
Concept explainers
Interpretation: The structure of two ethylheptane has to be drawn and their systematic name has to be given. The chiral structure among them has to be identified.
Concept introduction:
IUPAC naming for
Name the main chain: Find the longest carbon chain and name the chain according to the number of carbon atoms it contains; is also the suffix part of the name.
Number the carbon atoms in the main chain: The carbons are numbered, in which the substituents must get lowest possible numbers.
Identify the substituents, and number each: The number at where substituents are present has to be noted. The substituents written as prefix.
Write the names as a single word: Use the hyphen to separate the numbers from the different prefix; commas to separate numbers. If two or more different substituents are present, arrange them in alphabetical order. If two or more identical substituents are present, use prefixes di-, tri-, tetra-, but this particular prefix should not be used for alphabetizing purpose.
Isomers: Isomers are the compounds which have same molecular formula but have different properties. There are different types of isomers known for example, structural isomers, stereoisomers, geometrical isomers and optical isomers etc
Stereoisomerism: The compounds which have same molecular formula but there is difference in the spatial arrangements of atoms are known as stereoisomers and this phenomenon is known as stereoisomerism.
A chiral carbon is the carbon atom which is substituted to four different groups. Due to presence of chiral carbon a molecule become chiral and it gives optical isomers also that is
All the substituents are different hence is is a chiral carbon and so molecule.

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Chapter 23 Solutions
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- Four liters of an aqueous solution containing 6.98 mg of acetic acid were prepared. At 25°C, the measured conductivity was 5.89x10-3 mS cm-1. Calculate the degree of dissociation of the acid and its ionization constant.Molecular weights: O (15.999), C (12.011), H (1.008).Limiting molar ionic conductivities (λ+0 and λ-0) of Ac-(aq) and H+(aq): 40.9 and 349.8 S cm-2 mol-1.arrow_forwardDetermine the change in Gibbs energy, entropy, and enthalpy at 25°C for the battery from which the data in the table were obtained.T (°C) 15 20 25 30 35Eo (mV) 227.13 224.38 221.87 219.37 216.59Data: n = 1, F = 96485 C mol–1arrow_forwardIndicate the correct options.1. The units of the transport number are Siemens per mole.2. The Siemens and the ohm are not equivalent.3. The Van't Hoff factor is dimensionless.4. Molar conductivity does not depend on the electrolyte concentration.arrow_forward
- Ideally nonpolarizable electrodes can1. participate as reducers in reactions.2. be formed only with hydrogen.3. participate as oxidizers in reactions.4. form open and closed electrochemical systems.arrow_forwardIndicate the options for an electrified interface:1. Temperature has no influence on it.2. Not all theories that describe it include a well-defined electrical double layer.3. Under favorable conditions, its differential capacitance can be determined with the help of experimental measurements.4. A component with high electronic conductivity is involved in its formation.arrow_forwardTo describe the structure of the interface, there are theories or models that can be distinguished by:1. calculation of the charge density.2. distribution of ions in the solution.3. experimentally measured potential difference.4. external Helmoltz plane.arrow_forward
- Indicate the correct options when referring to Luther's equation:1. It is not always easy to compare its results with experimental results.2. It depends on the number of electrons exchanged in the species involved.3. Its foundation is thermodynamic.4. The values calculated with it do not depend on temperature.arrow_forwardIndicate which of the unit options correspond to a measurement of current density.1. A s m-22. mC s-1 m-23. Ω m-24. V J-1 m-2arrow_forwardIndicate the options that are true when referring to electrode membranes:1. The Donnan potential, in general, does not always intervene in membranes.2. There are several ways to classify the same membrane.3. Any membrane can be used to determine the pH of a solution.4. Only one solution and one membrane are needed to determine the pH of that solution.arrow_forward
- Calculate the maximum volume of carbon dioxide gasarrow_forwardIn galvanic cells, their potential1. can be measured with a potentiometer2. does not depend on the equilibrium constant of the reaction occurring within them3. is only calculated from the normal potentials of the electrodes they comprise4. can sometimes be considered a variation in a potential differencearrow_forwardIf some molecules in an excited state collide with other molecules in a ground state, this process1. can occur in solution and in the gas phase.2. can be treated as a bimolecular process.3. always results in collisional deactivation.4. does not compete with any other process.arrow_forward
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