
EBK STUDY GUIDE TO ACCOMPANY CHEMISTRY:
7th Edition
ISBN: 9781119360889
Author: HYSLOP
Publisher: VST
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Chapter 22, Problem 124RQ
Interpretation Introduction
Interpretation:
Out of the given species, the ones which undergoes the reactions specified are to be determined. The product that is formed from given molecules is to be written.
Concept Introduction:
Amides are the compounds that are formed by carboxylic acids. The hydroxyl group is replaced by nitrogen.
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32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy
level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention
to your units.
A. What is the partition function for this system?
B. What are the populations of each level?
Now instead, consider a system with energy levels of 0 J mol
C. Now what is the partition function?
D. And what are the populations of the two levels?
E. Finally, repeat the second calculation at 500 K.
and 500 J mol 1 at 300 K.
F. What do you notice about the populations as you increase the temperature? At what temperature
would you expect the states to have equal populations?
30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in
class, but the partition function that describes the translational and rotational motion of a homonuclear
diatomic molecule is given by
Itrans (V,T) =
=
2πmkBT
h²
V
grot (T)
4π²IKBT
h²
Where h is Planck's constant and I is molecular moment of inertia.
The overall partition function is qmolec Qtrans qrot.
Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational
modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a
volume of 1 m³. Here is some useful data:
Moment of inertia:
I2 I 7.46 x 10-
45
kg m²
2
O2 I 1.91 x 101
-46
kg m²
K
for each reaction step.
Be sure to account for all bond-breaking and bond-making
steps.
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Chapter 22 Solutions
EBK STUDY GUIDE TO ACCOMPANY CHEMISTRY:
Ch. 22 - Prob. 1PECh. 22 - Prob. 2PECh. 22 - Prob. 3PECh. 22 - Practice Exercise 22.4
Write the IUPAC names of...Ch. 22 - Oxidation of an alcohol gave the following...Ch. 22 - Prob. 6PECh. 22 - Prob. 7PECh. 22 - Prob. 8PECh. 22 - Prob. 9PECh. 22 - Prob. 10PE
Ch. 22 - Complete the following equation by drawing...Ch. 22 - Prob. 12PECh. 22 - Prob. 13PECh. 22 - Prob. 14PECh. 22 - Prob. 15PECh. 22 - Label the hydrophobic and hydrophilic portions of...Ch. 22 - Draw a ribose ring and a deoxyribose ring. What is...Ch. 22 - Practice Exercise 22.18
Which base pairs match in...Ch. 22 - Prob. 1RQCh. 22 - Prob. 2RQCh. 22 - Prob. 3RQCh. 22 - Prob. 4RQCh. 22 - Prob. 5RQCh. 22 - Prob. 6RQCh. 22 - Prob. 7RQCh. 22 - Which of the following compounds has the higher...Ch. 22 - In general terms, why do functional groups impart...Ch. 22 - Prob. 10RQCh. 22 - What is the difference between geometric isomers...Ch. 22 - Prob. 12RQCh. 22 - No number is needed to identify the location of...Ch. 22 - Prob. 14RQCh. 22 - Prob. 15RQCh. 22 - Prob. 16RQCh. 22 - 22.17 In general terms, why doesn't benzene...Ch. 22 - Prob. 18RQCh. 22 - 22.19 Explain why is more soluble in water than ....Ch. 22 - Prob. 20RQCh. 22 - Prob. 21RQCh. 22 - Why do aldehydes and ketones have boiling points...Ch. 22 - Acetic acid boils at 118C, higher even than...Ch. 22 - Methyl ethanoate has many more atoms than its...Ch. 22 - Prob. 25RQCh. 22 - 22.26 Write condensed structures of the following...Ch. 22 - 3-Butanol is not a proper name, but a structure...Ch. 22 - Prob. 28RQCh. 22 - Prob. 29RQCh. 22 - Prob. 30RQCh. 22 - Prob. 31RQCh. 22 - Prob. 32RQCh. 22 - Amines, RNH2, do not have boiling points as high...Ch. 22 - A monofunctional organic nitrogen compound...Ch. 22 - Prob. 35RQCh. 22 - Prob. 36RQCh. 22 - Prob. 37RQCh. 22 - Write the products