Chemistry: The Central Science, Books a la Carte Edition & Modified Mastering Chemistry with Pearson eText -- ValuePack Access Card Package
1st Edition
ISBN: 9780133910919
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 22, Problem 9E
Cyclopentadiene (C5H6) reacts with itself to form dicyclopentadiene (C10H12). A 0.0400 M solution of C5H6 was monitored as a function of time as the reaction 2 C5H6 was monitored as a function of time as the reaction 2 C5H6 → C10H12 preceded. The following data were collected.
| Time(s) | [C5H6] (M) |
| 0.0 | 0.0400 |
| 50.0 | 0.0300 |
| 100.0 | 0.0240 |
| 150.0 | 0.0200 |
| 200.0 | 0.0174 |
Plot [C5H6] versus time, In [C5H6] versus time, and 1/ [C5H6] versus time. (a) what is the order of the reaction? (b) What is the value of the rate constant?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling
point, choose 2 next to the substance with the next highest boiling point, and so on.
substance
C
D
chemical symbol,
chemical formula
or Lewis structure.
CH,-N-CH,
CH,
H
H 10: H
C-C-H
H H H
Cale
H 10:
H-C-C-N-CH,
Bri
CH,
boiling point
(C)
Сен
(C) B
(Choose
Please help me find the 1/Time, Log [I^-] Log [S2O8^2-], Log(time) on the data table. With calculation steps. And the average for runs 1a-1b. Please help me thanks in advance. Will up vote!
Q1: Answer the questions for the reaction below:
..!! Br
OH
a) Predict the product(s) of the reaction.
b) Is the substrate optically active? Are the product(s) optically active as a mix?
c) Draw the curved arrow mechanism for the reaction.
d) What happens to the SN1 reaction rate in each of these instances:
1. Change the substrate to
Br
"CI
2. Change the substrate to
3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF
4. Increase the substrate concentration by 3-fold.
Chapter 22 Solutions
Chemistry: The Central Science, Books a la Carte Edition & Modified Mastering Chemistry with Pearson eText -- ValuePack Access Card Package
Ch. 22.1 - Prob. 21.1.1PECh. 22.1 - Prob. 21.1.2PECh. 22.1 - Prob. 21.2.1PECh. 22.1 - Prob. 21.2.2PECh. 22.3 - At 25 ° C, the decomposition of dinitrogen...Ch. 22.3 - Practice Exercise 2 The decomposition of dimethyl...Ch. 22.4 - Practice Exercise 1 For a certain reaction A ...Ch. 22.4 - Prob. 21.4.2PECh. 22.7 - Prob. 21.7.1PECh. 22.7 - Prob. 21.7.2PE
Ch. 22.10 - Prob. 21.10.1PECh. 22.10 - Prob. 21.10.2PECh. 22.10 - Prob. 21.7.1PECh. 22.10 - Prob. 21.7.2PECh. 22 - Prob. 1DECh. 22 - Prob. 1ECh. 22 - Prob. 2ECh. 22 - Prob. 3ECh. 22 - Prob. 4ECh. 22 - The gas-phase reaction CL (g) + HBr (g) + HCl (g)...Ch. 22 - What is the molecularity of each of the following...Ch. 22 - Prob. 7ECh. 22 - Prob. 8ECh. 22 - Cyclopentadiene (C5H6) reacts with itself to form...Ch. 22 - Practice Exercise 1 An Alternative two-step...Ch. 22 - Prob. 11ECh. 22 - Practice Exercise 1
Consider the...Ch. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Prob. 15ECh. 22 - Prob. 16ECh. 22 - You study the rate of a reaction, measuring both...Ch. 22 - Suppose that for the reaction K+L M, you monitor...Ch. 22 - Prob. 19ECh. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - The following graph shows two different reaction...Ch. 22 - Prob. 23ECh. 22 - Prob. 24ECh. 22 - Prob. 25ECh. 22 - Prob. 26ECh. 22 - Prob. 27ECh. 22 - Prob. 28ECh. 22 - Prob. 29ECh. 22 - Prob. 30ECh. 22 - Prob. 31ECh. 22 - Prob. 32ECh. 22 - Prob. 33ECh. 22 - Prob. 34ECh. 22 - Prob. 35ECh. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Prob. 39ECh. 22 - Prob. 40ECh. 22 - Prob. 41ECh. 22 - Prob. 42ECh. 22 - Prob. 43ECh. 22 - Prob. 44ECh. 22 - Prob. 45ECh. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - Prob. 49ECh. 22 - Prob. 50ECh. 22 - Prob. 51ECh. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Prob. 58ECh. 22 - Prob. 59ECh. 22 - Prob. 60ECh. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Prob. 71ECh. 22 - Prob. 72ECh. 22 - Prob. 73ECh. 22 - Prob. 74ECh. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - Prob. 79ECh. 22 - Prob. 80ECh. 22 - Prob. 81AECh. 22 - Prob. 82AECh. 22 - Prob. 83AECh. 22 - Prob. 84AECh. 22 - Prob. 85AECh. 22 - Prob. 86AECh. 22 - Prob. 87AECh. 22 - Prob. 88AECh. 22 - Prob. 89AECh. 22 - Prob. 90AECh. 22 - Prob. 91AECh. 22 - Prob. 92IECh. 22 - Prob. 93IECh. 22 - Prob. 94IECh. 22 - Prob. 95IECh. 22 - Prob. 96IECh. 22 - Prob. 97IECh. 22 - Prob. 98IECh. 22 - Prob. 99IECh. 22 - Prob. 100IECh. 22 - Prob. 101IECh. 22 - Prob. 102IECh. 22 - Prob. 103IECh. 22 - Prob. 104IECh. 22 - Prob. 105IECh. 22 - Prob. 106IECh. 22 - Prob. 107IE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Experiment 27 hates & Mechanisms of Reations Method I visual Clock Reaction A. Concentration effects on reaction Rates Iodine Run [I] mol/L [S₂082] | Time mo/L (SCC) 0.04 54.7 Log 1/ Time Temp Log [ ] 13,20] (time) / [I] 199 20.06 23.0 30.04 0.04 0.04 80.0 22.8 45 40.02 0.04 79.0 21.6 50.08 0.03 51.0 22.4 60-080-02 95.0 23.4 7 0.08 0-01 1970 23.4 8 0.08 0.04 16.1 22.6arrow_forward(15 pts) Consider the molecule B2H6. Generate a molecular orbital diagram but this time using a different approach that draws on your knowledge and ability to put concepts together. First use VSEPR or some other method to make sure you know the ground state structure of the molecule. Next, generate an MO diagram for BH2. Sketch the highest occupied and lowest unoccupied MOs of the BH2 fragment. These are called frontier orbitals. Now use these frontier orbitals as your basis set for producing LGO's for B2H6. Since the BH2 frontier orbitals become the LGOS, you will have to think about what is in the middle of the molecule and treat its basis as well. Do you arrive at the same qualitative MO diagram as is discussed in the book? Sketch the new highest occupied and lowest unoccupied MOs for the molecule (B2H6).arrow_forwardQ8: Propose an efficient synthesis of cyclopentene from cyclopentane.arrow_forward
- Q7: Use compound A-D, design two different ways to synthesize E. Which way is preferred? Please explain. CH3I ONa NaOCH 3 A B C D E OCH3arrow_forwardPredict major product(s) for the following reactions. Note the mechanism(s) of the reactions (SN1, E1, SN2 or E2).arrow_forward(10 pts) The density of metallic copper is 8.92 g cm³. The structure of this metal is cubic close-packed. What is the atomic radius of copper in copper metal?arrow_forward
- Predict major product(s) for the following reactions. Note the mechanism(s) of the reactions (SN1, E1, SN2 or E2).arrow_forwardPredict major product(s) for the following reactions. Note the mechanism(s) of the reactions (SN1, E1, SN2 or E2).arrow_forwardQ3: Rank the following compounds in increasing reactivity of E1 and E2 eliminations, respectively. Br ca. go do A CI CI B C CI Darrow_forward
- Q5: Predict major product(s) for the following reactions. Note the mechanism(s) of the reactions (SN1, E1, SN2 or E2). H₂O דיי "Br KN3 CH3CH2OH NaNH2 NH3 Page 3 of 6 Chem 0310 Organic Chemistry 1 HW Problem Sets CI Br excess NaOCH 3 CH3OH Br KOC(CH3)3 DuckDuckGarrow_forwardQ4: Circle the substrate that gives a single alkene product in a E2 elimination. CI CI Br Brarrow_forwardPlease calculate the chemical shift of each protonsarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY