Organic Chemistry, Loose-leaf Version
Organic Chemistry, Loose-leaf Version
8th Edition
ISBN: 9781305865549
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
Question
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Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

  • Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:
  • • Identifying as what is the functional group.
  • • Identifying the position of the functional group on the benzene ring.
  • • Identifying as what is the alkyl substituent.
  • • Identifying the position of the alkyl substituent on the benzene ring.
  • Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

  • Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:
  • • Identifying as what is the functional group.
  • • Identifying the position of the functional group on the benzene ring.
  • • Identifying as what is the alkyl substituent.
  • • Identifying the position of the alkyl substituent on the benzene ring.
  • Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

  • Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:
  • • Identifying as what is the functional group.
  • • Identifying the position of the functional group on the benzene ring.
  • • Identifying as what is the alkyl substituent.
  • • Identifying the position of the alkyl substituent on the benzene ring.
  • Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

  • Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:
  • • Identifying as what is the functional group.
  • • Identifying the position of the functional group on the benzene ring.
  • • Identifying as what is the alkyl substituent.
  • • Identifying the position of the alkyl substituent on the benzene ring.
  • Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

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Chapter 21 Solutions

Organic Chemistry, Loose-leaf Version

Ch. 21 - Name the following compounds and ions.Ch. 21 - Prob. 21.9PCh. 21 - Draw a structural formula for each compound. (a)...Ch. 21 - Molecules of 6,6-dinitrobiphenyl-2,2-dicarboxylic...Ch. 21 - Following each name is the number of Kekul...Ch. 21 - Prob. 21.13PCh. 21 - Prob. 21.14PCh. 21 - Prob. 21.15PCh. 21 - Which of the molecules and ions given in Problem...Ch. 21 - Prob. 21.17PCh. 21 - Naphthalene and azulene are constitutional isomers...Ch. 21 - Prob. 21.19PCh. 21 - Prob. 21.20PCh. 21 - Following are IR and 1H-NMR spectra of compound D....Ch. 21 - Compound E (C8H10O2) is a neutral solid. Its mass...Ch. 21 - Following are 1H-NMR and 13C-NMR spectral data for...Ch. 21 - Following are 1H-NMR and 13C-NMR spectral data for...Ch. 21 - Compound H (C8H6O3) gives a precipitate when...Ch. 21 - Compound I (C11H14O2) is insoluble in water,...Ch. 21 - Propose a structural formula for compound J...Ch. 21 - Propose a structural formula for the analgesic...Ch. 21 - Prob. 21.29PCh. 21 - Prob. 21.30PCh. 21 - Given here are 1H-NMR and 13C-NMR spectral data...Ch. 21 - Prob. 21.32PCh. 21 - Prob. 21.33PCh. 21 - Prob. 21.34PCh. 21 - Arrange the molecules and ions in each set in...Ch. 21 - Prob. 21.36PCh. 21 - Prob. 21.37PCh. 21 - From each pair, select the stronger base.Ch. 21 - Prob. 21.39PCh. 21 - Prob. 21.40PCh. 21 - Prob. 21.41PCh. 21 - Prob. 21.42PCh. 21 - Following is an equation for iodination of...Ch. 21 - Prob. 21.44PCh. 21 - Prob. 21.45PCh. 21 - Prob. 21.46PCh. 21 - When warmed in dilute sulfuric acid,...Ch. 21 - In the chemical synthesis of DNA and RNA, hydroxyl...Ch. 21 - Prob. 21.49PCh. 21 - Write the products of the following sequences of...Ch. 21 - Prob. 21.51PCh. 21 - Show how to convert 1-phenylpropane into the...Ch. 21 - Prob. 21.53PCh. 21 - Cromolyn sodium, developed in the 1960s, has been...Ch. 21 - Prob. 21.55PCh. 21 - Prob. 21.56PCh. 21 - Prob. 21.57PCh. 21 - Prob. 21.58PCh. 21 - Prob. 21.59PCh. 21 - Prob. 21.60PCh. 21 - Prob. 21.61PCh. 21 - Prob. 21.62PCh. 21 - Prob. 21.63PCh. 21 - Following is a synthesis for toremifene, a...
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