OWLv2 with Student Solutions Manual eBook for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 4 terms (24 months)
OWLv2 with Student Solutions Manual eBook for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 4 terms (24 months)
8th Edition
ISBN: 9781305863170
Author: William L. Masterton; Cecile N. Hurley
Publisher: Cengage Learning US
bartleby

Concept explainers

Question
Book Icon
Chapter 22, Problem 13QAP
Interpretation Introduction

Interpretation:

The name of the given derivative of nitrobenzene should be determined.

Concept introduction:

The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

When a benzene ring is substituted with only one substituent (monosubstituted ring), we do not indicate its position on the ring. For example: benzene ring substituted with nitro, will name it as nitrobenzene.

For a benzene ring substituted with more than one substituent the position of the substituents is written first in the name followed by di, tri, tetra etc. (to indicate the number of substituents) followed by the name of the substituents then adding suffix benzene or common name of monoderivative of benzene.

The numbering is done in such a way that the substituents gets the lowest numbers.

The prefixes used in organic chemistry for disubstituted benzene are ortho-, meta-, and para- which are used to indicate the position of substituent (non-hydrogen) on benzene.

  • Ortho
  • It describes the position of substituents at 1 and 2 positions on benzene, an aromatic compound. The symbol used for ortho is o- that means substituents at 1,2-positions.

  • Meta
  • It describes the position of substituents at 1 and 3 positions on benzene, an aromatic compound. The symbol used for ortho is m- that means substituents at 1,3-positions.

  • Para
  • It describes the position of substituents at 1 and 4 positions on benzene, an aromatic compound. The symbol used for ortho is p- that means substituents at 1,4-positions.

Interpretation Introduction

Interpretation:

The name of the given derivative of nitrobenzene should be determined.

Concept introduction:

The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

When a benzene ring is substituted with only one substituent (monosubstituted ring), we do not indicate its position on the ring. For example: benzene ring substituted with nitro, will name it as nitrobenzene.

For a benzene ring substituted with more than one substituent the position of the substituents is written first in the name followed by di, tri, tetra etc. (to indicate the number of substituents) followed by the name of the substituents then adding suffix benzene or common name of monoderivative of benzene.

The numbering is done in such a way that the substituents gets the lowest numbers.

The prefixes used in organic chemistry for disubstituted benzene are ortho-, meta-, and para- which are used to indicate the position of substituent (non-hydrogen) on benzene.

  • Ortho
  • It describes the position of substituents at 1 and 2 positions on benzene, an aromatic compound. The symbol used for ortho is o- that means substituents at 1,2-positions.

  • Meta
  • It describes the position of substituents at 1 and 3 positions on benzene, an aromatic compound. The symbol used for ortho is m- that means substituents at 1,3-positions.

  • Para
  • It describes the position of substituents at 1 and 4 positions on benzene, an aromatic compound. The symbol used for ortho is p- that means substituents at 1,4-positions.

Interpretation Introduction

Interpretation:

The name of the given derivative of nitrobenzene should be determined.

Concept introduction:

The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

When a benzene ring is substituted with only one substituent (monosubstituted ring), we do not indicate its position on the ring. For example: benzene ring substituted with nitro, will name it as nitrobenzene.

For a benzene ring substituted with more than one substituent the position of the substituents is written first in the name followed by di, tri, tetra etc. (to indicate the number of substituents) followed by the name of the substituents then adding suffix benzene or common name of monoderivative of benzene.

The numbering is done in such a way that the substituents gets the lowest numbers.

Blurred answer
Students have asked these similar questions
Q4. Radicals a. For the following indicated bonds, rank them in order of decreasing AH° for homolytic cleavage. Based on your answer, which bond would be most likely to break homolytically? (c) CH3 CH3 H3C CH3 (a) CH3 (b)
Q1. (a) Draw equations for homolytic and heterolytic cleavages of the N-H bond in NH3. Use curved arrows to show the electron movement. (b) Draw equations for homolytic and heterolytic cleavages of the N-H bond in NH4*. Use curved arrows to show the electron movement.
ohing Quantitative Relationships 425 The specific heats and atomic masses of 20 of the elements are given in the table below. Use a graphical method to determine if there is a relationship between specific heat and the atomic mass. a. b. C. d. e. If your graphs revealed relationship between specific heat and atomic revealed a mathematical mass, write down an equation for the relationship. Comment on the usefulness of the determination of specific heat as a method for identifying an element. Would specific heat alone give you much confidence with regard to the identity of the element? If you think measurement of another property would be needed to support an identification, what property would you measure and why? The elements listed in the table are all selected metals. The values for nitrogen, oxygen, fluorine and neon are 1.040, 0.918, 0.824 and 1.030 J/g K respectively. Do these elements fit your equation? element atomic mass specific heat (almol) (Jig K) magnesium 24.305 1.023…

Chapter 22 Solutions

OWLv2 with Student Solutions Manual eBook for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 4 terms (24 months)

Ch. 22 - Prob. 11QAPCh. 22 - Prob. 12QAPCh. 22 - Prob. 13QAPCh. 22 - Name the following compounds as derivatives of...Ch. 22 - Prob. 15QAPCh. 22 - Prob. 16QAPCh. 22 - Prob. 17QAPCh. 22 - Prob. 18QAPCh. 22 - Prob. 19QAPCh. 22 - Prob. 20QAPCh. 22 - Prob. 21QAPCh. 22 - Prob. 22QAPCh. 22 - Prob. 23QAPCh. 22 - Arrange these compounds in order of increasing...Ch. 22 - The Kbfor ethylamine (CH3CH2NH2) is 4.3104 . What...Ch. 22 - When aniline, C6H5NH2(Kb=7.41010) , reacts with a...Ch. 22 - When ethylamine, a weak base (Kb=4.3104) , reacts...Ch. 22 - When the conjugate acid of aniline, C6H5NH3+,...Ch. 22 - Draw the structural isomers of the alkane C6H14.Ch. 22 - Prob. 30QAPCh. 22 - Prob. 31QAPCh. 22 - Draw the structural isomers of C3H6Cl2 in which...Ch. 22 - Prob. 33QAPCh. 22 - Prob. 34QAPCh. 22 - Prob. 35QAPCh. 22 - Prob. 36QAPCh. 22 - Draw structures for all the alcohols with...Ch. 22 - Prob. 38QAPCh. 22 - Prob. 39QAPCh. 22 - Prob. 40QAPCh. 22 - Maleic acid and fumaric acid are the cis- and...Ch. 22 - Prob. 42QAPCh. 22 - Which of the following can show optical isomerism?...Ch. 22 - Prob. 44QAPCh. 22 - Prob. 45QAPCh. 22 - Prob. 46QAPCh. 22 - Prob. 47QAPCh. 22 - Prob. 48QAPCh. 22 - Prob. 49QAPCh. 22 - Prob. 50QAPCh. 22 - Prob. 51QAPCh. 22 - Prob. 52QAPCh. 22 - Calculate [H+] and the pH of a 0.10 M solution of...Ch. 22 - Prob. 54QAPCh. 22 - The general formula of an alkane is CnH2n+2 . What...Ch. 22 - Prob. 56QAPCh. 22 - Prob. 57QAPCh. 22 - Prob. 58QAPCh. 22 - Prob. 59QAPCh. 22 - Write an equation for the reaction of chloroacetic...
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Text book image
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Text book image
Chemistry In Focus
Chemistry
ISBN:9781337399692
Author:Tro, Nivaldo J.
Publisher:Cengage Learning,
Text book image
Introductory Chemistry For Today
Chemistry
ISBN:9781285644561
Author:Seager
Publisher:Cengage
Text book image
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Text book image
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Text book image
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning