Of the following, which is not a statement of the second law of
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- Of the following, which is not a statement of the second law of thermodynamics? (a) No heat engine operating in a cycle can absorb energy from a reservoir and use it entirely to do work, (b) No real engine operating between two energy reservoirs can be more efficient than a Carnot engine operating between the same two reservoirs, (c) When a system undergoes a change in state, the change in the internal energy of the system is the sum of the energy transferred to the system by heat and the work done on the system, (d) The entropy of the Universe increases in all natural processes, (e) Energy will not spontaneously transfer by heat from a cold object to a hot object.arrow_forwardWhich of the following is true for the entropy change of a system that undergoes a reversible, adiabatic process? (a) S 0 (b) S = 0 (c) S 0arrow_forwardA copper rod of cross-sectional area 5.0 cm2 and length 5.0 m conducts heat from a heat reservoir at 373 K to one at 273 K. What is the time rate of change of the universe's entropy for this process?arrow_forward
- Is it possible for a system to have an entropy change if it neither absorbs nor emits heat during a reversible? transition? What happens it the process is irreversible?arrow_forwardConsider cyclic processes completely characterized by each of the following net energy inputs and outputs. In each case, the energy transfers listed are the only ones occurring. Classify each process as (a) possible, (b) impossible according to the first law of thermodynamics, (c) impossible according to the second law of thermodynamics, or (d) impossible according to both the first and second laws. (i) Input is 5 J of work, and output is 4 J of work. (ii) Input is 5 J of work, and output is 5 J of energy transferred by heat. (iii) Input is 5 J of energy transferred by electrical transmission, and output is 6 J of work. (iv) Input is 5 J of energy transferred by heat, and output is 5 J of energy transferred by heat. (v) Input is 5 J of energy transferred by heat, and output is 5 J of work. (vi) Input is 5 J of energy transferred by heat, and output is 3 J of work plus 2 J of energy transferred by heat.arrow_forwardTrue or False: The entropy change in an adiabatic process must be zero because Q = 0.arrow_forward
- Give an example of a spontaneous process in which a system becomes less ordered and energy becomes less available to do work. What happens to the system's entropy in this process?arrow_forwardAt point A in a Carnot cycle, 2.34 mol of a monatomic ideal gas has a pressure of 1 4000 kPa, a volume of 10.0 L, and a temperature of 720 K. The gas expands isothermally to point B and then expands adiabatically to point C, where its volume is 24.0 L. An isothermal compression brings it to point D, where its volume is 15.0 L. An adiabatic process returns the gas to point A. (a) Determine all the unknown pressures, volumes, and temperatures as you f ill in the following table: (b) Find the energy added by heat, the work done by the engine, and the change in internal energy for each of the steps A B, B C, C D, and D A (c) Calculate the efficiency Wnet/|Qk|. (d) Show that the efficiency is equal to 1 - TC/TA, the Carnot efficiency.arrow_forwardDoes the entropy increase for a Carnot engine for each cycle?arrow_forward
- A Carnot engine operates in a Carnot cycle between a heat source at 550 and a heat sink at 20 . Find the efficiency of the Carnot engine.arrow_forwardAn ideal gas is taken from an initial temperature Ti to a higher final temperature Tf along two different reversible paths. Path A is at constant pressure, and path B is at constant volume. What is the relation between the entropy changes of the gas for these paths? (a) SA SB (b) SA = SB (c) SA SBarrow_forwardThe energy output of a heat pump is greater than the energy used to operate the pump. Why doesn't this statement violate the first law of thermodynamics?arrow_forward
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