8th Edition

ISBN: 9780134595450

Author: Bruice

Publisher: PEARSON

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A class of organic compounds needed in the human body for normal activities is known as vitamins. They are characterized into two parts depending upon their solubility in water. They can act as coenzymes, cofactors, or prosthetic groups for enzymes.

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Textbook Question

Chapter 22, Problem 42P

Proof that an imine was formed between aldolase and its substrate was obtained by using D-fructose-1,6-bisphosphate labeled at the C-2 position with ^l4C as the substrate. NaBH₄ was added to the reaction mixture. A radioactive product was isolated from the reaction mixture and hydrolyzed in an acidic solution. Draw the structure of the radioactive product obtained from the acidic solution. (Hint: NaBH₄ reduces an imine linkage.)

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Chapter 22, Problem 41P

Chapter 22, Problem 43P

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Chapter 22 Solutions

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL

Ch. 22.2 - Compare each of the mechanisms listed here with...Ch. 22.2 - Prob. 3P Ch. 22.2 - Prob. 4P Ch. 22.3 - a. Draw the mechanism for the following reaction...Ch. 22.5 - Prob. 7P Ch. 22.5 - Propose a mechanism for the Co2+ catalyzed...Ch. 22.6 - Prob. 9P Ch. 22.7 - Prob. 10P Ch. 22.7 - Prob. 12P Ch. 22.7 - Prob. 13P

Ch. 22.9 - Which of the following amino acid side chains can...Ch. 22.9 - Which of the following C-terminal peptide bonds is...Ch. 22.9 - Carboxypeptidase A has esterase activity as well...Ch. 22.10 - Arginine and lysine side chains fit into trypsins...Ch. 22.10 - Explain why serine proteases do not catalyze...Ch. 22.11 - If H2 18O is used in the hydrolysis reaction...Ch. 22.11 - Draw the pH-activity profile for an enzyme that...Ch. 22.12 - The pHactivity profile for glucose-6-phosphate...Ch. 22.12 - Prob. 23P Ch. 22.13 - Draw the mechanism for the hydroxide ion-catalyzed...Ch. 22.13 - What advantage does the enzyme gain by forming an...Ch. 22.13 - Prob. 26P Ch. 22.13 - Prob. 27P Ch. 22.13 - Aldolase shows no activity if it is incubated with...Ch. 22 - Which of the following parameters would be...Ch. 22 - Prob. 29P Ch. 22 - Prob. 30P Ch. 22 - Prob. 31P Ch. 22 - Indicate the type of catalysis that is occurring...Ch. 22 - The deuterium kinetic isotope effect (KH2O/KD2O)...Ch. 22 - Prob. 34P Ch. 22 - Co2+ catalyzes the hydrolysis of the lactam shown...Ch. 22 - there are two kinds of aldolases. Class I...Ch. 22 - Prob. 37P Ch. 22 - The hydrolysis of the ester shown here is...Ch. 22 - Prob. 39P Ch. 22 - At pH = 12, the rate of hydrolysis of ester A is...Ch. 22 - 2-Acetoxycyclohexyl tosylate reacts with acetate...Ch. 22 - Proof that an imine was formed between aldolase...Ch. 22 - Prob. 43P Ch. 22 - a. Explain why the alkyl halide shown here reacts...Ch. 22 - Triosephosphate isomerase (TIM) catalyzes the...

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