Chemistry for Today: General Organic and Biochemistry
9th Edition
ISBN: 9781337514576
Author: Seager
Publisher: Cengage
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Chapter 24, Problem 24.71E
Interpretation Introduction
Interpretation:
The reason corresponding to the fact that the enzymes have comparatively short half-lives is to be stated.
Concept introduction:
Enzymes being the catalysts increase the
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The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 24 Solutions
Chemistry for Today: General Organic and Biochemistry
Ch. 24 - How does the caloric value of fat compare with the...Ch. 24 - What are the products of triglyceride digestion?Ch. 24 - Prob. 24.3ECh. 24 - Prob. 24.4ECh. 24 - Prob. 24.5ECh. 24 - Prob. 24.6ECh. 24 - Prob. 24.7ECh. 24 - Prob. 24.8ECh. 24 - Prob. 24.9ECh. 24 - Prob. 24.10E
Ch. 24 - Prob. 24.11ECh. 24 - Prob. 24.12ECh. 24 - Prob. 24.13ECh. 24 - Prob. 24.14ECh. 24 - Prob. 24.15ECh. 24 - Prob. 24.16ECh. 24 - Prob. 24.17ECh. 24 - Prob. 24.18ECh. 24 - Prob. 24.19ECh. 24 - Prob. 24.20ECh. 24 - Prob. 24.21ECh. 24 - Prob. 24.22ECh. 24 - Prob. 24.23ECh. 24 - Prob. 24.24ECh. 24 - Prob. 24.25ECh. 24 - Prob. 24.26ECh. 24 - Prob. 24.27ECh. 24 - Prob. 24.28ECh. 24 - Prob. 24.29ECh. 24 - Prob. 24.30ECh. 24 - Differentiate between a ketonemia, b ketonuria, c...Ch. 24 - Prob. 24.32ECh. 24 - Prob. 24.33ECh. 24 - Prob. 24.34ECh. 24 - Prob. 24.35ECh. 24 - Prob. 24.36ECh. 24 - List three vital functions served by amino acids...Ch. 24 - Prob. 24.38ECh. 24 - Prob. 24.39ECh. 24 - Prob. 24.40ECh. 24 - Prob. 24.41ECh. 24 - Prob. 24.42ECh. 24 - Prob. 24.43ECh. 24 - Prob. 24.44ECh. 24 - Prob. 24.45ECh. 24 - Prob. 24.46ECh. 24 - Prob. 24.47ECh. 24 - Prob. 24.48ECh. 24 - Prob. 24.49ECh. 24 - Prob. 24.50ECh. 24 - Prob. 24.51ECh. 24 - Prob. 24.52ECh. 24 - Prob. 24.53ECh. 24 - Prob. 24.54ECh. 24 - Differentiate between glucogenic and ketogenic...Ch. 24 - Prob. 24.56ECh. 24 - Prob. 24.57ECh. 24 - Prob. 24.58ECh. 24 - Prob. 24.59ECh. 24 - Prob. 24.60ECh. 24 - Prob. 24.61ECh. 24 - Prob. 24.62ECh. 24 - Prob. 24.63ECh. 24 - Prob. 24.64ECh. 24 - Prob. 24.65ECh. 24 - Prob. 24.66ECh. 24 - Prob. 24.67ECh. 24 - Prob. 24.68ECh. 24 - Prob. 24.69ECh. 24 - Prob. 24.70ECh. 24 - Prob. 24.71ECh. 24 - Prob. 24.72ECh. 24 - Prob. 24.73ECh. 24 - Prob. 24.74ECh. 24 - Prob. 24.75ECh. 24 - Prob. 24.76ECh. 24 - Prob. 24.77ECh. 24 - Prob. 24.78ECh. 24 - Prob. 24.79ECh. 24 - Prob. 24.80ECh. 24 - The clinic nurse is evaluating a man wearing a...
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- Consider the following two acid-base reactions: OH OHI Based on what you know about the compounds and their acidity, which direction would you expect both of these reactions to proceed? Show your reasoning. A pKa table has been provided in case you need it. Functional group Example pka CHA -50 Alkane -35 Amine : NH3 Alkyne RH 25 Water HO-H 169 16 10 Protonated amines NH 10 5 Carboxylic acids OH Hydrochloric acid HCI A chemist intends to run the following reaction on the three substrates shown below: H₂O R-CI product room temp. Cl Cl (1) (2) (3) They find one will react quickly, one slowly, and one will not react at all. Which is which, and why? HINT: What is the reaction they're trying to do? Does that mechanism tell you anything about why something would be favored?arrow_forwardNH3 decomposes through an equilibrium reaction between NH3, H2, and N2. Only one of the options is correct:(A). The mechanism of the NH3 decomposition reaction must necessarily involve the collision of two NH3 molecules to induce a rearrangement of the atoms in this molecule.(B). The molecular weight of the NH3 decomposition reaction is 2 since two NH3 molecules must collide.(C). The rate of the NH3 decomposition reaction must be greater than that of NH3 synthesis, since the former requires two molecules to collide and the latter, four.(D). The NH3 decomposition reaction cannot occur in a single step.arrow_forwardGiven the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 lowarrow_forward
- A 2-step reaction has the following mechanism: | 1. (fast) R2 R+R 2. (slow) R+Q K₂ P k_1 What series does it have? (A). v= - = (k + k1 − k-1)[R2][Q] (B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q] (C). v=k₂[R]²[Q]² (D). v = k[R₂]1/2[Q]arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
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