The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

Question

Want to see the full answer?

Answer 1

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

In the solid state, oxalic acid occurs as a dihydrate with the formula H2C2O4 C+2H2O. Use this formula to calculate the formula weight of oxalic acid. Use the calculated formula weight and the number of moles (0.00504mol) of oxalic acid in each titrated unknown sample recorded in Table 6.4 to calculate the number of grams of pure oxalic acid dihydrate contained in each titrated unknown sample.

1. Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their (2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these orbitals from the two atoms forming a homonuclear л-bond. Which element would have a stronger bond, and why? (4 points)

Write the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.

Answer 2

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 6

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 7

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

Solution Summary: The author illustrates the transformation of 1-hexanol by the use of nitrile as an intermediate. Grignard reagent is used to generate R- carbanion which

Concept explainers

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Want to see the full answer?

Chapter 21 Solutions

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

Solution Summary: The author illustrates the transformation of 1-hexanol by the use of nitrile as an intermediate. Grignard reagent is used to generate R- carbanion which

Concept explainers

Interpretation: The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Want to see the full answer?

Chapter 21 Solutions

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.