that can be expected to form in...Ch. 22 - Prob. 39RQCh. 22 - Prob. 40RQCh. 22 - 22.41 What do we mean by the term polymer...Ch. 22 - Prob. 42RQCh. 22 - Prob. 43RQCh. 22 - Prob. 44RQCh. 22 - Prob. 45RQCh. 22 - Prob. 46RQCh. 22 - Prob. 47RQCh. 22 - Prob. 48RQCh. 22 - Prob. 49RQCh. 22 - Prob. 50RQCh. 22 - Prob. 51RQCh. 22 - Prob. 52RQCh. 22 - Prob. 53RQCh. 22 - Prob. 54RQCh. 22 - Prob. 55RQCh. 22 - Prob. 56RQCh. 22 - Prob. 57RQCh. 22 - Prob. 58RQCh. 22 - What are the three fundamental needs for...Ch. 22 - Prob. 60RQCh. 22 - Prob. 61RQCh. 22 - Prob. 62RQCh. 22 - Name the compounds that form when sucrose is...Ch. 22 - Prob. 64RQCh. 22 - Prob. 65RQCh. 22 - Prob. 66RQCh. 22 - Prob. 67RQCh. 22 - 22.68 What function is served by glycogen in the...Ch. 22 - How are lipids defined?Ch. 22 - Why are lipids more soluble than carbohydrates in...Ch. 22 - 22.71 Cholesterol is not an ester, yet it is...Ch. 22 - A product such as corn oil is advertised as...Ch. 22 - Is it likely that the following compound could be...Ch. 22 - Describe the specific ways in which the monomers...Ch. 22 - What is the peptide bond? How is it similar to the...Ch. 22 - Prob. 76RQCh. 22 - Prob. 77RQCh. 22 - Why is a distinction made between the terms...Ch. 22 - Prob. 79RQCh. 22 - What kind of substance makes up most enzymes?Ch. 22 - Prob. 81RQCh. 22 - Prob. 82RQCh. 22 - Prob. 83RQCh. 22 - 22.84 How are the two DNA strands in a double...Ch. 22 - In what ways do DNA and RNA differ structurally.Ch. 22 - 22.86 Which base pairs with
Ch. 22 - The process of transcription begins with which...Ch. 22 - The process of translation begins with which...Ch. 22 - Prob. 89RQCh. 22 - 22.90 Write full (expanded) structures for each of...Ch. 22 - Prob. 91RQCh. 22 - Prob. 92RQCh. 22 - Prob. 93RQCh. 22 - Prob. 94RQCh. 22 - Prob. 95RQCh. 22 - Prob. 96RQCh. 22 - Prob. 97RQCh. 22 - Prob. 98RQCh. 22 - Prob. 99RQCh. 22 - Prob. 100RQCh. 22 - Prob. 101RQCh. 22 - 22.102 Write the structures of the cis and tram...Ch. 22 - 22.103 Write the structures of the products that...Ch. 22 - Prob. 104RQCh. 22 - 22.105 Repeat Problem 22.103 using...Ch. 22 - Repeat Problem 22.104 using cyclohexene. The...Ch. 22 - Prob. 107RQCh. 22 - Predict the products of the reaction of benzene...Ch. 22 - Prob. 109RQCh. 22 - Prob. 110RQCh. 22 - Prob. 111RQCh. 22 - Prob. 112RQCh. 22 - Prob. 113RQCh. 22 - Write the structure of the product of the...Ch. 22 - Prob. 115RQCh. 22 - Prob. 116RQCh. 22 - Prob. 117RQCh. 22 - Prob. 118RQCh. 22 - Prob. 119RQCh. 22 - Prob. 120RQCh. 22 - Prob. 121RQCh. 22 - Write the structures of the products that form in...Ch. 22 - Prob. 123RQCh. 22 - Prob. 124RQCh. 22 - Prob. 125RQCh. 22 - Prob. 126RQCh. 22 - Prob. 127RQCh. 22 - Prob. 128RQCh. 22 - 22.129 Write the structure of a triacylglycerol...Ch. 22 - 22.130 Write the structures of the products of the...Ch. 22 - Write the structure of the triacylglycerol that...Ch. 22 - *22.132 If the compound in Problem 22.130 is...Ch. 22 - *22.133 What parts of glyccrophospholipid...Ch. 22 - *22.134 In general terms, describe the structure...Ch. 22 - Prob. 135RQCh. 22 - What is the structure of the tripeptide that could...Ch. 22 - 22.137 What are the structures of the two...Ch. 22 - Prob. 138RQCh. 22 - Prob. 139RQCh. 22 - Prob. 140RQCh. 22 - Prob. 141RQCh. 22 - 22.142 Suggest a reason why trimethylamine, , has...Ch. 22 - Prob. 143RQCh. 22 - How many tripeptides can be made from three...Ch. 22 - Prob. 145RQCh. 22 - Prob. 146RQCh. 22 - Estimate the number of kilojoules of heat that...Ch. 22 - Prob. 148RQCh. 22 - Prob. 149RQCh. 22 - The compound that causes your eyes to water when...Ch. 22 - Prob. 151RQCh. 22 - Prob. 152RQCh. 22 - Use resonance structures to explain why urea,...Ch. 22 - Prob. 154RQCh. 22 - Prob. 155RQ
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