CHEMISTRY >CUSTOM<
CHEMISTRY >CUSTOM<
14th Edition
ISBN: 9781259137815
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 22, Problem 30QP
Interpretation Introduction

Interpretation:

The reason that crystal field splitting for an octahedral complex is always greater than that of a tetrahedral complex is to be explained.

Concept Introduction:

Crystal field splitting is defined as the difference in the energies between the lower-energy (dxydyz, and dzx) and the higher-energy (dx2y2 and dz2) d orbitals.

Complex ions have 47d electrons, out of which three electrons will enter the lower-energy orbitals but the remaining may either enter the lower-energy orbital(s) or the higher-energy orbital(s).

When the electrons enter the higher-energy orbital(s), that is, dx2y2 and/or dz2, high-spin complexes are formed. Weak ligands produce high-spin complexes. When electrons, in the presence of strong ligands, enter the lower-energy orbital(s), that is, dxydyz, and dzx, they form low spin complexes.

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Chapter 22 Solutions

CHEMISTRY >CUSTOM<

Ch. 22.3 - Prob. 1PPACh. 22.3 - Prob. 1PPBCh. 22.3 - Prob. 1PPCCh. 22.3 - Prob. 1CPCh. 22.3 - Prob. 2CPCh. 22.4 - Prob. 1PPACh. 22.4 - Practice Problem BUILD Transition metal ions can...Ch. 22.4 - Prob. 1PPCCh. 22 - Prob. 1QPCh. 22 - Prob. 2QPCh. 22 - 22.3 Explain why atomic radii decrease very...Ch. 22 - Prob. 4QPCh. 22 - Write the electron configurations of the following...Ch. 22 - Prob. 6QPCh. 22 - Prob. 7QPCh. 22 - Prob. 8QPCh. 22 - Describe the interaction between a donor atom and...Ch. 22 - Prob. 10QPCh. 22 - Complete the following statements for the complex...Ch. 22 - Prob. 12QPCh. 22 - Prob. 13QPCh. 22 - Prob. 14QPCh. 22 - Prob. 15QPCh. 22 - Prob. 16QPCh. 22 - Prob. 17QPCh. 22 - Prob. 18QPCh. 22 - Prob. 19QPCh. 22 - Prob. 20QPCh. 22 - Prob. 21QPCh. 22 - The complex ion [Ni ( CN ) 2 Br 2 ] 2- has a...Ch. 22 - Prob. 23QPCh. 22 - Prob. 24QPCh. 22 - Prob. 25QPCh. 22 - Prob. 26QPCh. 22 - Prob. 27QPCh. 22 - Prob. 28QPCh. 22 - Prob. 29QPCh. 22 - Prob. 30QPCh. 22 - Prob. 31QPCh. 22 - Prob. 32QPCh. 22 - Prob. 33QPCh. 22 - Prob. 34QPCh. 22 - Prob. 35QPCh. 22 - Prob. 36QPCh. 22 - Prob. 37QPCh. 22 - Prob. 38QPCh. 22 - Prob. 39QPCh. 22 - Prob. 40QPCh. 22 - Prob. 41QPCh. 22 - A concentrated aqueous copper(II) chloride...Ch. 22 - Prob. 43QPCh. 22 - Prob. 44QPCh. 22 - Prob. 45APCh. 22 - Prob. 46APCh. 22 - Prob. 47APCh. 22 - Prob. 48APCh. 22 - Prob. 49APCh. 22 - Draw qualitative diagrams for the crystal held...Ch. 22 - Prob. 51APCh. 22 - Prob. 52APCh. 22 - Prob. 53APCh. 22 - Prob. 54APCh. 22 - Prob. 55APCh. 22 - Prob. 56APCh. 22 - Prob. 57APCh. 22 - Prob. 58APCh. 22 - 22.59 The -porphyrin complex is more stable than...Ch. 22 - Prob. 60APCh. 22 - Prob. 61APCh. 22 - Prob. 62APCh. 22 - Prob. 63APCh. 22 - Prob. 64APCh. 22 - Prob. 65APCh. 22 - Prob. 66APCh. 22 - Prob. 67APCh. 22 - Prob. 68APCh. 22 - Locate the transition metal atoms and ions in the...Ch. 22 - Prob. 70APCh. 22 - Prob. 71APCh. 22 - Copper is known to exist in the +3 oxidation...Ch. 22 - 22.73 Chemical analysis shows that hemoglobin...Ch. 22 - Prob. 74APCh. 22 - Prob. 75APCh. 22 - Prob. 76APCh. 22 - 22.77 Commercial silver-plating operations...Ch. 22 - Prob. 78APCh. 22 - 22.79 (a) The free Cu(I) ion is unstable in...Ch. 22 - Prob. 1SEPPCh. 22 - Prob. 2SEPPCh. 22 - Prob. 3SEPPCh. 22 - Prob. 4SEPP
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