Concept explainers
(a)
Interpretation:
The non-hydrogen atom in each case should be identified and the molecular formula for each hydride should be written.
Concept introduction:
Hydrogen can form only one bond. So, atom with more than one bond is the non-hydrogen atom. The second row elements contain Lithium, Beryllium, Boron, Carbon, Nitrogen, Oxygen, fluorine and neon.
(b)
Interpretation:
An electron-dot structure for each hydride should be drawn. For which hydride there is a problem in drawing the structure should be determined.
Concept introduction:
Electron-dot structure represents valence electrons of an atom by dots and show how they are distributed in a molecule. Every atom tries to a complete valence shell or to achieve noble gas configuration by making bonds with other atoms.
Want to see the full answer?
Check out a sample textbook solutionChapter 22 Solutions
LCPO CHEMISTRY W/MODIFIED MASTERING
- Q.5(a) The alkali metals follow the noble gases in their atomic structure. What properties of these metals can be predicted from this information? (b) Arrange the carbonates of alkaline earth metals in order of thermal stability. (c) Explain the process involved in the manufacture of NaOH, Na2CO3 and NaHCO3. (d) Identify the element X in each of the following: (i) The oxide of XO2 has a high M.P., and is very abundant in nature. (ii) X forms three oxides: XO, XO2, X3O2. (iii) X forms compounds mainly in the +2 O.S., though some compounds in +4 state do exist. (iv) X occurs as several allotropes, including a molecular one. (e) Borazine reacts with three mole equivalents of HCl to give a material with chemical composition B3N3H9C13. (i) What is the structure of product? (ii) How does the isoelectronic benzene react with HCl? (f) Explain why bond length in NO (115 pm) is longer than that in nitrosonium ion (106 pm)?arrow_forwardCompounds such as NaBH₄, Al(BH₄)₃, and LiAlH₄ arecomplex hydrides used as reducing agents in many syntheses.(a) Give the oxidation state of each element in these compounds.(b) Write a Lewis structure for the polyatomic anion in NaBH₄,and predict its shape.arrow_forward(b) Is boron a metal or a non-metal? Give reasons for your answer. (c) Why is aluminium a useful structural material even though it reacts readilywith water and oxygen? (d) What is the usual valence shown by elements of Group 13 in compounds?arrow_forward
- (A) if both sentences are true, (B) if both sentences are false, (C) if the first sentence is true but the second is false, and (D) if the first sentence is false but the second is true. 1. When a non-metallic oxide reacts with water, a base will be formed as the product of the reaction. When a metallic oxide like phosphorous pentoxide reacts with water, a base will be formed as the product of the reaction. 2. When water is mixed with oxides, hydrogen gas is evolved. A red to blue color change in the litmus paper indicates that the solution tested is an acid. 3. The filtrate in any filtration process is left on the surface of the filter paper, while the residue is collected at the bottom of the flask/container after passing through the filter paper. In the distillation process, the methyl violet served as a compound to acidify the water. 4. In the Winkler Titration Method, the starch solution turns colorless in the presence of free iodine in the solution to be titrated. In the Winkler…arrow_forwardCompounds such as NaBH4, Al(BH4)3, and LiAlH4 are complex hydrides used as reducing agents in many syntheses. (a) Give the oxidation state of each element in these compounds. (b) Write a Lewis structure for the polyatomic anion in NaBH4, and predict its shape.arrow_forwardA molecular property of the Group 6A(16) hydrides changes abruptly down the group. This change has been ex-plained in terms of a change in orbital hybridization.(a) Between what periods does the change occur?(b) What is the change in the molecular property?(c) What is the change in hybridization?(d) What other group displays a similar change?arrow_forward
- Consider the following three statements about the reactivityof an alkali metal M with oxygen gas:(i) Based on their positions in the periodic table, the expectedproduct is the ionic oxide M2O.(ii) Some of the alkali metals produce metal peroxides or metalsuperoxides when they react with oxygen.(iii) When dissolved in water, an alkali metal oxide produces abasic solution.Which of the statements (i), (ii), and (iii) is or are true?(a) Only one of the statements is true.(b) Statements (i) and (ii) are true.(c) Statements (i) and (iii) are true.(d) Statements (ii) and (iii) are true.(e) All three statements are true.arrow_forwardWhich of the following statements are true?(a) Both nitrogen and phosphorus can form a pentafluoridecompound.(b) Although CO is a well-known compound, SiO does notexist under ordinary conditions.(c) Cl2 is easier to oxidize than I2.(d) At room temperature, the stable form of oxygen is O2,whereas that of sulfur is S8.arrow_forwardWrite a balanced equation for each of the following reactions:(a) Sulfur dioxide reacts with water. (b) Solid zincsulfide reacts with hydrochloric acid. (c) Elemental sulfurreacts with sulfite ion to form thiosulfate. (d) Sulfur trioxideis dissolved in sulfuric acid.arrow_forward
- Write a Lewis structure for each of the following molecules and ions:(a) (CH3)3SiH(b) SiO44−(c) Si2H6(d) Si(OH)4(e) SiF62−arrow_forwardWrite a balanced equation for each of the following: (a) A characteristic reaction of Group 1A(1) elements: chunks of sodium react violently with water to form hydrogen gas and sodium hydroxide solution. (b) The destruction of marble statuary by acid rain: aqueous nitric acid reacts with calcium carbonate to form carbon dioxide, water, and aqueous calcium nitrate. (c) Halogen compounds exchanging bonding partners: phosphorus trifl uoride is prepared by the reaction of phosphorus trichloride and hydrogen fl uoride; hydrogen chloride is the other product. The reaction involves gases only.arrow_forward(a) (i) (ii) (iii) With the aid of a simple schematic, explain what covalent bonding is and how it is formed. What are the differences between a covalent bond and an ionic bond? Which type of bond is found in crystalline silicon? At room temperature do you expect an ionic crystal to be a good electrical conductor or a good electrical insulator? Explain why.arrow_forward
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax