EBK STUDY GUIDE TO ACCOMPANY CHEMISTRY:
7th Edition
ISBN: 9781119360889
Author: HYSLOP
Publisher: VST
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Question
Chapter 22, Problem 94RQ
Interpretation Introduction
Interpretation:
The saturated compounds are to be identified from the given list of compounds.
Concept Information:
Saturated compounds are the type of compounds that contain carbon chains with single bonds, like
Unsaturated compounds are those compounds which are composed of carbon with double or triple bonds, like
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Chapter 22 Solutions
EBK STUDY GUIDE TO ACCOMPANY CHEMISTRY:
Ch. 22 - Prob. 1PECh. 22 - Prob. 2PECh. 22 - Prob. 3PECh. 22 - Practice Exercise 22.4
Write the IUPAC names of...Ch. 22 - Oxidation of an alcohol gave the following...Ch. 22 - Prob. 6PECh. 22 - Prob. 7PECh. 22 - Prob. 8PECh. 22 - Prob. 9PECh. 22 - Prob. 10PE
Ch. 22 - Complete the following equation by drawing...Ch. 22 - Prob. 12PECh. 22 - Prob. 13PECh. 22 - Prob. 14PECh. 22 - Prob. 15PECh. 22 - Label the hydrophobic and hydrophilic portions of...Ch. 22 - Draw a ribose ring and a deoxyribose ring. What is...Ch. 22 - Practice Exercise 22.18
Which base pairs match in...Ch. 22 - Prob. 1RQCh. 22 - Prob. 2RQCh. 22 - Prob. 3RQCh. 22 - Prob. 4RQCh. 22 - Prob. 5RQCh. 22 - Prob. 6RQCh. 22 - Prob. 7RQCh. 22 - Which of the following compounds has the higher...Ch. 22 - In general terms, why do functional groups impart...Ch. 22 - Prob. 10RQCh. 22 - What is the difference between geometric isomers...Ch. 22 - Prob. 12RQCh. 22 - No number is needed to identify the location of...Ch. 22 - Prob. 14RQCh. 22 - Prob. 15RQCh. 22 - Prob. 16RQCh. 22 - 22.17 In general terms, why doesn't benzene...Ch. 22 - Prob. 18RQCh. 22 - 22.19 Explain why is more soluble in water than ....Ch. 22 - Prob. 20RQCh. 22 - Prob. 21RQCh. 22 - Why do aldehydes and ketones have boiling points...Ch. 22 - Acetic acid boils at 118C, higher even than...Ch. 22 - Methyl ethanoate has many more atoms than its...Ch. 22 - Prob. 25RQCh. 22 - 22.26 Write condensed structures of the following...Ch. 22 - 3-Butanol is not a proper name, but a structure...Ch. 22 - Prob. 28RQCh. 22 - Prob. 29RQCh. 22 - Prob. 30RQCh. 22 - Prob. 31RQCh. 22 - Prob. 32RQCh. 22 - Amines, RNH2, do not have boiling points as high...Ch. 22 - A monofunctional organic nitrogen compound...Ch. 22 - Prob. 35RQCh. 22 - Prob. 36RQCh. 22 - Prob. 37RQCh. 22 - Write the products that can be expected to form in...Ch. 22 - Prob. 39RQCh. 22 - Prob. 40RQCh. 22 - 22.41 What do we mean by the term polymer...Ch. 22 - Prob. 42RQCh. 22 - Prob. 43RQCh. 22 - Prob. 44RQCh. 22 - Prob. 45RQCh. 22 - Prob. 46RQCh. 22 - Prob. 47RQCh. 22 - Prob. 48RQCh. 22 - Prob. 49RQCh. 22 - Prob. 50RQCh. 22 - Prob. 51RQCh. 22 - Prob. 52RQCh. 22 - Prob. 53RQCh. 22 - Prob. 54RQCh. 22 - Prob. 55RQCh. 22 - Prob. 56RQCh. 22 - Prob. 57RQCh. 22 - Prob. 58RQCh. 22 - What are the three fundamental needs for...Ch. 22 - Prob. 60RQCh. 22 - Prob. 61RQCh. 22 - Prob. 62RQCh. 22 - Name the compounds that form when sucrose is...Ch. 22 - Prob. 64RQCh. 22 - Prob. 65RQCh. 22 - Prob. 66RQCh. 22 - Prob. 67RQCh. 22 - 22.68 What function is served by glycogen in the...Ch. 22 - How are lipids defined?Ch. 22 - Why are lipids more soluble than carbohydrates in...Ch. 22 - 22.71 Cholesterol is not an ester, yet it is...Ch. 22 - A product such as corn oil is advertised as...Ch. 22 - Is it likely that the following compound could be...Ch. 22 - Describe the specific ways in which the monomers...Ch. 22 - What is the peptide bond? How is it similar to the...Ch. 22 - Prob. 76RQCh. 22 - Prob. 77RQCh. 22 - Why is a distinction made between the terms...Ch. 22 - Prob. 79RQCh. 22 - What kind of substance makes up most enzymes?Ch. 22 - Prob. 81RQCh. 22 - Prob. 82RQCh. 22 - Prob. 83RQCh. 22 - 22.84 How are the two DNA strands in a double...Ch. 22 - In what ways do DNA and RNA differ structurally.Ch. 22 - 22.86 Which base pairs with
Ch. 22 - The process of transcription begins with which...Ch. 22 - The process of translation begins with which...Ch. 22 - Prob. 89RQCh. 22 - 22.90 Write full (expanded) structures for each of...Ch. 22 - Prob. 91RQCh. 22 - Prob. 92RQCh. 22 - Prob. 93RQCh. 22 - Prob. 94RQCh. 22 - Prob. 95RQCh. 22 - Prob. 96RQCh. 22 - Prob. 97RQCh. 22 - Prob. 98RQCh. 22 - Prob. 99RQCh. 22 - Prob. 100RQCh. 22 - Prob. 101RQCh. 22 - 22.102 Write the structures of the cis and tram...Ch. 22 - 22.103 Write the structures of the products that...Ch. 22 - Prob. 104RQCh. 22 - 22.105 Repeat Problem 22.103 using...Ch. 22 - Repeat Problem 22.104 using cyclohexene. The...Ch. 22 - Prob. 107RQCh. 22 - Predict the products of the reaction of benzene...Ch. 22 - Prob. 109RQCh. 22 - Prob. 110RQCh. 22 - Prob. 111RQCh. 22 - Prob. 112RQCh. 22 - Prob. 113RQCh. 22 - Write the structure of the product of the...Ch. 22 - Prob. 115RQCh. 22 - Prob. 116RQCh. 22 - Prob. 117RQCh. 22 - Prob. 118RQCh. 22 - Prob. 119RQCh. 22 - Prob. 120RQCh. 22 - Prob. 121RQCh. 22 - Write the structures of the products that form in...Ch. 22 - Prob. 123RQCh. 22 - Prob. 124RQCh. 22 - Prob. 125RQCh. 22 - Prob. 126RQCh. 22 - Prob. 127RQCh. 22 - Prob. 128RQCh. 22 - 22.129 Write the structure of a triacylglycerol...Ch. 22 - 22.130 Write the structures of the products of the...Ch. 22 - Write the structure of the triacylglycerol that...Ch. 22 - *22.132 If the compound in Problem 22.130 is...Ch. 22 - *22.133 What parts of glyccrophospholipid...Ch. 22 - *22.134 In general terms, describe the structure...Ch. 22 - Prob. 135RQCh. 22 - What is the structure of the tripeptide that could...Ch. 22 - 22.137 What are the structures of the two...Ch. 22 - Prob. 138RQCh. 22 - Prob. 139RQCh. 22 - Prob. 140RQCh. 22 - Prob. 141RQCh. 22 - 22.142 Suggest a reason why trimethylamine, , has...Ch. 22 - Prob. 143RQCh. 22 - How many tripeptides can be made from three...Ch. 22 - Prob. 145RQCh. 22 - Prob. 146RQCh. 22 - Estimate the number of kilojoules of heat that...Ch. 22 - Prob. 148RQCh. 22 - Prob. 149RQCh. 22 - The compound that causes your eyes to water when...Ch. 22 - Prob. 151RQCh. 22 - Prob. 152RQCh. 22 - Use resonance structures to explain why urea,...Ch. 22 - Prob. 154RQCh. 22 - Prob. 155RQ
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