From the given structure of a compound, the name has to be written. Concept Introduction: Benzene Nomenclature: Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here: • Identifying as what is the functional group . • Identifying the position of the functional group on the benzene ring. • Identifying as what is the alkyl substituent. • Identifying the position of the alkyl substituent on the benzene ring. Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

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Answer 1

Question

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…

Propose a synthesis pathway for the following transformations. b) c) d)

Answer 2

Question

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

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Answer 3

Question

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

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Answer 4

Question

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 6

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 7

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 8

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 9

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 10

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 11

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 12

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 13

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 21.2 - Construct a Frost circle for a planar...Ch. 21.2 - Which compound gives a signal in the 1H-NMR...Ch. 21.2 - Prob. 21.3P Ch. 21.2 - Prob. 21.4P Ch. 21.3 - Prob. 21.5P Ch. 21.4 - Arrange these compounds in order of increasing...Ch. 21.4 - Prob. AQ Ch. 21.4 - Prob. BQ Ch. 21.4 - Prob. CQ Ch. 21.5 - Prob. 21.7P

Solution Summary: The author explains that the name of a compound can be analysed by observing and identifying various aspects of its given structure.

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Chapter 21 Solutions