Chapter 23.4, Problem 23.6AFP

Interpretation Introduction

Interpretation:

The given complex ${\left[V{(H_{2}O)}_6\right]}^{3+}or{\left[V{(N{H}_3)}_6\right]}^{3+}$ which one is absorbs visible light of higher energy has to be identified.

Concept introduction:

The fact that colour depends on the ligand allows us to create a spectrochemical series, which ranks the ability of a ligand to split $\text{d-orbital}$ energies.

The relative magnitude of $\Delta$ for a series of octahedral complexes of a given metal ion.  As $\Delta$ increases, higher energies (shorter wavelengths) of light must be absorbed to excite electrons.

The spectrochemical series is

  $I^{-}<C{l}^{-}<F^{-}<O{H}^{-}<H_{2}O<SC{N}^{-}<en<N{O}_2^{-}<C{N}^{-}<CO$