ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
8th Edition
ISBN: 9780134595450
Author: Bruice
Publisher: PEARSON
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Chapter 22.12, Problem 22P
The pH–activity profile for glucose-6-phosphate isomerase indicates the participation of a group with a pKa = 6.7 as a basic catalyst and a group with a pKa = 9.3 as an acid catalyst. Draw the pH–activity profile and identify the amino acids that participate in the catalysis.
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Students have asked these similar questions
14. Which one of the compounds
below is the major organic
product obtained from the
following series of reactions?
Br
OH
OH
CH3O™ Na+
H*, H₂O
SN2
HO
OH
A
B
C
D
0
E
Wavelength (nm)
I'm not sure what equation I can come up with other than the one generated with my graph. Can you
please show me the calculations that were used to find this equation?
Give an equation that relates energy to wavelength. Explain how you arrived at your equation.
Wavelength Energy (kJ/mol)
(nm)
350
341.8
420
284.8
470
254.5
530
225.7
580
206.3
620
192.9
700
170.9
750
159.5
Energy vs. Wavelength (Graph 1)
400
350
y=-0.4367x+470.82
300
250
200
150
100
50
O
0
100
200
300
400
500
600
700
800
Energy (kJ/mol)
5. Draw molecular orbital diagrams for superoxide (O2¯), and peroxide (O2²-). A good starting
point would be MO diagram for O2 given in your textbook. Then: a) calculate bond orders in
superoxide and in peroxide; indicate which species would have a stronger oxygen-oxygen bond;
b) indicate which species would be a radical.
(4 points)
Chapter 22 Solutions
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
Ch. 22.2 - Compare each of the mechanisms listed here with...Ch. 22.2 - Prob. 3PCh. 22.2 - Prob. 4PCh. 22.3 - a. Draw the mechanism for the following reaction...Ch. 22.5 - Prob. 7PCh. 22.5 - Propose a mechanism for the Co2+ catalyzed...Ch. 22.6 - Prob. 9PCh. 22.7 - Prob. 10PCh. 22.7 - Prob. 12PCh. 22.7 - Prob. 13P
Ch. 22.9 - Which of the following amino acid side chains can...Ch. 22.9 - Which of the following C-terminal peptide bonds is...Ch. 22.9 - Carboxypeptidase A has esterase activity as well...Ch. 22.10 - Arginine and lysine side chains fit into trypsins...Ch. 22.10 - Explain why serine proteases do not catalyze...Ch. 22.11 - If H2 18O is used in the hydrolysis reaction...Ch. 22.11 - Draw the pH-activity profile for an enzyme that...Ch. 22.12 - The pHactivity profile for glucose-6-phosphate...Ch. 22.12 - Prob. 23PCh. 22.13 - Draw the mechanism for the hydroxide ion-catalyzed...Ch. 22.13 - What advantage does the enzyme gain by forming an...Ch. 22.13 - Prob. 26PCh. 22.13 - Prob. 27PCh. 22.13 - Aldolase shows no activity if it is incubated with...Ch. 22 - Which of the following parameters would be...Ch. 22 - Prob. 29PCh. 22 - Prob. 30PCh. 22 - Prob. 31PCh. 22 - Indicate the type of catalysis that is occurring...Ch. 22 - The deuterium kinetic isotope effect (KH2O/KD2O)...Ch. 22 - Prob. 34PCh. 22 - Co2+ catalyzes the hydrolysis of the lactam shown...Ch. 22 - there are two kinds of aldolases. Class I...Ch. 22 - Prob. 37PCh. 22 - The hydrolysis of the ester shown here is...Ch. 22 - Prob. 39PCh. 22 - At pH = 12, the rate of hydrolysis of ester A is...Ch. 22 - 2-Acetoxycyclohexyl tosylate reacts with acetate...Ch. 22 - Proof that an imine was formed between aldolase...Ch. 22 - Prob. 43PCh. 22 - a. Explain why the alkyl halide shown here reacts...Ch. 22 - Triosephosphate isomerase (TIM) catalyzes the...
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- Wavelength (nm) I'm not sure what equation I can come up with other than the one generated with my graph. Can you please show me the calculations that were used to find this equation? Give an equation that relates energy to wavelength. Explain how you arrived at your equation. Wavelength Energy (kJ/mol) (nm) 350 341.8 420 284.8 470 254.5 530 225.7 580 206.3 620 192.9 700 170.9 750 159.5 Energy vs. Wavelength (Graph 1) 400 350 y=-0.4367x+470.82 300 250 200 150 100 50 O 0 100 200 300 400 500 600 700 800 Energy (kJ/mol)arrow_forward6. For the following molecules: draw Lewis dot-structures; use VSEPR method to determine geometries of the following molecules/ions. Are the central atoms in these molecules/ions considered of normal valency, or are they hypervalent? (please read paragraph 2.6) a) BrF3 (6 points) b) BrF4 c) IF₂ 4arrow_forwardNonearrow_forward
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