(a) Interpretation: The synthesis of the quaternary ammonium salt ( CH 3 ) 3 N + CH 2 PhBr − from dimethylamine and any other reagents is to be predicted. Concept introduction: The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

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Answer 1

Question

Chapter 23, Problem 23.19P

Interpretation Introduction

(a)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from dimethylamine and any other reagents is to be predicted.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from benzylamine and any other reagents is to be stated.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below: QUESTION: Summarise and report these results including an indication of measurement uncertainty. In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical). Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32…

Indicate the rate expressions for reactions that have order 0, 1, and 2.

Answer 2

Question

Chapter 23, Problem 23.19P

Interpretation Introduction

(a)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from dimethylamine and any other reagents is to be predicted.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from benzylamine and any other reagents is to be stated.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

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Answer 3

Question

Chapter 23, Problem 23.19P

Interpretation Introduction

(a)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from dimethylamine and any other reagents is to be predicted.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from benzylamine and any other reagents is to be stated.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

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Answer 4

Question

Chapter 23, Problem 23.19P

Interpretation Introduction

(a)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from dimethylamine and any other reagents is to be predicted.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from benzylamine and any other reagents is to be stated.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

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Answer 5

Chapter 23, Problem 23.19P

Interpretation Introduction

(a)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from dimethylamine and any other reagents is to be predicted.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from benzylamine and any other reagents is to be stated.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

Answer 6

Chapter 23, Problem 23.19P

Interpretation Introduction

(a)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from dimethylamine and any other reagents is to be predicted.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

Answer 7

Chapter 23, Problem 23.19P

Interpretation Introduction

(a)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from dimethylamine and any other reagents is to be predicted.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from benzylamine and any other reagents is to be stated.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The synthesis of the quaternary ammonium salt (CH3)3N+CH2PhBr− from benzylamine and any other reagents is to be stated.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine. The imine is reduced to new amine. In the process of reductive amination the reduction of amine takes place with the gain of electrons by the given compound.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains the process of synthesis of the quaternary ammonium salt from dimethylamine and sodium cyanoborohydride.

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Chapter 23 Solutions