
Concept explainers
(a)
Interpretation:
The Fisher projection of the open chain of glucose is to be drawn.
Concept introduction:
The most abundant monsaccharide is glucose. Six carbon atoms are present in the Fisher projection of the open chain of glucose. Fisher projections are used to represent the open chain form of sugars.
(a)

Answer to Problem 23.46SP
The Fisher projection of the open chain of glucose is shown in Figure 1.
Explanation of Solution
The Fisher projection of the open chain of glucose is shown below. Glucose is an aldose because it a sugar with an
Figure 1
(b)
Interpretation:
The most stable conformation of the most stable pyranose anomer is to be drawn.
Concept introduction:
Cyclic monosaccharides are drawn with the help of Fisher projection. The groups on the right side of fisher projection are down in the cyclic structure while groups on the left side are up.
(b)

Answer to Problem 23.46SP
The most stable conformation of the most stable pyranose anomer is shown in Figure 2.
Explanation of Solution
The most stable conformation of the most stable pyranose anomer is shown in Figure 2. In
Figure 2
(c)
Interpretation:
The most stable conformation of the most stable pyranose anomer is to be drawn.
Concept introduction:
Cyclic monosaccharides are drawn with the help of Fisher projection. The groups on the right side of fisher projection are down in the cyclic structure while groups on the left side are up.
(c)

Answer to Problem 23.46SP
The Haworth projection of the most stable pyranose anomer is shown in Figure 3.
Explanation of Solution
The Haworth projection of the most stable pyranose anomer is shown below.
Figure 3
Want to see more full solutions like this?
Chapter 23 Solutions
ORGANIC CHEMISTRY
- The acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBTarrow_forwardWhat does the phrase 'fit for purpose' mean in relation to analytical chemistry? Please provide examples too.arrow_forwardFor each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects Resonance Effects Overall Electron-Density × NO2 ○ donating O donating O withdrawing O withdrawing O electron-rich electron-deficient no inductive effects O no resonance effects O similar to benzene E [ CI O donating withdrawing O no inductive effects Explanation Check ○ donating withdrawing no resonance effects electron-rich electron-deficient O similar to benzene © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Accesarrow_forward
- Understanding how substituents activate Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation HN NH2 Check X (Choose one) (Choose one) (Choose one) (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Aarrow_forwardIdentifying electron-donating and electron-withdrawing effects on benzene For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Inductive Effects Resonance Effects Overall Electron-Density Molecule CF3 O donating O donating O withdrawing O withdrawing O no inductive effects O no resonance effects electron-rich electron-deficient O similar to benzene CH3 O donating O withdrawing O no inductive effects O donating O withdrawing Ono resonance effects O electron-rich O electron-deficient O similar to benzene Explanation Check Х © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forward* Hint: Think back to Chem 1 solubility rules. Follow Up Questions for Part B 12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant for the forward reaction? Explain. (4 pts) a) Changing the concentration of a reactant or product. (2 pts) b) Changing the temperature of an exothermic reaction. (2 pts) ofarrow_forward
- Draw TWO general chemical equation to prepare Symmetrical and non-Symmetrical ethers Draw 1 chemical reaction of an etherarrow_forwardPlease help me with the following questions for chemistry.arrow_forwardDraw the chemical structure [OR IUPAC name] of the following: a- m-chloromethoxybenzene b.arrow_forward
- Show by chemical equation the reaction of [HCN] and [CH3MgBr] with any alarrow_forwardGive the chemical equation for the preparation of: -Any aldehyde -Any keytonearrow_forward+ C8H16O2 (Fatty acid) + 11 02 → 8 CO2 a. Which of the above are the reactants? b. Which of the above are the products? H2o CO₂ c. Which reactant is the electron donor? Futty acid d. Which reactant is the electron acceptor? e. Which of the product is now reduced? f. Which of the products is now oxidized? 02 #20 102 8 H₂O g. Where was the carbon initially in this chemical reaction and where is it now that it is finished? 2 h. Where were the electrons initially in this chemical reaction and where is it now that it is finished?arrow_forward
- World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningGeneral, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,





