ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
9th Edition
ISBN: 9780134645704
Author: WADE AND SIMEK
Publisher: PEARSON
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Chapter 23, Problem 23.47SP

(a)

Interpretation Introduction

To draw: The chair conformation of β-D-mannopyranose.

Interpretation: The chair conformation of β-D-mannopyranose is to be drawn.

Concept introduction: Cyclic monosaccharides are drawn with the help of Fisher projection. The groups on the right side of fisher projection are projected downwards in the cyclic structure while groups on the left side are projected upwards. In Haworth projection or chair conformation, oxygen is present at the back, right-hand corner with C1 at the far right.

(b)

Interpretation Introduction

To draw: The chair conformation of α-D-allopyranose.

Interpretation: The chair conformation of α-D-allopyranose is to be drawn.

Concept introduction: Cyclic monosaccharides are drawn with the help of Fisher projection. The groups on the right side of fisher projection are projected downwards in the cyclic structure while groups on the left side are projected upwards. In Haworth projection or chair conformation, oxygen is present at the back, right-hand corner with C1 at the far right.

(c)

Interpretation Introduction

To draw: The chair conformation of β-D-galactopyranose.

Interpretation: The chair conformation of β-D-galactopyranose is to be drawn.

Concept introduction: Cyclic monosaccharides are drawn with the help of Fisher projection. The groups on the right side of fisher projection are projected downwards in the cyclic structure while groups on the left side are projected upwards. In Haworth projection or chair conformation, oxygen is present at the back, right-hand corner with C1 at the far right.

(d)

Interpretation Introduction

To draw: The chair conformation of N-acetylglucosamine.

Interpretation: The chair conformation of N-acetylglucosamine is to be drawn.

Concept introduction: Cyclic monosaccharides are drawn with the help of Fisher projection. The groups on the right side of fisher projection are projected downwards in the cyclic structure while groups on the left side are projected upwards. In Haworth projection or chair conformation, oxygen is present at the back, right-hand corner with C1 at the far right.

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Chapter 23 Solutions

ORGANIC CHEMISTRY

Ch. 23.4 - Prob. 23.11PCh. 23.5 - Prob. 23.12PCh. 23.5 - Prob. 23.13PCh. 23.6 - Prob. 23.14PCh. 23.6 - Prob. 23.15PCh. 23.7 - Prob. 23.16PCh. 23.7 - Prob. 23.17PCh. 23.7 - Two sugars, A and B, are known to be glucose and...Ch. 23.7 - Prob. 23.19PCh. 23.8 - Prob. 23.20PCh. 23.8 - Prob. 23.21PCh. 23.8 - Prob. 23.22PCh. 23.8 - Prob. 23.23PCh. 23.8 - Prob. 23.24PCh. 23.9 - a. Show the product that results when fructose is...Ch. 23.9 - Prob. 23.26PCh. 23.9 - Prob. 23.27PCh. 23.9 - Prob. 23.28PCh. 23.10 - Prob. 23.29PCh. 23.10 - Prob. 23.30PCh. 23.10 - Prob. 23.31PCh. 23.11 - Prob. 23.32PCh. 23.11 - The Wohl degradation, an alternative to the Ruff...Ch. 23.11 - Prob. 23.34PCh. 23.11 - Prob. 23.35PCh. 23.12A - Prob. 23.36PCh. 23.12A - Give an equation to show the reduction of Tollens...Ch. 23.12A - Prob. 23.38PCh. 23.12B - Prob. 23.39PCh. 23.12C - Prob. 23.40PCh. 23.12C - Prob. 23.41PCh. 23.13A - Prob. 23.42PCh. 23.15 - Cytosine, uracil, and guanine have tautomeric...Ch. 23.15 - a. An aliphatic aminoglycoside is relatively...Ch. 23.16C - Prob. 23.45PCh. 23 - Prob. 23.46SPCh. 23 - Prob. 23.47SPCh. 23 - Prob. 23.48SPCh. 23 - Prob. 23.49SPCh. 23 - Prob. 23.50SPCh. 23 - Prob. 23.51SPCh. 23 - Prob. 23.52SPCh. 23 - Prob. 23.53SPCh. 23 - Prob. 23.54SPCh. 23 - Prob. 23.55SPCh. 23 - Prob. 23.56SPCh. 23 - Prob. 23.57SPCh. 23 - Prob. 23.58SPCh. 23 - Prob. 23.59SPCh. 23 - Prob. 23.60SPCh. 23 - Prob. 23.61SPCh. 23 - Prob. 23.62SPCh. 23 - Prob. 23.63SPCh. 23 - Draw the structure of a four-residue segment of...Ch. 23 - Retroviruses like HIV, the pathogen responsible...Ch. 23 - Prob. 23.66SPCh. 23 - Prob. 23.67SP
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