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(a)
Interpretation: The structures of the major products when aniline is treated with the given set of reagents have to be drawn.
Concept Introduction:
An amino group present in an
To find: Draw the structure of the major product when aniline is treated with the given reagent (a)
Find the director of amino group
(b)
Interpretation: The structures of the major products when aniline is treated with the given set of reagents have to be drawn.
Concept Introduction:
Acetylation is the reaction in which acetyl group is introduced in the reactive center of the compound. In most cases, bases are used as the reagents.
To find: Draw the structure of the major product when aniline is treated with the given reagent (b)
Find the nature of aniline and pyridine
(c)
Interpretation: The structures of the major products when aniline is treated with the given set of reagents have to be drawn.
Concept Introduction:
When excess methyl iodide is treated with the
To find: Draw the structure of the major product when aniline is treated with the given reagent (c)
Find the reactive group in aniline for the reagent (c)
(d)
Interpretation: The structures of the major products when aniline is treated with the given set of reagents have to be drawn.
Concept Introduction:
When aniline is treated with NaNO2 and HCl, the corresponding diazonium salt is formed which is an intermediate for the transformation of various
To find: Draw the structure of the major product when aniline is treated with the given reagent (d)
Put the reaction of aniline with NaNO2 and HCl
To find: Draw the structure of the major product when aniline is treated with the given reagent (d)
Put the reaction of aniline with NaNO2 and HCl
(e)
Interpretation: The structures of the major products when aniline is treated with the given set of reagents have to be drawn.
Concept Introduction:
A compound containing an amino group is treated with sodium nitrite and HCl leading to the formation of diazonium salt.
Sandmeyer reactions use copper salts as the reagents. Here, aryldiazonium salt is converted into aryl halides or aryl cyanides by using copper halides or copper cyanides.
To find: Draw the structure of the major product when aniline is treated with the given reagent (e)
Put the reaction of aniline with NaNO2 and HCl
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Chapter 22 Solutions
Organic Chemistry
- Q1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? H Br H Br (S) CH3 (R) CH3 H3C (S) H3C H Br Br H A C enantiomers H Br H Br (R) CH3 H3C (R) (S) CH3 H3C H Br Br H B D identicalarrow_forward2. Histamine (below structure) is a signal molecule involved in immune response and is a neurotransmitter. Histamine features imidazole ring which is an aromatic heterocycle. Please answer the following questions regarding Histamine. b a HN =N C NH2 a. Determine hybridization of each N atom (s, p, sp, sp², sp³, etc.) in histamine N-a hybridization: N-b hybridization: N-c hybridization: b. Determine what atomic orbitals (s, p, sp, sp², sp³, etc.) of the lone pair of each N atom resided in N-a hybridization: N-b hybridization: N-c hybridization:arrow_forwardNonearrow_forward
- 29. Use frontier orbital analysis (HOMO-LUMO interactions) to decide whether the following dimerization is 1) thermally allowed or forbidden and 2) photochemically allowed or forbidden. +arrow_forward30.0 mL of 0.10 mol/L iron sulfate and 20.0 mL of 0.05 mol/L of silver nitrate solutions are mixed together. Justify if any precipitate would formarrow_forwardDoes the carbonyl group first react with the ethylene glycol, in an intermolecular reaction, or with the end alcohol, in an intramolecular reaction, to form a hemiacetal? Why does it react with the alcohol it does first rather than the other one? Please do not use an AI answer.arrow_forward
- The number of noncyclic isomers that have the composition C4H8Owith the O as part of an OH group, counting a pair of stereoisomers as1, is A. 8; B. 6; C. 9; D. 5; E. None of the other answers is correct.arrow_forwardNonearrow_forwardThe number of carbon skeletons that have 8 carbons, one of which istertiary is A. 7; B. More than 7; C. 6; D. 5; E. 4arrow_forward
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