(a) Interpretation: Mechanism leading to the major organic product(s) for the given reaction is to be drawn. Concept introduction: In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile ( C-Nu ) . In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place. In the case of proton transfer reaction, a proton is abstracted by the electronegative atom like oxygen. If benzyne intermediate is symmetrical then only one product is formed.

Question

Want to see the full answer?

Answer 1

Question

Chapter 23, Problem 23.77P

Interpretation Introduction

(a)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, a proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is symmetrical then only one product is formed.

Interpretation Introduction

(b)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of the proton transfer reaction, the proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Interpretation Introduction

(c)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, the proton is abstracted by the electronegative atom like nitrogen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

NH (aq)+CNO (aq) → CO(NH2)2(s) Experiment [NH4] (M) [CNO] (M) Initial rate (M/s) 1 0.014 0.02 0.002 23 0.028 0.02 0.008 0.014 0.01 0.001 Calculate the rate contant for this reaction using the data provided in the table.

2CIO2 + 20H-1 CIO31 + CIO2 + H2O Experiment [CIO2], M [OH-1], M 1 0.0500 0.100 23 2 0.100 0.100 3 0.100 0.0500 Initial Rate, M/s 0.0575 0.230 0.115 ... Given this date, calculate the overall order of this reaction.

2 3 .(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I Experiment [1-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 0.000069 4 0.0025 0.0025 0.000140 Calculate the rate constant of this reaction using the table data.

Answer 2

Question

Chapter 23, Problem 23.77P

Interpretation Introduction

(a)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, a proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is symmetrical then only one product is formed.

Interpretation Introduction

(b)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of the proton transfer reaction, the proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Interpretation Introduction

(c)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, the proton is abstracted by the electronegative atom like nitrogen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 23, Problem 23.77P

Interpretation Introduction

(a)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, a proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is symmetrical then only one product is formed.

Interpretation Introduction

(b)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of the proton transfer reaction, the proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Interpretation Introduction

(c)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, the proton is abstracted by the electronegative atom like nitrogen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 23, Problem 23.77P

Interpretation Introduction

(a)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, a proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is symmetrical then only one product is formed.

Interpretation Introduction

(b)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of the proton transfer reaction, the proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Interpretation Introduction

(c)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, the proton is abstracted by the electronegative atom like nitrogen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 23, Problem 23.77P

Interpretation Introduction

(a)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, a proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is symmetrical then only one product is formed.

Interpretation Introduction

(b)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of the proton transfer reaction, the proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Interpretation Introduction

(c)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, the proton is abstracted by the electronegative atom like nitrogen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Answer 6

Chapter 23, Problem 23.77P

Interpretation Introduction

(a)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, a proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is symmetrical then only one product is formed.

Answer 7

Chapter 23, Problem 23.77P

Interpretation Introduction

(a)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, a proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is symmetrical then only one product is formed.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of the proton transfer reaction, the proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of the proton transfer reaction, the proton is abstracted by the electronegative atom like oxygen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, the proton is abstracted by the electronegative atom like nitrogen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Mechanism leading to the major organic product(s) for the given reaction is to be drawn.

Concept introduction:

In the nucleophile addition step, nucleophile attacked on electrophilic carbon. In this step new bond is formed between carbon and nucleophile (C-Nu).

In the nucleophile elimination step, a good leaving group like halogens is removed and the formation of a double bond takes place.

In the case of proton transfer reaction, the proton is abstracted by the electronegative atom like nitrogen.

If benzyne intermediate is not symmetrical then more than one product is formed.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Want to see the full answer?

Chapter 23 Solutions