The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

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Answer 1

Question

Chapter 21.8C, Problem 21.25P

(a)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of N-cyclohexylacetamide followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(c)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of ε-caprolactam followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(d)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(e)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of tertiary amide followed by hydrolysis gives tertiary amine.

(f)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

A chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.

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Answer 2

Question

Chapter 21.8C, Problem 21.25P

(a)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of N-cyclohexylacetamide followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(c)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of ε-caprolactam followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(d)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(e)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of tertiary amide followed by hydrolysis gives tertiary amine.

(f)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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Answer 3

Question

Chapter 21.8C, Problem 21.25P

(a)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of N-cyclohexylacetamide followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(c)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of ε-caprolactam followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(d)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(e)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of tertiary amide followed by hydrolysis gives tertiary amine.

(f)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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Answer 4

Question

Chapter 21.8C, Problem 21.25P

(a)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of N-cyclohexylacetamide followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(c)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of ε-caprolactam followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(d)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(e)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of tertiary amide followed by hydrolysis gives tertiary amine.

(f)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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Answer 5

Chapter 21.8C, Problem 21.25P

(a)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of N-cyclohexylacetamide followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(c)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of ε-caprolactam followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(d)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

(e)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of tertiary amide followed by hydrolysis gives tertiary amine.

(f)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 6

Chapter 21.8C, Problem 21.25P

(a)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 7

Chapter 21.8C, Problem 21.25P

(a)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of N-cyclohexylacetamide followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of N-cyclohexylacetamide followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of ε-caprolactam followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of ε-caprolactam followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of tertiary amide followed by hydrolysis gives tertiary amine.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of tertiary amide followed by hydrolysis gives tertiary amine.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

Solution Summary: The author explains the expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis.

Concept explainers

Interpretation:

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Interpretation:

The expected product of lithium aluminium hydride reduction of N-cyclohexylacetamide followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Interpretation:

The expected product of lithium aluminium hydride reduction of ε-caprolactam followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of tertiary amide followed by hydrolysis gives tertiary amine.

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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Chapter 21 Solutions

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

Solution Summary: The author explains the expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis.

Concept explainers

Interpretation: The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Interpretation: The expected product of lithium aluminium hydride reduction of N-cyclohexylacetamide followed by hydrolysis is to be stated. Concept introduction: The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Interpretation: The expected product of lithium aluminium hydride reduction of ε-caprolactam followed by hydrolysis is to be stated. Concept introduction: The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Interpretation: The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated. Concept introduction: The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Interpretation: The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated. Concept introduction: The lithium aluminium hydride reduction of tertiary amide followed by hydrolysis gives tertiary amine.

Interpretation: The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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Chapter 21 Solutions

Interpretation:

The expected product of lithium aluminium hydride reduction of butyronitrile followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Interpretation:

The expected product of lithium aluminium hydride reduction of N-cyclohexylacetamide followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Interpretation:

The expected product of lithium aluminium hydride reduction of ε-caprolactam followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of secondary amide followed by hydrolysis gives secondary amine.

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of tertiary amide followed by hydrolysis gives tertiary amine.

Interpretation:

The expected product of lithium aluminium hydride reduction of given compound followed by hydrolysis is to be stated.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.