh. 24.1 - Prob. 24.3BFPCh. 24.2 - Prob. 24.4AFPCh. 24.2 - Prob. 24.4BFPCh. 24.2 - Prob. 24.5AFPCh. 24.2 - Prob. 24.5BFP
Ch. 24.2 - Prob. 24.6AFPCh. 24.2 - Prob. 24.6BFPCh. 24.6 - Prob. 24.7AFPCh. 24.6 - Prob. 24.7BFPCh. 24.7 - Prob. B24.1PCh. 24.7 - Prob. B24.2PCh. 24.7 - Prob. B24.3PCh. 24.7 - Prob. B24.4PCh. 24 - Prob. 24.1PCh. 24 - Prob. 24.2PCh. 24 - Prob. 24.3PCh. 24 - Prob. 24.4PCh. 24 - Prob. 24.5PCh. 24 - Prob. 24.6PCh. 24 - Prob. 24.7PCh. 24 - Prob. 24.8PCh. 24 - Prob. 24.9PCh. 24 - Prob. 24.10PCh. 24 - Prob. 24.11PCh. 24 - Prob. 24.12PCh. 24 - Prob. 24.13PCh. 24 - Prob. 24.14PCh. 24 - Prob. 24.15PCh. 24 - Prob. 24.16PCh. 24 - Prob. 24.17PCh. 24 - Prob. 24.18PCh. 24 - Prob. 24.19PCh. 24 - Prob. 24.20PCh. 24 - Prob. 24.21PCh. 24 - Prob. 24.22PCh. 24 - Prob. 24.23PCh. 24 - Prob. 24.24PCh. 24 - Prob. 24.25PCh. 24 - Prob. 24.26PCh. 24 - Prob. 24.27PCh. 24 - Prob. 24.28PCh. 24 - Prob. 24.29PCh. 24 - Prob. 24.30PCh. 24 - Prob. 24.31PCh. 24 - Prob. 24.32PCh. 24 - Prob. 24.33PCh. 24 - Prob. 24.34PCh. 24 - Prob. 24.35PCh. 24 - Prob. 24.36PCh. 24 - Prob. 24.37PCh. 24 - Prob. 24.38PCh. 24 - Prob. 24.39PCh. 24 - Prob. 24.40PCh. 24 - Prob. 24.41PCh. 24 - Prob. 24.42PCh. 24 - Prob. 24.43PCh. 24 - Prob. 24.44PCh. 24 - Prob. 24.45PCh. 24 - Prob. 24.46PCh. 24 - Prob. 24.47PCh. 24 - Prob. 24.48PCh. 24 - Prob. 24.49PCh. 24 - Prob. 24.50PCh. 24 - Prob. 24.51PCh. 24 - Prob. 24.52PCh. 24 - Prob. 24.53PCh. 24 - Prob. 24.54PCh. 24 - Prob. 24.55PCh. 24 - Prob. 24.56PCh. 24 - Prob. 24.57PCh. 24 - Prob. 24.58PCh. 24 - Prob. 24.59PCh. 24 - Prob. 24.60PCh. 24 - Prob. 24.61PCh. 24 - Prob. 24.62PCh. 24 - Prob. 24.63PCh. 24 - Prob. 24.64PCh. 24 - Prob. 24.65PCh. 24 - Prob. 24.66PCh. 24 - Prob. 24.67PCh. 24 - Prob. 24.68PCh. 24 - Prob. 24.69PCh. 24 - Prob. 24.70PCh. 24 - Prob. 24.71PCh. 24 - Prob. 24.72PCh. 24 - Prob. 24.73PCh. 24 - Prob. 24.74PCh. 24 - Prob. 24.75PCh. 24 - Prob. 24.76PCh. 24 - Prob. 24.77PCh. 24 - Prob. 24.78PCh. 24 - Prob. 24.79PCh. 24 - Prob. 24.80PCh. 24 - Prob. 24.81PCh. 24 - Prob. 24.82PCh. 24 - Prob. 24.83PCh. 24 - Prob. 24.84PCh. 24 - Prob. 24.85PCh. 24 - Prob. 24.86PCh. 24 - Prob. 24.87PCh. 24 - Prob. 24.88PCh. 24 - Prob. 24.89PCh. 24 - Prob. 24.90PCh. 24 - Prob. 24.91PCh. 24 - Prob. 24.92PCh. 24 - Prob. 24.93PCh. 24 - Prob. 24.94PCh. 24 - Prob. 24.95PCh. 24 - Prob. 24.96PCh. 24 - Prob. 24.97PCh. 24 - Prob. 24.98PCh. 24 - Prob. 24.99PCh. 24 - Prob. 24.100PCh. 24 - Prob. 24.101PCh. 24 - Prob. 24.102PCh. 24 - Prob. 24.103PCh. 24 - Prob. 24.104PCh. 24 - Prob. 24.105PCh. 24 - Prob. 24.106PCh. 24 - Prob. 24.107PCh. 24 - Prob. 24.108PCh. 24 - Prob. 24.109PCh. 24 - Prob. 24.110PCh. 24 - Prob. 24.111PCh. 24 - Prob. 24.112PCh. 24 - Prob. 24.113PCh. 24 - Prob. 24.114PCh. 24 - Prob. 24.115PCh. 24 - Prob. 24.116PCh. 24 - Prob. 24.117PCh. 24 - Prob. 24.118PCh. 24 - Prob. 24.119PCh. 24 - Prob. 24.120PCh. 24 - Prob. 24.121PCh. 24 - Prob. 24.122PCh. 24 - Prob. 24.123PCh. 24 - Prob. 24.124PCh. 24 - Prob. 24.125PCh. 24 - Prob. 24.126PCh. 24 - Prob. 24.127PCh. 24 - Prob. 24.128PCh. 24 - Prob. 24.129PCh. 24 - Prob. 24.130PCh. 24 - Prob. 24.131PCh. 24 - Prob. 24.132PCh. 24 - Prob. 24.133PCh. 24 - Prob. 24.134PCh. 24 - Prob. 24.135PCh. 24 - Prob. 24.136PCh. 24 - Prob. 24.137PCh. 24 - Prob. 24.138PCh. 24 - Prob. 24.139PCh. 24 - Prob. 24.140PCh. 24 - Prob. 24.141PCh. 24 - Prob. 24.142PCh. 24 - Prob. 24.143PCh. 24 - Prob. 24.144P
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