The chiral carbon atoms found in the monosaccharide’s D-ribose and D-mannose are to be determined. Concept introduction: Carbohydrates are naturally occurring organic compounds. As the name implies carbohydrates are hydrates of carbon and have general formula of C X ( H 2 O ) Y . Basically, carbohydrates are polyhydroxy aldehyde and ketones , for examples, glucose and fructose. Glucose is a six carbon atoms aldehyde sugar whereas fructose is a six carbon atoms ketone sugar. D-ribose and D-mannose are aldehyde sugar belongs to the pentose class. The chiral carbon atom is defined as the carbon atom which has four different group of atoms attached to it. To determine: The number of chiral carbon atoms in D-ribose.
The chiral carbon atoms found in the monosaccharide’s D-ribose and D-mannose are to be determined. Concept introduction: Carbohydrates are naturally occurring organic compounds. As the name implies carbohydrates are hydrates of carbon and have general formula of C X ( H 2 O ) Y . Basically, carbohydrates are polyhydroxy aldehyde and ketones , for examples, glucose and fructose. Glucose is a six carbon atoms aldehyde sugar whereas fructose is a six carbon atoms ketone sugar. D-ribose and D-mannose are aldehyde sugar belongs to the pentose class. The chiral carbon atom is defined as the carbon atom which has four different group of atoms attached to it. To determine: The number of chiral carbon atoms in D-ribose.
Solution Summary: The author explains that carbohydrates are hydrates of carbon and have general formula of polyhydroxy aldehyde and ketones.
Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.
Chapter 22, Problem 104E
(a)
Interpretation Introduction
Interpretation: The chiral carbon atoms found in the monosaccharide’s D-ribose and D-mannose are to be determined.
Concept introduction: Carbohydrates are naturally occurring organic compounds. As the name implies carbohydrates are hydrates of carbon and have general formula of
CX(H2O)Y. Basically, carbohydrates are
polyhydroxyaldehyde and ketones, for examples, glucose and fructose. Glucose is a six carbon atoms aldehyde sugar whereas fructose is a six carbon atoms ketone sugar. D-ribose and D-mannose are aldehyde sugar belongs to the pentose class. The chiral carbon atom is defined as the carbon atom which has four different group of atoms attached to it.
To determine: The number of chiral carbon atoms in D-ribose.
(b)
Interpretation Introduction
Interpretation: The chiral carbon atoms found in the monosaccharide’s D-ribose and D-mannose are to be determined.
Concept introduction: Carbohydrates are naturally occurring organic compounds. As the name implies carbohydrates are hydrates of carbon and have general formula of
CX(H2O)Y. Basically, carbohydrates are
polyhydroxy aldehyde and ketones, for examples, glucose and fructose. Glucose is a six carbon atoms aldehyde sugar whereas fructose is a six carbon atoms ketone sugar. D-ribose and D-mannose are aldehyde sugar belongs to the pentose class. The chiral carbon atom is defined as the carbon atom which has four different group of atoms attached to it.
To determine: The number of chiral carbon atoms in D-mannose.
Draw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant
rate under these conditions, check the box underneath the drawing area instead.
Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products.
Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but
strong heat or reflux is not used.
Cl
C
O Substitution will not occur at a significant rate.
Explanation
Check
+
O-CH3
Х
Click and drag to start
drawing a structure.
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