Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 21.12, Problem 14P
Which of the following base sequences would most likely be recognized by a restriction endonuclease?
- A. ACGCGT
- B. ACGGGT
- C. ACGGCA
- D. ACACGT
- E. ACATCGT
- F. CCAACC
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Students have asked these similar questions
(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 21 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 21.1 - Draw the structure for each of the following: a....Ch. 21.3 - If one of the strands of DNA has the following...Ch. 21.4 - The 2,3-cyclic phosphodiester that is formed...Ch. 21.5 - Using a dark line for the original parental DNA...Ch. 21.7 - Why do both thymine and uracil specify the...Ch. 21.9 - If methionine is always the first amino acid...Ch. 21.9 - Four Cs occur in a row in the segment of mRNA...Ch. 21.9 - UAA is a stop codon. Why does the UAA sequence in...Ch. 21.9 - A change in which base of a codon would be least...Ch. 21.9 - Write the sequences of bases in the sense strand...
Ch. 21.9 - List the possible codons on mRNA that specify each...Ch. 21.10 - Adenine can be deaminated to hypoxanthine, and...Ch. 21.10 - Explain why thymine cannot be deaminated.Ch. 21.12 - Which of the following base sequences would most...Ch. 21 - Draw structures for the following: a....Ch. 21 - What nonapeptide is coded for by the following...Ch. 21 - What is the sequence of bases in the template...Ch. 21 - What is the sequence of bases in the sense strand...Ch. 21 - What would be the C-terminal amino acid if the...Ch. 21 - What would be the base sequence of the segment of...Ch. 21 - Propose a mechanism for the following reaction:Ch. 21 - A segment of DNA has 18 base pairs. It has 7...Ch. 21 - Match the codon with the anticodon: Codon: AAA GCA...Ch. 21 - Using the single-letter abbreviations for the...Ch. 21 - Indicate whether each functional group of the five...Ch. 21 - Using the A and D designations in Problem 25,...Ch. 21 - Which of the following pairs of dinucleotides are...Ch. 21 - If an mRNA contained only U and G in random...Ch. 21 - Why is the codon a triplet rather than a doublet...Ch. 21 - Human immunodeficiency virus (HIV) is the...Ch. 21 - The amino acid sequences of peptide fragments...Ch. 21 - Which cytosine in the following sense strand of...Ch. 21 - Prob. 33PCh. 21 - Why does DNA not unravel completely before...Ch. 21 - The first amino acid incorporated into a...
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