
a)
Interpretation:
The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor is to be given.
Concept introduction:
Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered α,β- unsaturated
To give:
The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor.
b)
Interpretation:
The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown is to be given.
Concept introduction:
Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered α,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the α-carbon of the donor and the β- carbon of the unsaturated ester.
To give:
The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown.

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Chapter 23 Solutions
Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th
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