Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 22, Problem 50QAP
Interpretation Introduction
Interpretation:
The name of the product formed by the addition of Cl2 to 2-methyl-2-butene should be determined.
Concept introduction:
The alkene consists of carbon-carbon double bond that contains of a sigma and a pi bond.
Interpretation Introduction
Interpretation:
The name of the product formed by the addition of I2 to 2-methyl-2-butene should be determined.
Concept introduction:
The alkene consists of carbon-carbon double bond that contains of a sigma and a pi bond. Alkenes are quite reactive that is they can be easily broken due to weak carbon-carbon pi bond. They generally undergo addition reaction, in which reagents are added across double bonds resulting in the formation of single bonds.
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1. (a) Draw structures of the seven isomeric alkynes of formula C6H10 - (b) Give the IUPAC and derived name of each. (c) Indicate which ones will react with Ag' or Cu(NH3)2.
5. Give the structural formulae and name the functional groups of the following compounds.
(a) 3-chlorobut-1-ene
(b) butanedioic acid
Name the functional group:
(c) propanamide
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(d) 3-methylbutanal
Name the functional group:
Name the functional group:
Which compounds exhibit geometric isomerism? Draw andname the two isomers in each case:(a) 1-pentene(b) 2-pentene(c) 1-chloropropene(d) 2-chloropropene
Chapter 22 Solutions
Chemistry: Principles and Reactions
Ch. 22 - Classify each of the following hydrocarbons as...Ch. 22 - Classify each of the following hydrocarbons as...Ch. 22 - Write the formula for (a) an alkene with two...Ch. 22 - Write the formula for (a) an alkyne with 16...Ch. 22 - Name the following alkanes.Ch. 22 - Name the following alkanes.Ch. 22 - Prob. 7QAPCh. 22 - Prob. 8QAPCh. 22 - The following names are incorrect; draw a...Ch. 22 - Prob. 10QAP
Ch. 22 - Prob. 11QAPCh. 22 - Prob. 12QAPCh. 22 - Prob. 13QAPCh. 22 - Name the following compounds as derivatives of...Ch. 22 - Prob. 15QAPCh. 22 - Prob. 16QAPCh. 22 - Prob. 17QAPCh. 22 - Prob. 18QAPCh. 22 - Prob. 19QAPCh. 22 - Prob. 20QAPCh. 22 - Prob. 21QAPCh. 22 - Prob. 22QAPCh. 22 - Prob. 23QAPCh. 22 - Arrange these compounds in order of increasing...Ch. 22 - The Kbfor ethylamine (CH3CH2NH2) is 4.3104 . What...Ch. 22 - When aniline, C6H5NH2(Kb=7.41010) , reacts with a...Ch. 22 - When ethylamine, a weak base (Kb=4.3104) , reacts...Ch. 22 - When the conjugate acid of aniline, C6H5NH3+,...Ch. 22 - Draw the structural isomers of the alkane C6H14.Ch. 22 - Prob. 30QAPCh. 22 - Prob. 31QAPCh. 22 - Draw the structural isomers of C3H6Cl2 in which...Ch. 22 - Prob. 33QAPCh. 22 - Prob. 34QAPCh. 22 - Prob. 35QAPCh. 22 - Prob. 36QAPCh. 22 - Draw structures for all the alcohols with...Ch. 22 - Prob. 38QAPCh. 22 - Prob. 39QAPCh. 22 - Prob. 40QAPCh. 22 - Maleic acid and fumaric acid are the cis- and...Ch. 22 - Prob. 42QAPCh. 22 - Which of the following can show optical isomerism?...Ch. 22 - Prob. 44QAPCh. 22 - Prob. 45QAPCh. 22 - Prob. 46QAPCh. 22 - Prob. 47QAPCh. 22 - Prob. 48QAPCh. 22 - Prob. 49QAPCh. 22 - Prob. 50QAPCh. 22 - Prob. 51QAPCh. 22 - Prob. 52QAPCh. 22 - Calculate [H+] and the pH of a 0.10 M solution of...Ch. 22 - Prob. 54QAPCh. 22 - The general formula of an alkane is CnH2n+2 . What...Ch. 22 - Prob. 56QAPCh. 22 - Prob. 57QAPCh. 22 - Prob. 58QAPCh. 22 - Prob. 59QAPCh. 22 - Write an equation for the reaction of chloroacetic...
