a) Interpretation: The products of the reaction shown are to be given. Concept introduction: Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids. To give: The products of the reaction shown.

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Answer 1

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.SE, Problem 42AP

Interpretation Introduction

a)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids.

To give:

The products of the reaction shown.

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be given.

Concept introduction:

In the first reaction the base abstracts a proton to yield an enolate ion. In the second reaction alkylation takes place.

To give:

The product of the reaction shown.

Interpretation Introduction

c)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

When carboxylic acids are treated with Br₂ and PBr₃, bromination occurs at the carbon Î±- to the carboxyl group and the acid group also is converted into an acyl bromide. When treated with water the acyl bromide gets hydrolyzed to yield the free acid.

To give:

The products of the reaction shown.

Interpretation Introduction

d)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform.

To give:

The products of the reaction shown.

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QUESTION 1 Write the IUPAC names for the following compounds. (a) (b) 2 H₂C CH (c) Br (d) HO (e) COOH

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Part 1. Draw monomer units of the following products and draw their reaction mechanism 1) Bakelite like polymer Using: Resorcinol + NaOH + Formalin 2) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerol 3) Temporary cross-linked polymer Using: 4% polyvinyl alcohol+ methyl red + 4% sodium borate

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.SE, Problem 42AP

Interpretation Introduction

a)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids.

To give:

The products of the reaction shown.

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be given.

Concept introduction:

In the first reaction the base abstracts a proton to yield an enolate ion. In the second reaction alkylation takes place.

To give:

The product of the reaction shown.

Interpretation Introduction

c)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

When carboxylic acids are treated with Br₂ and PBr₃, bromination occurs at the carbon Î±- to the carboxyl group and the acid group also is converted into an acyl bromide. When treated with water the acyl bromide gets hydrolyzed to yield the free acid.

To give:

The products of the reaction shown.

Interpretation Introduction

d)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform.

To give:

The products of the reaction shown.

Expert Solution & Answer

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.SE, Problem 42AP

Interpretation Introduction

a)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids.

To give:

The products of the reaction shown.

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be given.

Concept introduction:

In the first reaction the base abstracts a proton to yield an enolate ion. In the second reaction alkylation takes place.

To give:

The product of the reaction shown.

Interpretation Introduction

c)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

When carboxylic acids are treated with Br₂ and PBr₃, bromination occurs at the carbon Î±- to the carboxyl group and the acid group also is converted into an acyl bromide. When treated with water the acyl bromide gets hydrolyzed to yield the free acid.

To give:

The products of the reaction shown.

Interpretation Introduction

d)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform.

To give:

The products of the reaction shown.

Expert Solution & Answer

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See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.SE, Problem 42AP

Interpretation Introduction

a)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids.

To give:

The products of the reaction shown.

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be given.

Concept introduction:

In the first reaction the base abstracts a proton to yield an enolate ion. In the second reaction alkylation takes place.

To give:

The product of the reaction shown.

Interpretation Introduction

c)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

When carboxylic acids are treated with Br₂ and PBr₃, bromination occurs at the carbon Î±- to the carboxyl group and the acid group also is converted into an acyl bromide. When treated with water the acyl bromide gets hydrolyzed to yield the free acid.

To give:

The products of the reaction shown.

Interpretation Introduction

d)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform.

To give:

The products of the reaction shown.

Expert Solution & Answer

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Answer 5

Chapter 22.SE, Problem 42AP

Interpretation Introduction

a)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids.

To give:

The products of the reaction shown.

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be given.

Concept introduction:

In the first reaction the base abstracts a proton to yield an enolate ion. In the second reaction alkylation takes place.

To give:

The product of the reaction shown.

Interpretation Introduction

c)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

When carboxylic acids are treated with Br₂ and PBr₃, bromination occurs at the carbon Î±- to the carboxyl group and the acid group also is converted into an acyl bromide. When treated with water the acyl bromide gets hydrolyzed to yield the free acid.

To give:

The products of the reaction shown.

Interpretation Introduction

d)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform.

To give:

The products of the reaction shown.

Answer 6

Chapter 22.SE, Problem 42AP

Interpretation Introduction

a)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids.

To give:

The products of the reaction shown.

Answer 7

Chapter 22.SE, Problem 42AP

Interpretation Introduction

a)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids.

To give:

The products of the reaction shown.

Answer 8

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be given.

Concept introduction:

In the first reaction the base abstracts a proton to yield an enolate ion. In the second reaction alkylation takes place.

To give:

The product of the reaction shown.

Answer 9

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown is to be given.

Concept introduction:

In the first reaction the base abstracts a proton to yield an enolate ion. In the second reaction alkylation takes place.

To give:

The product of the reaction shown.

Answer 10

Interpretation Introduction

c)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

When carboxylic acids are treated with Br₂ and PBr₃, bromination occurs at the carbon Î±- to the carboxyl group and the acid group also is converted into an acyl bromide. When treated with water the acyl bromide gets hydrolyzed to yield the free acid.

To give:

The products of the reaction shown.

Answer 11

Interpretation Introduction

c)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

When carboxylic acids are treated with Br₂ and PBr₃, bromination occurs at the carbon Î±- to the carboxyl group and the acid group also is converted into an acyl bromide. When treated with water the acyl bromide gets hydrolyzed to yield the free acid.

To give:

The products of the reaction shown.

Answer 12

Interpretation Introduction

d)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform.

To give:

The products of the reaction shown.

Answer 13

Interpretation Introduction

d)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform.

To give:

The products of the reaction shown.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22.1 - Prob. 1P Ch. 22.1 - How many acidic hydrogens does each of the...Ch. 22.1 - Prob. 3P Ch. 22.3 - Write the complete mechanism for the deuteration...Ch. 22.3 - Prob. 5P Ch. 22.4 - If methanol rather than water is added at the end...Ch. 22.5 - Prob. 7P Ch. 22.5 - Draw a resonance structure of the acetonitrile...Ch. 22.6 - If methanol rather than water is added at the end...Ch. 22.7 - Prob. 10P

a) Interpretation: The products of the reaction shown are to be given. Concept introduction: Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids. To give: The products of the reaction shown.

Solution Summary: The author explains the products of the reaction shown: cyclohexanecarboxylic acid and CO 2.

a)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids.

To give:

The products of the reaction shown.

b)

Interpretation:

The product of the reaction shown is to be given.

Concept introduction:

In the first reaction the base abstracts a proton to yield an enolate ion. In the second reaction alkylation takes place.

To give:

The product of the reaction shown.

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Chapter 22 Solutions

a) Interpretation: The products of the reaction shown are to be given. Concept introduction: Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids. To give: The products of the reaction shown.

Solution Summary: The author explains the products of the reaction shown: cyclohexanecarboxylic acid and CO 2.

a) Interpretation: The products of the reaction shown are to be given. Concept introduction: Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids. To give: The products of the reaction shown.

b) Interpretation: The product of the reaction shown is to be given. Concept introduction: In the first reaction the base abstracts a proton to yield an enolate ion. In the second reaction alkylation takes place. To give: The product of the reaction shown.

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Chapter 22 Solutions

a)

Interpretation:

The products of the reaction shown are to be given.

Concept introduction:

Compounds having two carboxyl groups attached to a carbon readily undergo decarboxylation, when heated, to yield monocarboxylic acids.

To give:

The products of the reaction shown.

b)

Interpretation:

The product of the reaction shown is to be given.

Concept introduction:

In the first reaction the base abstracts a proton to yield an enolate ion. In the second reaction alkylation takes place.

To give:

The product of the reaction shown.