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OWLv2 with Student Solutions Manual eBook for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 4 terms (24 months)
8th Edition
ISBN: 9781305863170
Author: William L. Masterton; Cecile N. Hurley
Publisher: Cengage Learning US
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Textbook Question
Chapter 22, Problem 24QAP
Arrange these compounds in order of increasing boiling point.
(a) 1-butanol, butane, diethylether
(b) hexane, 1-hexanol, dipropylether
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Chapter 22 Solutions
OWLv2 with Student Solutions Manual eBook for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 4 terms (24 months)
Ch. 22 - Classify each of the following hydrocarbons as...Ch. 22 - Classify each of the following hydrocarbons as...Ch. 22 - Write the formula for (a) an alkene with two...Ch. 22 - Write the formula for (a) an alkyne with 16...Ch. 22 - Name the following alkanes.Ch. 22 - Name the following alkanes.Ch. 22 - Prob. 7QAPCh. 22 - Prob. 8QAPCh. 22 - The following names are incorrect; draw a...Ch. 22 - Prob. 10QAP
Ch. 22 - Prob. 11QAPCh. 22 - Prob. 12QAPCh. 22 - Prob. 13QAPCh. 22 - Name the following compounds as derivatives of...Ch. 22 - Prob. 15QAPCh. 22 - Prob. 16QAPCh. 22 - Prob. 17QAPCh. 22 - Prob. 18QAPCh. 22 - Prob. 19QAPCh. 22 - Prob. 20QAPCh. 22 - Prob. 21QAPCh. 22 - Prob. 22QAPCh. 22 - Prob. 23QAPCh. 22 - Arrange these compounds in order of increasing...Ch. 22 - The Kbfor ethylamine (CH3CH2NH2) is 4.3104 . What...Ch. 22 - When aniline, C6H5NH2(Kb=7.41010) , reacts with a...Ch. 22 - When ethylamine, a weak base (Kb=4.3104) , reacts...Ch. 22 - When the conjugate acid of aniline, C6H5NH3+,...Ch. 22 - Draw the structural isomers of the alkane C6H14.Ch. 22 - Prob. 30QAPCh. 22 - Prob. 31QAPCh. 22 - Draw the structural isomers of C3H6Cl2 in which...Ch. 22 - Prob. 33QAPCh. 22 - Prob. 34QAPCh. 22 - Prob. 35QAPCh. 22 - Prob. 36QAPCh. 22 - Draw structures for all the alcohols with...Ch. 22 - Prob. 38QAPCh. 22 - Prob. 39QAPCh. 22 - Prob. 40QAPCh. 22 - Maleic acid and fumaric acid are the cis- and...Ch. 22 - Prob. 42QAPCh. 22 - Which of the following can show optical isomerism?...Ch. 22 - Prob. 44QAPCh. 22 - Prob. 45QAPCh. 22 - Prob. 46QAPCh. 22 - Prob. 47QAPCh. 22 - Prob. 48QAPCh. 22 - Prob. 49QAPCh. 22 - Prob. 50QAPCh. 22 - Prob. 51QAPCh. 22 - Prob. 52QAPCh. 22 - Calculate [H+] and the pH of a 0.10 M solution of...Ch. 22 - Prob. 54QAPCh. 22 - The general formula of an alkane is CnH2n+2 . What...Ch. 22 - Prob. 56QAPCh. 22 - Prob. 57QAPCh. 22 - Prob. 58QAPCh. 22 - Prob. 59QAPCh. 22 - Write an equation for the reaction of chloroacetic...
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- Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.arrow_forwardFor each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.arrow_forwardA molecule shows peaks at 1379, 1327, 1249, 739 cm-1. Draw a diagram of the energy levels for such a molecule. Draw arrows for the possible transitions that could occur for the molecule. In the diagram imagine exciting an electron, what are its various options for getting back to the ground state? What process would promote radiation less decay? What do you expect for the lifetime of an electron in the T1 state? Why is phosphorescence emission weak in most substances? What could you do to a sample to enhance the likelihood that phosphorescence would occur over radiationless decay?arrow_forward
- Please correct answer and don't use hand ratingarrow_forwardThe SN 1 mechanism starts with the rate-determining step which is the dissociation of the alkyl halide into a carbocation and a halide ion. The next step is the rapid reaction of the carbocation intermediate with the nucleophile; this step completes the nucleophilic substitution stage. The step that follows the nucleophilic substitution is a fast acid-base reaction. The nucleophile now acts as a base to remove the proton from the oxonium ion from the previous step, to give the observed product. Draw a curved arrow mechanism for the reaction, adding steps as necessary. Be sure to include all nonzero formal charges. Cl: Add/Remove step G Click and drag to start drawing a structure.arrow_forwardPlease correct answer and don't use hand ratingarrow_forward
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