
Concept explainers
(a)
Interpretation:
Nitrogen atom that is a more basic among the two nitrogen atoms present in epibatidine has to be explained.
Concept introduction:
Depending on the number of carbon side chain of the nitrogen, different types of amines can form.
According to the explanations by Lewis, if a species donates an electron pair then it is a Lewis base whereas if a species receives an electron pair, then it is Lewis acid.
Hybridization is the mixing of valence atomic orbitals to get equivalent hybridized orbitals that having similar characteristics and energy.
(b)
Interpretation:
Chiral centers in epibatidine have to be marked.
Concept Introduction:
Amines are the derivatives of ammonia
Depending on the number of carbon side chain of the nitrogen, different types of amines can form.
Chirality: It refers to an atom in a molecule that contains four different substituents.

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Chapter 23 Solutions
Organic Chemistry
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- Consider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forwardIn a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
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