
Loose Leaf for Chemistry: The Molecular Nature of Matter and Change
8th Edition
ISBN: 9781260151749
Author: Silberberg Dr., Martin; Amateis Professor, Patricia
Publisher: McGraw-Hill Education
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Chapter 23.3, Problem 23.5BFP
Interpretation Introduction
Interpretation:
The all of the possible stereoisomer for the given
Concept introduction:
Stereoisomers: Atoms Arranged Differently in Space.
Stereoisomers are compounds that have the same atomic connections but different spatial arrangements of the atoms.
Stereoisomers can be either geometric or optical. For geometric isomers, check if the
ligands can be arranged either next to (cis) or opposite (trans) each other. Then, check if the mirror image of any of the geometric isomers is not superimposable. If mirror image is not superimposable, the structure is an optical isomer.
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Please help me find the 1/Time, Log [I^-] Log [S2O8^2-], Log(time) on the data table. With calculation steps. And the average for runs 1a-1b. Please help me thanks in advance. Will up vote!
Q1: Answer the questions for the reaction below:
..!! Br
OH
a) Predict the product(s) of the reaction.
b) Is the substrate optically active? Are the product(s) optically active as a mix?
c) Draw the curved arrow mechanism for the reaction.
d) What happens to the SN1 reaction rate in each of these instances:
1. Change the substrate to
Br
"CI
2. Change the substrate to
3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF
4. Increase the substrate concentration by 3-fold.
Experiment 27 hates & Mechanisms of Reations
Method I visual Clock Reaction
A. Concentration effects on reaction Rates
Iodine
Run [I] mol/L [S₂082] | Time
mo/L
(SCC)
0.04 54.7
Log
1/ Time Temp Log [ ] 13,20] (time)
/ [I] 199
20.06
23.0
30.04 0.04
0.04 80.0
22.8
45
40.02
0.04 79.0
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50.08
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22.4
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23.4
7 0.08
0-01 1970
23.4
8 0.08 0.04 16.1
22.6
Chapter 23 Solutions
Loose Leaf for Chemistry: The Molecular Nature of Matter and Change
Ch. 23.1 - Write partial electron configurations (no noble...Ch. 23.1 - Find the charge of each of the following ions,...Ch. 23.2 - Prob. 23.2AFPCh. 23.2 - Prob. 23.2BFPCh. 23.3 - Give the coordination number and the charge of the...Ch. 23.3 - Write the formula of the coordination compound...Ch. 23.3 - Prob. 23.4AFPCh. 23.3 - Prob. 23.4BFPCh. 23.3 - Prob. 23.5AFPCh. 23.3 - Prob. 23.5BFP
Ch. 23.4 - Prob. 23.6AFPCh. 23.4 - Prob. 23.6BFPCh. 23.4 - Prob. 23.7AFPCh. 23.4 - Prob. 23.7BFPCh. 23.4 - Prob. B23.1PCh. 23.4 - Prob. B23.2PCh. 23 - Prob. 23.1PCh. 23 - Write the general electron configuration of a...Ch. 23 - Prob. 23.3PCh. 23 - Prob. 23.4PCh. 23 - Prob. 23.5PCh. 23 - Prob. 23.6PCh. 23 - (a) What is the range in electronegativity across...Ch. 23 - (a) Explain the major difference between the...Ch. 23 - (a) What behavior distinguishes paramagnetic and...Ch. 23 - Prob. 23.10PCh. 23 - Using the periodic table to locate each element,...Ch. 23 - Using the periodic table to locate each element,...Ch. 23 - Using the periodic table to