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- A certain hydrocarbon has a molecular formula of C5H8. Which of the following is not a structural possibility for this hydrocarbon: (d) It contains an alkyne O It contains one ring and one double bond (c) It contains two double bonds and no rings O (b) It contains one ring and no double bondsarrow_forward(a) Alkenes are relatively stable compounds but are more reactive than alkanes and serve as a feedstock for the petrochemical industry because they can participate in a wide variety of reactions. Predict the products obtained from following reaction. Write the chemical reaction and name the products according to IUPAC system. (i) the reaction of 3-ethyl-3-methyl-1-pentene with hydrogen bromide (ii) the reaction of 3-ethyl-2-pentene with hydrogen bromidearrow_forward(1) Write a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction. (a) Complete hydrogenation of 2-Methylhexa-1,5-diene (b) Complete halogenation (Br2) of 3-Ethyl-2,2-dimethylhept-3-ene (c) Reaction of (4E)-2.4-Dimethylhexa-1,4-diene with a mole of water (d) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr (e) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide (f) Formation of Gilman reagent using isopropyl bromide (g) Ozonolysis of 3,3-Dimethyloct-4-yne (h) Complete halogenation (Cl2) of 3-Ethyl-5-methyl-1,6,8-decatriyne (i) Partial hydrogenation using Lindlar's Catalyst 2,2,5,5-Tetramethylhex-3-yne (i) Reaction of 3.4-Dimethylcyclodecyne with sodium amidearrow_forward
- What is the structure of the major product(s) formed when 2-methyl-1-butene reacts with (a) bromine (b) bromine in water (c) bromine in NaCl solutionarrow_forwardGive chemical tests to distinguish between the following pairs of compounds :(a) Benzyl chloride and Chlorobenzene(b) Chloroform and Carbon tetrachloridearrow_forward(B) Draw a structural diagram for each of the following organic compounds: (a) 2-ethyl-4-methyl-2-pentanol (b) 1,2-ethandiol (c) 1,3-dimethylbenzenearrow_forward
- Draw line structures for the following alkenes. Which can exist as cis–trans isomers? For those that can, draw both isomers.(a) 2-Methyloct-2-ene (b) Hept-3-ene(c) 3,4-Dimethylhex-3-enearrow_forwardA certain hydrocarbon has a molecular formula of C5H8. Which of the following is not a structural possibility for this hydrocarbon? (a) It is a cycloalkane. (b) It contains one ring and one double bond. (c) It contains two double bonds and no rings. (d) It is an alkyne.arrow_forward(a) The compound given below had the following IUPAC name and structural formula dibromocyclopentane C3H6CHBrCHBr (i) What type of isomerism is possible in the organic compound? (ii) Draw all the pairs of possible isomers and name them.arrow_forward
- Which compounds exhibit geometric isomerism? Draw andname the two isomers in each case:(a) propene(b) 3-hexene(c) 1,1-dichloroethene(d) 1,2-dichloroethenearrow_forwardWhich compounds exhibit geometric isomerism? Draw and name the two isomers in each case:(a) propene (b) 3-hexene(c) 1,1-dichloroethene (d) 1,2-dichloroethenearrow_forwardWrite structural formulas for compounds that meet the following descriptions:(a) An alkene, C6H12, that cannot have cis–trans isomersand whose longest chain is 5 carbons long(b) An alkene with a chemical formula of C10H12 that hascis–trans isomers and contains a benzene ring.arrow_forward
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