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a)
Interpretation:
Using an alkylation reaction as the key step how the compound shown can be prepared is to be given.
Concept introduction:
An alkylation reaction is used to introduce a methyl or a primary alkyl group in α- position of aTo give:
Using an alkylation reaction as the key step how to prepare the compound shown.
b)
Interpretation:
Using an alkylation reaction as the key step how the compound shown can be prepared.
Concept introduction:
An alkylation reaction is used to introduce a methyl or a primary alkyl group in α- position of a ketone, ester or nitrile by a SN2 reaction of the enolate ion with an alkyl halide. Thus by looking at α- carbon of the product the alkyl halide to be used in the reaction can be identified. The enolate ion can be produced by using lithium diisopropylamide (LDA).
To give:
Using an alkylation reaction as the key step how to prepare the compound shown.
c)
Interpretation:
Using an alkylation reaction as the key step how the compound shown can be prepared.
Concept introduction:
An alkylation reaction is used to introduce a methyl or a primary alkyl group in α- position of a ketone, ester or nitrile by aSN2reaction of the enolate ion with an alkyl halide. Thus by looking at α- carbon of the product the alkyl halide to be used in the reaction can be identified. The enolate ion can be produced by using lithium diisopropylamide (LDA).
To give:
Using an alkylation reaction as the key step how to prepare the compound shown.
d)
Interpretation:
Using an alkylation reaction as the key step how the compound shown can be prepared.
Concept introduction:
An alkylation reaction is used to introduce a methyl or a primary alkyl group in α- position of a ketone, ester or nitrile by a SN2 reaction of the enolate ion with an alkyl halide. Thus by looking at α- carbon of the product the alkyl halide to be used in the reaction can be identified. The enolate ion can be produced by using lithium diisopropylamide (LDA).
To give:
Using an alkylation reaction as the key step how to prepare the compound shown.
e)
Interpretation:
Using an alkylation reaction as the key step how the compound shown can be prepared.
Concept introduction:
An alkylation reaction is used to introduce a methyl or a primary alkyl group in α- position of a ketone, ester or nitrile by a SN2 reaction of the enolate ion with an alkyl halide. Thus by looking at α- carbon of the product the alkyl halide to be used in the reaction can be identified. The enolate ion can be produced by using lithium diisopropylamide (LDA).
To give:
Using an alkylation reaction as the key step how to prepare the compound shown.
f)
Interpretation:
Using an alkylation reaction as the key step how the compound shown can be prepared.
Concept introduction:
An alkylation reaction is used to introduce a methyl or a primary alkyl group in α- position of a ketone, ester or nitrile by a SN2 reaction of the enolate ion with an alkyl halide. Thus by looking at α- carbon of the product the alkyl halide to be used in the reaction can be identified. The enolate ion can be produced by using lithium diisopropylamide (LDA).
To give:
Using an alkylation reaction as the key step how to prepare the compound shown.
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Chapter 22 Solutions
Bundle: Organic Chemistry, 9th, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
- NH2 1. CH3–MgCl 2. H3O+ ? As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new C - C bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new C - C bond. Х ☐: Carrow_forwardPredict the major products of this organic reaction. If there will be no major products, check the box under the drawing area instead. No reaction. : + Х è OH K Cr O 2 27 2 4' 2 Click and drag to start drawing a structure.arrow_forwardLaminar compounds are characterized by havinga) a high value of the internal surface of the solid.b) a high adsorption potential.arrow_forward
- Intercalation compounds have their sheetsa) negatively charged.b) positively charged.arrow_forwardIndicate whether the following two statements are correct or not:- Polythiazine, formed by N and S, does not conduct electricity- Carbon can have a specific surface area of 3000 m2/garrow_forwardIndicate whether the following two statements are correct or not:- The S8 heterocycle is the origin of a family of compounds- Most of the elements that give rise to stable heterocycles belong to group d.arrow_forward
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- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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