EBK EXPLORING CHEMICAL ANALYSIS
EBK EXPLORING CHEMICAL ANALYSIS
5th Edition
ISBN: 8220101443908
Author: Harris
Publisher: MAC HIGHER
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Chapter 23, Problem 23.26P
Interpretation Introduction

Interpretation:

Reason behind the reduction in electroosmotic flow in presence of a buffer that contains 1mM MgSO4 and 1mM CaCl2 has to be explained. Cause of restoration of electroosmotic flow in presence of 3mM EDTA has to be suggested.

Concept Introduction:

Electro-osmosis is a kinetic process in which the transport of bulk fluid through a porous membrane under the influence of an electric field is taken place.

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Questions 4 and 5
For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions.  Assume all reagents are in excess unless otherwise indicated.
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