a) Interpretation: The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given. Concept introduction: Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester. To give: The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Question

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 8

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 12

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 16

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 20

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 24

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Students have asked these similar questions

81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 8

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 12

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 16

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 20

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 24

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 8

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 12

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 16

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 20

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 24

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 8

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 12

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 16

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 20

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 24

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Answer 5

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 4

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 8

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 12

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 16

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 20

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 24

Answer 6

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 2

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 3

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 4

Answer 7

Chapter 23.SE, Problem 62AP

Interpretation Introduction

a)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 8

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 2

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and phenyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 3

Answer 13

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 4

Answer 14

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 6

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 7

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 8

Answer 15

Interpretation Introduction

b)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 16

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 6

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and methyl vinyl ketone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 7

Answer 21

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 8

Answer 22

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 10

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 11

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 12

Answer 23

Interpretation Introduction

c)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 24

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 10

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylacetoacetate (nucleophilic donor) and vinyl nitrile (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 11

Answer 29

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 12

Answer 30

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 14

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 15

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 16

Answer 31

Interpretation Introduction

d)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 32

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 14

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro ethane (nucleophilic donor) and ethylacrylate (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 15

Answer 37

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 16

Answer 38

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 18

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 19

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 20

Answer 39

Interpretation Introduction

e)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 40

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 18

Answer 41

Expert Solution

Answer 42

Expert Solution

Answer 43

Expert Solution

Answer 44

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between the ethylsuccinate (nucleophilic donor) and nitro ethene (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 19

Answer 45

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 20

Answer 46

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 22

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 23

Conclusion

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 24

Answer 47

Interpretation Introduction

f)

Interpretation:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β-diketones or β-ketonitriles or malonic esters (donors) to an unhindered α,β-unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β-carbon of the unsaturated ester.

To give:

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown.

Answer 48

Expert Solution

Answer to Problem 62AP

The nucleophilic donor and electrophilic acceptor that react in a Michael reaction to yield the compound shown are

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 22

Answer 49

Expert Solution

Answer 50

Expert Solution

Answer 51

Expert Solution

Answer 52

Explanation of Solution

An analysis of the structure of the compound indicates that it is formed by the reaction between nitro methane (nucleophilic donor) and 2-cyclopentenone (electrophilic acceptor).

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 23.SE, Problem 62AP , additional homework tip 23