Bundle: Organic Chemistry, 9th, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
Bundle: Organic Chemistry, 9th, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
9th Edition
ISBN: 9781305701021
Author: John E. McMurry
Publisher: Cengage Learning
Question
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Chapter 23.11, Problem 19P
Interpretation Introduction

a)

Bundle: Organic Chemistry, 9th, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card, Chapter 23.11, Problem 19P , additional homework tip  1

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, ethyl acrylate, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the product.

To identify:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated, ethyl acrylate, is hydrolyzed.

Interpretation Introduction

b)

Bundle: Organic Chemistry, 9th, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card, Chapter 23.11, Problem 19P , additional homework tip  2

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acrolein is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor, acrolein, to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acroline.

Interpretation Introduction

c)

Bundle: Organic Chemistry, 9th, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card, Chapter 23.11, Problem 19P , additional homework tip  3

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with an α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one.

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Chapter 23 Solutions

Bundle: Organic Chemistry, 9th, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card

Ch. 23.7 - Show the products you would expect to obtain by...Ch. 23.7 - Prob. 12PCh. 23.8 - What product would you expect from the following...Ch. 23.9 - What product would you expect From the following...Ch. 23.9 - Prob. 15PCh. 23.10 - Prob. 16PCh. 23.10 - Prob. 17PCh. 23.10 - Prob. 18PCh. 23.11 - Prob. 19PCh. 23.11 - Show how you might use an enamine reaction to...Ch. 23.12 - Prob. 21PCh. 23.12 - How would you prepare the following compound using...Ch. 23.SE - Prob. 23VCCh. 23.SE - Prob. 24VCCh. 23.SE - Prob. 25VCCh. 23.SE - The following molecule was formed by a Robinson...Ch. 23.SE - Prob. 27MPCh. 23.SE - Prob. 28MPCh. 23.SE - Predict the product(s) and provide the mechanism...Ch. 23.SE - Predict the product(s) and provide the mechanism...Ch. 23.SE - Predict the product(s) and provide the mechanism...Ch. 23.SE - Knoevenagel condensation is a reaction involving...Ch. 23.SE - Azlactones are important starting materials used...Ch. 23.SE - Prob. 34MPCh. 23.SE - Isoleucine, another of the twenty amino acids...Ch. 23.SE - The first step in the citric acid cycle of food...Ch. 23.SE - Prob. 37MPCh. 23.SE - The Knoevenagel reaction is a carbonyl...Ch. 23.SE - The Darzens reaction invoIves a two-step,...Ch. 23.SE - The following reaction involves a hydrolysis...Ch. 23.SE - Prob. 41MPCh. 23.SE - Prob. 42MPCh. 23.SE - Prob. 43MPCh. 23.SE - Propose a mechanism for the following...Ch. 23.SE - Prob. 45MPCh. 23.SE - Prob. 46MPCh. 23.SE - Prob. 47MPCh. 23.SE - Prob. 48APCh. 23.SE - Prob. 49APCh. 23.SE - Prob. 50APCh. 23.SE - Prob. 51APCh. 23.SE - Prob. 52APCh. 23.SE - Prob. 53APCh. 23.SE - Prob. 54APCh. 23.SE - Prob. 55APCh. 23.SE - Prob. 56APCh. 23.SE - Prob. 57APCh. 23.SE - Prob. 58APCh. 23.SE - In the mixed Claisen reaction of cyclopentanone...Ch. 23.SE - Ethyl dimethylacetoacetate reacts instantly at...Ch. 23.SE - Prob. 61APCh. 23.SE - Prob. 62APCh. 23.SE - The so-called Wieland-Miescher ketone is a...Ch. 23.SE - Prob. 64APCh. 23.SE - Prob. 65APCh. 23.SE - Prob. 66APCh. 23.SE - What condensation products would you expect to...Ch. 23.SE - The following reactions are unlikely to provide...Ch. 23.SE - Fill in the missing reagents a-h in the following...Ch. 23.SE - Prob. 70APCh. 23.SE - Prob. 71APCh. 23.SE - Prob. 72APCh. 23.SE - Prob. 73AP
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