The structure, name and the class belongs for the product fromed from the reaction between butanoic acid and methylamine should be given. The balanced chemical equation for the reaction of butanoic acid andmethylamine should be written. Concept introduction: Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia. Here, the − O H group is attached to the carbonyl carbon atom of the carboxylic acid is being replaced by − N H 2 , − N H R ' or − N R ' 2 group in the an amine or ammonia forming amide and water. Chemical equation is the representation of a chemical reaction , in which the reactants and products of the reactions are represented left and right side of an arrow respectively by using their respective chemical formulas. Balanced chemical equation of a reaction is written according to law of conservation of mass.

Question

-Page: 8 nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]". What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry of [Co(H2O)]? b) Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron configurations of [Co(H2O)]: Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of [Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1 kJ/mol) Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low in configuration vs in the high spin configuration? What can you say about the importance of exchange energy 07

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Question

Chapter 23, Problem 67PS

Interpretation Introduction

Interpretation: The structure, name and the class belongs for the product fromed from the reaction between butanoic acid and methylamine should be given. The balanced chemical equation for the reaction of butanoic acid andmethylamine should be written.

Concept introduction:

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Here, the −OH group is attached to the carbonyl carbon atom of the carboxylic acid is being replaced by −NH2, −NHR' or −NR'2 group in the an amine or ammonia forming amide and water.

Chemical equation is the representation of a chemical reaction, in which the reactants and products of the reactions are represented left and right side of an arrow respectively by using their respective chemical formulas.

Balanced chemical equation of a reaction is written according to law of conservation of mass.

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-Page: 8 nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]". What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry of [Co(H2O)]? b) Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron configurations of [Co(H2O)]: Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of [Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1 kJ/mol) Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low in configuration vs in the high spin configuration? What can you say about the importance of exchange energy 07

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