Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
9th Edition
ISBN: 9781292151229
Author: Wade, LeRoy G.
Publisher: PEARSON
bartleby

Concept explainers

Question
Book Icon
Chapter 21.11, Problem 21.32P

(a)

Interpretation Introduction

Interpretation:

The use of anhydride to synthesize the given compound and the reason for the preference of an anhydride over an acid chloride is to be explained.

Concept introduction:

Anhydrides undergo many of the reactions as same as acid chlorides. Anhydrides are easily converted to less reactive acid derivatives as well as they participate in the Friedel-Crafts acylation. Many reactions of anhydrides involve the loss of one of the two acid molecules as a leaving group. Anhydrides often give better yields than acetyl chloride for acetylation of alcohols.

(b)

Interpretation Introduction

Interpretation:

The use of anhydride to synthesize the given compound and the reason for the preference of an anhydride over an acid chloride is to be explained.

Concept introduction:

Anhydrides undergo many of the reactions as same as acid chlorides. Anhydrides are easily converted to less reactive acid derivatives as well as they participate in the Friedel-Crafts acylation. Many reactions of anhydrides involve the loss of one of the two acid molecules as a leaving group. Anhydrides often give better yields than acetyl chloride for acetylation of alcohols.

(c)

Interpretation Introduction

Interpretation:

The use of anhydride to synthesize the given compound and the reason for the preference of an anhydride over an acid chloride is to be explained.

Concept introduction:

Anhydrides undergo many of the reactions as same as acid chlorides. Anhydrides are easily converted to less reactive acid derivatives as well as they participate in the Friedel-Crafts acylation. Many reactions of anhydrides involve the loss of one of the two acid molecules as a leaving group. Anhydrides often give better yields than acetyl chloride for acetylation of alcohols.

(d)

Interpretation Introduction

Interpretation:

The use of anhydride to synthesize the given compound and the reason for the preference of an anhydride over an acid chloride is to be explained.

Concept introduction:

Anhydrides undergo many of the reactions as same as acid chlorides. Anhydrides are easily converted to less reactive acid derivatives as well as they participate in the Friedel-Crafts acylation. Many reactions of anhydrides involve the loss of one of the two acid molecules as a leaving group. Anhydrides often give better yields than acetyl chloride for acetylation of alcohols.

Blurred answer
Students have asked these similar questions
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ X
Predict the major products of this organic reaction: OH NaBH4 H ? CH3OH Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. ☐ : S
Predict the major products of this organic reaction: 1. LIAIHA 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. X : ☐

Chapter 21 Solutions

Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition

Ch. 21.7C - Prob. 21.20PCh. 21.7C - Prob. 21.21PCh. 21.7D - Prob. 21.22PCh. 21.7D - The mechanism for acidic hydrolysis of a nitrile...Ch. 21.8A - Prob. 21.24PCh. 21.8C - Prob. 21.25PCh. 21.9 - Prob. 21.26PCh. 21.9 - Prob. 21.27PCh. 21.9 - Prob. 21.28PCh. 21.10 - Draw a mechanism for the acylation of anisole by...Ch. 21.10 - Prob. 21.30PCh. 21.11 - Prob. 21.31PCh. 21.11 - Prob. 21.32PCh. 21.12 - Problem 21-33 Propose a mechanism for the...Ch. 21.12 - Suggest the most appropriate reagent for each...Ch. 21.12 - Show how you would synthesize each compound,...Ch. 21.13 - Prob. 21.36PCh. 21.13 - Prob. 21.37PCh. 21.14 - Prob. 21.38PCh. 21.14 - Prob. 21.39PCh. 21.16 - Prob. 21.40PCh. 21.16 - Prob. 21.41PCh. 21 - Prob. 21.42SPCh. 21 - Give appropriate names for the following...Ch. 21 - Predict the major products formed when benzoyl...Ch. 21 - Predict the products of the following reactions....Ch. 21 - Prob. 21.46SPCh. 21 - Prob. 21.47SPCh. 21 - Prob. 21.48SPCh. 21 - Propose mechanisms for the following reactions.Ch. 21 - Prob. 21.51SPCh. 21 - An ether extraction of nutmeg gives large...Ch. 21 - Prob. 21.53SPCh. 21 - Show how you would accomplish the following...Ch. 21 - Prob. 21.55SPCh. 21 - Prob. 21.56SPCh. 21 - Prob. 21.57SPCh. 21 - Prob. 21.58SPCh. 21 - Prob. 21.59SPCh. 21 - Explain this curious result. What does this...Ch. 21 - Prob. 21.61SPCh. 21 - Prob. 21.62SPCh. 21 - Prob. 21.63SPCh. 21 - A chemist was called to an abandoned aspirin...Ch. 21 - Prob. 21.67SPCh. 21 - The IR spectrum, 13ONTVTR spectrum, and 1HNMR...Ch. 21 - Prob. 21.69SPCh. 21 - Prob. 21.70SPCh. 21 - Prob. 21.71SP
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Text book image
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning