The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified. Concept Introduction : Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes. To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (a) Determine the ring which is more strongly activated

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Answer 1

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Chapter 22.11, Problem 27PTS

(a)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (a)

Determine the ring which is more strongly activated

(b)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (b)

Determine the ring which is more strongly activated

(c)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (c)

Determine the ring which is more strongly activated

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Answer 2

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Chapter 22.11, Problem 27PTS

(a)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (a)

Determine the ring which is more strongly activated

(b)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (b)

Determine the ring which is more strongly activated

(c)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (c)

Determine the ring which is more strongly activated

Expert Solution & Answer

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Answer 3

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Chapter 22.11, Problem 27PTS

(a)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (a)

Determine the ring which is more strongly activated

(b)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (b)

Determine the ring which is more strongly activated

(c)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (c)

Determine the ring which is more strongly activated

Expert Solution & Answer

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Answer 4

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Chapter 22.11, Problem 27PTS

(a)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (a)

Determine the ring which is more strongly activated

(b)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (b)

Determine the ring which is more strongly activated

(c)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (c)

Determine the ring which is more strongly activated

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Answer 5

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Answer 6

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Answer 7

Chapter 22.11, Problem 27PTS

(a)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (a)

Determine the ring which is more strongly activated

(b)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (b)

Determine the ring which is more strongly activated

(c)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (c)

Determine the ring which is more strongly activated

Answer 8

Chapter 22.11, Problem 27PTS

(a)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (a)

Determine the ring which is more strongly activated

Answer 9

Chapter 22.11, Problem 27PTS

(a)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (a)

Determine the ring which is more strongly activated

Answer 10

(b)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (b)

Determine the ring which is more strongly activated

Answer 11

(b)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (b)

Determine the ring which is more strongly activated

Answer 12

(c)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (c)

Determine the ring which is more strongly activated

Answer 13

(c)

Interpretation Introduction

Interpretation: The given sets of azo dyes have to be prepared via an azo coupling reaction using the corresponding reactants which have to be identified.

Concept Introduction:

Aryldiazonium salts on coupling with an activated aromatic ring give an azo dye which produces a deep color in the final product. This color is due to the extended conjugation in it. This reaction occurs by electrophilic substitution reaction. This method is called an azo coupling. The obtained final compound is known as azo dyes.

To find: Identify the reactants involved in the given product of azo dye via an azo coupling reaction (c)

Determine the ring which is more strongly activated

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22.2 - Prob. 1LTS Ch. 22.2 - Prob. 1PTS Ch. 22.2 - Prob. 2PTS Ch. 22.3 - Prob. 4CC Ch. 22.3 - Prob. 5CC Ch. 22.3 - Prob. 6CC Ch. 22.3 - Prob. 7CC Ch. 22.3 - Prob. 8CC Ch. 22.3 - Prob. 9CC Ch. 22.4 - Prob. 10CC

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Chapter 22 Solutions