ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 21.5, Problem 16P
Interpretation Introduction

Interpretation:

The structure of the product of each of the given compounds undergoes Claisen condensation with ethyl phenyl acetate respectively is to be determined.

Concept introduction:

The reaction mechanism includes the removal of α- hydrogen atom of one ester by a base that ultimately attacks the CO group of another ester. It is a base catalyzed reaction and results in the formation β-keto ester, such reaction is called as the mixed Claisen condensation reaction.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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Chapter 21 Solutions

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