(a) Interpretation: For the acid the α- and β-positions are to be labeled. Concept introduction: Fatty acids contain a long side chain of carbon atoms and a carboxylic acid group. For the nomenclature the carbon atom of carboxyl group is labeled as 0 and the carbon atom adjacent to the carboxylic group is labeled as α-carbon. Similarly, the carbon atom which is adjacent to the α-carbon is known as β-carbon.

Question

You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you manipulated and exploited the acid-base chemistry of one or more of the compounds in your mixture to facilitate their separation into different phases. The key to understanding how liquid- liquid extractions work is by knowing which layer a compound is in, and in what protonation state. The following liquid-liquid extraction is different from the one you performed in Experiment 4, but it uses the same type of logic. Your task is to show how to separate apart Compound A and Compound B. . Complete the following flowchart of a liquid-liquid extraction. Handwritten work is encouraged. • Draw by hand (neatly) only the appropriate organic compound(s) in the boxes. . Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4 and 5. • Box 7a requires the solvent (name is fine). • Box 7b requires one inorganic compound. • You can neatly complete this assignment by hand and…

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 24, Problem 24.17E

Interpretation Introduction

(a)

Interpretation:

For the acid the α- and β-positions are to be labeled.

Concept introduction:

Fatty acids contain a long side chain of carbon atoms and a carboxylic acid group. For the nomenclature the carbon atom of carboxyl group is labeled as 0 and the carbon atom adjacent to the carboxylic group is labeled as α-carbon. Similarly, the carbon atom which is adjacent to the α-carbon is known as β-carbon.

Interpretation Introduction

(b)

Interpretation:

For the acid the α- and β-positions are to be labeled.

Concept introduction:

Fatty acids contain a long side chain of carbon atoms and a carboxylic acid group. For the nomenclature the carbon atom of carboxyl group is labeled as 0 and the carbon atom adjacent to the carboxylic group is labeled as α-carbon. Similarly, the carbon atom which is adjacent to the α-carbon is known as β-carbon.

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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you manipulated and exploited the acid-base chemistry of one or more of the compounds in your mixture to facilitate their separation into different phases. The key to understanding how liquid- liquid extractions work is by knowing which layer a compound is in, and in what protonation state. The following liquid-liquid extraction is different from the one you performed in Experiment 4, but it uses the same type of logic. Your task is to show how to separate apart Compound A and Compound B. . Complete the following flowchart of a liquid-liquid extraction. Handwritten work is encouraged. • Draw by hand (neatly) only the appropriate organic compound(s) in the boxes. . Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4 and 5. • Box 7a requires the solvent (name is fine). • Box 7b requires one inorganic compound. • You can neatly complete this assignment by hand and…

b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;' The compound has the ff electronic transitions: 0%o* and no a* 1H NMR Spectrum (CDCl3, 400 MHz) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm 13C{H} NMR Spectrum (CDCl3, 100 MHz) Solvent 80 70 60 50 40 30 20 10 0 ppm ppm ¹H-13C me-HSQC Spectrum ppm (CDCl3, 400 MHz) 5 ¹H-¹H COSY Spectrum (CDCl3, 400 MHz) 0.5 10 3.5 3.0 2.5 2.0 1.5 1.0 10 15 20 20 25 30 30 -35 -1.0 1.5 -2.0 -2.5 3.0 -3.5 0.5 ppm 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 24, Problem 24.17E

Interpretation Introduction

(a)

Interpretation:

For the acid the α- and β-positions are to be labeled.

Concept introduction:

Fatty acids contain a long side chain of carbon atoms and a carboxylic acid group. For the nomenclature the carbon atom of carboxyl group is labeled as 0 and the carbon atom adjacent to the carboxylic group is labeled as α-carbon. Similarly, the carbon atom which is adjacent to the α-carbon is known as β-carbon.

Interpretation Introduction

(b)

Interpretation:

For the acid the α- and β-positions are to be labeled.

Concept introduction:

Fatty acids contain a long side chain of carbon atoms and a carboxylic acid group. For the nomenclature the carbon atom of carboxyl group is labeled as 0 and the carbon atom adjacent to the carboxylic group is labeled as α-carbon. Similarly, the carbon atom which is adjacent to the α-carbon is known as β-carbon.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 24, Problem 24.17E

Interpretation Introduction

(a)

Interpretation:

For the acid the α- and β-positions are to be labeled.

Concept introduction:

Fatty acids contain a long side chain of carbon atoms and a carboxylic acid group. For the nomenclature the carbon atom of carboxyl group is labeled as 0 and the carbon atom adjacent to the carboxylic group is labeled as α-carbon. Similarly, the carbon atom which is adjacent to the α-carbon is known as β-carbon.

Interpretation Introduction

(b)

Interpretation:

For the acid the α- and β-positions are to be labeled.

Concept introduction:

Fatty acids contain a long side chain of carbon atoms and a carboxylic acid group. For the nomenclature the carbon atom of carboxyl group is labeled as 0 and the carbon atom adjacent to the carboxylic group is labeled as α-carbon. Similarly, the carbon atom which is adjacent to the α-carbon is known as β-carbon.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 24, Problem 24.17E

Interpretation Introduction