Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter 24, Problem 24.56P
Interpretation Introduction

(a)

Interpretation:

How to produce the given compound from an alkene or alkyne is to be determined.

Concept introduction:

In each of these reactions, the CC or C=C reacts. A syn 1, 2-diol is formed when a C=C  is treated with KMnO4/KOH in cold temperature or with OsO4. A 1, 2-diketone is formed when an internal CC is treated with KMnO4/KOH in cold temperature or with OsO4.

Expert Solution
Check Mark

Answer to Problem 24.56P

The starting compound and the reaction condition are given below.

Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 24, Problem 24.56P , additional homework tip  1

Explanation of Solution

The product from this reaction is a syn 1, 2-diol. A syn 1, 2-diol is formed when a C=C  is treated with KMnO4/KOH in a cold temperature or with OsO4. The starting material and the reaction condition are given below.

Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 24, Problem 24.56P , additional homework tip  2

Conclusion

The given reaction is explained as when C=C  reacts with KMnO4/KOH or OsO4 it produces a syn 1, 2-diol.

Interpretation Introduction

(b)

Interpretation:

How to produce the given compound from an alkene or alkyne is to be determined.

Concept introduction:

In each of these reactions, the CC or C=C react. A syn 1, 2-diol is formed when a C=C  is treated with KMnO4/KOH in a cold temperature or with OsO4. A 1, 2-diketone is formed when an internal CC is treated with KMnO4/KOH in cold temperature or with OsO4.

Expert Solution
Check Mark

Answer to Problem 24.56P

The starting compound and the reaction condition are given below.

Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 24, Problem 24.56P , additional homework tip  3

Explanation of Solution

The product from this reaction is a syn 1, 2-diol. A syn 1, 2-diol is formed when a C=C  is treated with KMnO4/KOH in a cold temperature or with OsO4. The starting material and the reaction condition are given below.

Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 24, Problem 24.56P , additional homework tip  4

Conclusion

The given reaction is explained as when C=C  reacts with KMnO4/KOH or OsO4 it produces a syn 1, 2-diol.

Interpretation Introduction

(c)

Interpretation:

How to produce the given compound from an alkene or alkyne is to be determined.

Concept introduction:

In each of these reactions, the CC or C=C react. A syn 1, 2-diol is formed when a C=C  is treated with KMnO4/KOH in a cold temperature or with OsO4. A 1, 2-diketone is formed when an internal CC is treated with KMnO4/KOH in cold temperature or with OsO4.

Expert Solution
Check Mark

Answer to Problem 24.56P

The starting compound and the reaction condition are given below.

Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 24, Problem 24.56P , additional homework tip  5

Explanation of Solution

The product from this reaction is a 1, 2-diketone. A 1, 2-diketone is formed when an internal CC is treated with KMnO4/KOH in cold temperature or with OsO4. The starting material and the reaction condition is given below.

Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 24, Problem 24.56P , additional homework tip  6

Conclusion

The given reaction is explained as when CC reacts with KMnO4/KOH or OsO4 it produce a 1, 2-diketone.

Interpretation Introduction

(d)

Interpretation:

How to produce the given compound from an alkene or alkyne is to be determined.

Concept introduction:

In each of these reactions, the CC or C=C react. A syn 1, 2-diol is formed when a C=C  is treated with KMnO4/KOH in a cold temperature or with OsO4. A 1, 2-diketone is formed when an internal CC is treated with KMnO4/KOH in cold temperature or with OsO4.

Expert Solution
Check Mark

Answer to Problem 24.56P

The starting compound and the reaction condition are given below.

Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 24, Problem 24.56P , additional homework tip  7Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 24, Problem 24.56P , additional homework tip  8

Explanation of Solution

The product from this reaction is a syn 1, 2-diol. A syn 1, 2-diol is formed when a C=C  is treated with KMnO4/KOH in a cold temperature or with OsO4. The starting material and the reaction condition is given below.

Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 24, Problem 24.56P , additional homework tip  9 Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 24, Problem 24.56P , additional homework tip  10

Conclusion

The given reaction is explained as when C=C  reacts with KMnO4/KOH or OsO4 it produces a syn 1, 2-diol.

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Chapter 24 Solutions

Organic Chemistry: Principles and Mechanisms (Second Edition)

Ch. 24 - Prob. 24.11PCh. 24 - Prob. 24.12PCh. 24 - Prob. 24.13PCh. 24 - Prob. 24.14PCh. 24 - Prob. 24.15PCh. 24 - Prob. 24.16PCh. 24 - Prob. 24.17PCh. 24 - Prob. 24.18PCh. 24 - Prob. 24.19PCh. 24 - Prob. 24.20PCh. 24 - Prob. 24.21PCh. 24 - Prob. 24.22PCh. 24 - Prob. 24.23PCh. 24 - Prob. 24.24PCh. 24 - Prob. 24.25PCh. 24 - Prob. 24.26PCh. 24 - Prob. 24.27PCh. 24 - Prob. 24.28PCh. 24 - Prob. 24.29PCh. 24 - Prob. 24.30PCh. 24 - Prob. 24.31PCh. 24 - Prob. 24.32PCh. 24 - Prob. 24.33PCh. 24 - Prob. 24.34PCh. 24 - Prob. 24.35PCh. 24 - Prob. 24.36PCh. 24 - Prob. 24.37PCh. 24 - Prob. 24.38PCh. 24 - Prob. 24.39PCh. 24 - Prob. 24.40PCh. 24 - Prob. 24.41PCh. 24 - Prob. 24.42PCh. 24 - Prob. 24.43PCh. 24 - Prob. 24.44PCh. 24 - Prob. 24.45PCh. 24 - Prob. 24.46PCh. 24 - Prob. 24.47PCh. 24 - Prob. 24.48PCh. 24 - Prob. 24.49PCh. 24 - Prob. 24.50PCh. 24 - Prob. 24.51PCh. 24 - Prob. 24.52PCh. 24 - Prob. 24.53PCh. 24 - Prob. 24.54PCh. 24 - Prob. 24.55PCh. 24 - Prob. 24.56PCh. 24 - Prob. 24.57PCh. 24 - Prob. 24.58PCh. 24 - Prob. 24.59PCh. 24 - Prob. 24.60PCh. 24 - Prob. 24.61PCh. 24 - Prob. 24.62PCh. 24 - Prob. 24.63PCh. 24 - Prob. 24.64PCh. 24 - Prob. 24.65PCh. 24 - Prob. 24.66PCh. 24 - Prob. 24.67PCh. 24 - Prob. 24.68PCh. 24 - Prob. 24.69PCh. 24 - Prob. 24.70PCh. 24 - Prob. 24.71PCh. 24 - Prob. 24.72PCh. 24 - Prob. 24.73PCh. 24 - Prob. 24.74PCh. 24 - Prob. 24.75PCh. 24 - Prob. 24.76PCh. 24 - Prob. 24.77PCh. 24 - Prob. 24.78PCh. 24 - Prob. 24.79PCh. 24 - Prob. 24.80PCh. 24 - Prob. 24.81PCh. 24 - Prob. 24.82PCh. 24 - Prob. 24.83PCh. 24 - Prob. 24.84PCh. 24 - Prob. 24.1YTCh. 24 - Prob. 24.2YTCh. 24 - Prob. 24.3YTCh. 24 - Prob. 24.4YTCh. 24 - Prob. 24.5YTCh. 24 - Prob. 24.6YTCh. 24 - Prob. 24.7YTCh. 24 - Prob. 24.8YTCh. 24 - Prob. 24.9YTCh. 24 - Prob. 24.10YTCh. 24 - Prob. 24.11YTCh. 24 - Prob. 24.12YTCh. 24 - Prob. 24.13YTCh. 24 - Prob. 24.14YTCh. 24 - Prob. 24.15YTCh. 24 - Prob. 24.16YTCh. 24 - Prob. 24.17YT
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