As a hybrid of five contributing structures the given molecule has to be drawn. Concept Introduction: Kekule structures: The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures . The Kekule structure for benzene ring: The back and forth shift of the double bonds in between these two forms is shown here:

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Answer 1

Question

Chapter 21, Problem 21.13P

(a)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

(b)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

(c)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

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Г C-RSA CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0.0 b.092 0.797 1.088 1.813 C-RSA CHROMATOPAC CH=1 Report No. =13 ** CALCULATION REPORT ** DATA=1: @CHRM1.000 11/03/05 08:09:52 CH PKNO TIME 1 2 0.797 3 1.088 4 1.813 AREA 1508566 4625442 2180060 HEIGHT 207739 701206 V 287554 V MK IDNO CONC NAME 18.1447 55.6339 26.2213 TOTAL 8314067 1196500 100 C-R8A CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0. 0 087 337. 0.841 1.150 C-R8A CHROMATOPAC CH=1 Report No. =14 DATA=1: @CHRM1.000 11/03/05 08:12:40 ** CALCULATION REPORT ** CH PKNO TIME AREA 1 3 0.841 1099933 41.15 4039778 HEIGHT MK IDNO 170372 649997¯¯¯ CONC NAME 21.4007 78.5993 TOTAL 5139711 820369 100 3 C-R8A CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0.100 0:652 5.856 3 1.165 C-RSA CHROMATOPAC CH-1 Report No. =15 DATA=1: @CHRM1.000 11/03/05 08:15:26 ** CALCULATION REPORT ** CH PKNO TIME AREA HEIGHT MK IDNO CONC NAME 1 3 3 0.856 4 1.165 TOTAL 1253386 4838738 175481 708024 V 20.5739 79.4261 6092124…

Answer 2

Question

Chapter 21, Problem 21.13P

(a)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

(b)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

(c)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

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See solution

Answer 3

Question

Chapter 21, Problem 21.13P

(a)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

(b)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

(c)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

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Answer 4

Question

Chapter 21, Problem 21.13P

(a)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

(b)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

(c)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

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Answer 5

Chapter 21, Problem 21.13P

(a)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

(b)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

(c)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

Answer 6

Chapter 21, Problem 21.13P

(a)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

Answer 7

Chapter 21, Problem 21.13P

(a)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

Answer 8

(b)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

Answer 9

(b)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

Answer 10

(c)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

Answer 11

(c)

Interpretation Introduction

Interpretation: As a hybrid of five contributing structures the given molecule has to be drawn.

Concept Introduction:

Kekule structures:

The double bonds of an aromatic ring shift back and forth very rapidly. The resulted forms or structures cannot be separated and stay in equilibrium. Those structures are known as Kekule structures.

The Kekule structure for benzene ring:

The back and forth shift of the double bonds in between these two forms is shown here:

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21.2 - Construct a Frost circle for a planar...Ch. 21.2 - Which compound gives a signal in the 1H-NMR...Ch. 21.2 - Prob. 21.3P Ch. 21.2 - Prob. 21.4P Ch. 21.3 - Prob. 21.5P Ch. 21.4 - Arrange these compounds in order of increasing...Ch. 21.4 - Prob. AQ Ch. 21.4 - Prob. BQ Ch. 21.4 - Prob. CQ Ch. 21.5 - Prob. 21.7P

Solution Summary: The author explains that as a hybrid of five contributing structures the given molecule has to be drawn.

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Chapter 21 Solutions