locate each element,...Ch. 23 - Prob. 23.14PCh. 23 - Prob. 23.15PCh. 23 - What is the highest oxidation state for (a) Ta;...Ch. 23 - What is the highest oxidation state for (a) Nb;...Ch. 23 - Prob. 23.18PCh. 23 - Prob. 23.19PCh. 23 - Prob. 23.20PCh. 23 - Prob. 23.21PCh. 23 - Prob. 23.22PCh. 23 - Prob. 23.23PCh. 23 - Prob. 23.24PCh. 23 - Prob. 23.25PCh. 23 - Prob. 23.26PCh. 23 - What atomic property of the lanthanides leads to...Ch. 23 - Prob. 23.28PCh. 23 - Prob. 23.29PCh. 23 - Give the electron configuration of (a) La; (b)...Ch. 23 - Prob. 23.31PCh. 23 - Only a few lanthanides show an oxidation state...Ch. 23 - Prob. 23.33PCh. 23 - Prob. 23.34PCh. 23 - Describe the makeup of a complex ion, including...Ch. 23 - Prob. 23.36PCh. 23 - Prob. 23.37PCh. 23 - Prob. 23.38PCh. 23 - Prob. 23.39PCh. 23 - Prob. 23.40PCh. 23 - Prob. 23.41PCh. 23 - Prob. 23.42PCh. 23 - Prob. 23.43PCh. 23 - Prob. 23.44PCh. 23 - Prob. 23.45PCh. 23 - Prob. 23.46PCh. 23 - What are the charge and coordination number of the...Ch. 23 - What are the charge and coordination number of the...Ch. 23 - Prob. 23.49PCh. 23 - Give systematic names for the following...Ch. 23 - What are the charge and coordination number of the...Ch. 23 - What are the charge and coordination number of the...Ch. 23 - Prob. 23.53PCh. 23 - Prob. 23.54PCh. 23 - Prob. 23.55PCh. 23 - Prob. 23.56PCh. 23 - Prob. 23.57PCh. 23 - Prob. 23.58PCh. 23 - Prob. 23.59PCh. 23 - Prob. 23.60PCh. 23 - Prob. 23.61PCh. 23 - Prob. 23.62PCh. 23 - For any of the following that can exist as...Ch. 23 - Prob. 23.64PCh. 23 - Prob. 23.65PCh. 23 - Prob. 23.66PCh. 23 - Chromium(III), like cobalt(III), has a...Ch. 23 - When MCl4(NH3)2 is dissolved in water and treated...Ch. 23 - Prob. 23.69PCh. 23 -
What is a coordinate covalent bond?
Is such a...Ch. 23 - Prob. 23.71PCh. 23 - Prob. 23.72PCh. 23 - Prob. 23.73PCh. 23 - In terms of the theory of color absorption,...Ch. 23 - Prob. 23.75PCh. 23 - Prob. 23.76PCh. 23 - Prob. 23.77PCh. 23 - How do the relative magnitudes of Epairing and Δ...Ch. 23 - Prob. 23.79PCh. 23 - Give the number of d electrons (n of dn) for the...Ch. 23 - Give the number of d electrons (n of dn) for the...Ch. 23 - Prob. 23.82PCh. 23 - How many d electrons (n of dn) are in the central...Ch. 23 - Prob. 23.84PCh. 23 - Prob. 23.85PCh. 23 - Prob. 23.86PCh. 23 - Prob. 23.87PCh. 23 - Prob. 23.88PCh. 23 - Prob. 23.89PCh. 23 - Prob. 23.90PCh. 23 - Prob. 23.91PCh. 23 - Prob. 23.92PCh. 23 - Prob. 23.93PCh. 23 - Prob. 23.94PCh. 23 - Prob. 23.95PCh. 23 - Prob. 23.96PCh. 23 - Prob. 23.97PCh. 23 - Prob. 23.98PCh. 23 - When neptunium (Np) and plutonium (Pu) were...Ch. 23 - Prob. 23.100PCh. 23 - Prob. 23.101PCh. 23 - For the compound [Co(en)2Cl2]Cl, give:
The...Ch. 23 - Prob. 23.103PCh. 23 - Prob. 23.104PCh. 23 - Prob. 23.105PCh. 23 - Prob. 23.106PCh. 23 - Prob. 23.107PCh. 23 - Prob. 23.108PCh. 23 - Prob. 23.109PCh. 23 - Prob. 23.110PCh. 23 - Prob. 23.111PCh. 23 - The actinides Pa, U, and Np form a series of...Ch. 23 - Prob. 23.113PCh. 23 - Prob. 23.114PCh. 23 - Prob. 23.115PCh. 23 - Prob. 23.116PCh. 23 - Prob. 23.117PCh. 23 - Prob. 23.118PCh. 23 - Prob. 23.119PCh. 23 - Prob. 23.120PCh. 23 - Prob. 23.121PCh. 23 - Prob. 23.122P
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