Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 21, Problem 9QP
What process gives rise to the aurora borealis and aurora australis?
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 21 Solutions
Chemistry
Ch. 21.1 - Practice Problem ATTEMPT Calculate the wavelength...Ch. 21.1 - Practice Problem BUILD Which of the following...Ch. 21.1 - Prob. 1PPCCh. 21.1 - Prob. 1CPCh. 21.1 - Prob. 2CPCh. 21.2 - Practice Problem ATTEMPT which of the following is...Ch. 21.2 - Practice Problem BUILD Both O 2 and O 3 exhibit...Ch. 21.2 - Prob. 1PPCCh. 21.2 - 21.2.1 What maximum wavelength (in nm) of fight is...Ch. 21.2 - What process gives rise to the aurora borealis and...
Ch. 21.3 - Prob. 1PPACh. 21.3 - Practice Problem BUILD How long will it take for...Ch. 21.3 - Prob. 1PPCCh. 21.8 - Prob. 1CPCh. 21.8 - Prob. 2CPCh. 21 - Prob. 1QPCh. 21 - Prob. 2QPCh. 21 - Prob. 3QPCh. 21 - Prob. 4QPCh. 21 - Referring to Table 21.1, calculate the mole...Ch. 21 - Prob. 6QPCh. 21 - Prob. 7QPCh. 21 - Calculate the mass (in kg) of nitrogen, oxygen,...Ch. 21 - 21.9 What process gives rise to the aurora...Ch. 21 - Prob. 10QPCh. 21 - The highly reactive OH radical (a species with an...Ch. 21 - The green color observed in the aurora borealis is...Ch. 21 - Prob. 13QPCh. 21 - Prob. 14QPCh. 21 - Prob. 15QPCh. 21 - Prob. 16QPCh. 21 - What causes the polar ozone holes?Ch. 21 - How do volcanic eruptions contribute to ozone...Ch. 21 - Prob. 19QPCh. 21 - Discuss the effectiveness of some of the CFC...Ch. 21 - Prob. 21QPCh. 21 - Prob. 22QPCh. 21 - Prob. 23QPCh. 21 - Prob. 24QPCh. 21 - Prob. 25QPCh. 21 - Prob. 26QPCh. 21 - Prob. 27QPCh. 21 - Prob. 28QPCh. 21 - Prob. 29QPCh. 21 - Prob. 30QPCh. 21 - Prob. 31QPCh. 21 - Prob. 32QPCh. 21 - Describe three human activities that generate...Ch. 21 - Prob. 34QPCh. 21 - Prob. 35QPCh. 21 - Prob. 36QPCh. 21 - What effects do CFCs and their substitutes have on...Ch. 21 - Why are CFCs more effective greenhouse gases than...Ch. 21 - Prob. 39QPCh. 21 - Calcium oxide or quicklime ( CaO ) is used in...Ch. 21 - Prob. 41QPCh. 21 - 21.42 List three detrimental effects of acid...Ch. 21 - 21.43 Briefly discuss two industrial processes...Ch. 21 - Discuss ways to curb acid rain.Ch. 21 - Prob. 45QPCh. 21 - Prob. 46QPCh. 21 - Prob. 47QPCh. 21 - Identify the gas that is responsible for the brown...Ch. 21 - 21.49 The safety limits of ozone and carbon...Ch. 21 - Prob. 50QPCh. 21 - Prob. 51QPCh. 21 - 21.52 The gas-phase decomposition of peroxyacetyl...Ch. 21 - 21.53 On a smoggy day in a certain city. the ozone...Ch. 21 - Prob. 54QPCh. 21 - What is the best way to deal with indoor...Ch. 21 - Why is it dangerous to idle a car's engine in a...Ch. 21 - Prob. 57QPCh. 21 - Prob. 58QPCh. 21 - Prob. 59QPCh. 21 - Prob. 60APCh. 21 - Prob. 61APCh. 21 - Prob. 62APCh. 21 - Prob. 63APCh. 21 - Prob. 64APCh. 21 - 21.65 How are past temperatures determined from...Ch. 21 - The balance between SO 2 and SO 3 is important in...Ch. 21 - Prob. 67APCh. 21 - 21.68 A glass of water initially at pH 7.0 is...Ch. 21 - Prob. 69APCh. 21 - 21.70 Instead of monitoring carbon dioxide,...Ch. 21 - Describe the removal of SO 2 by CaO (to form CaSO...Ch. 21 - 21.72 Which of the following settings is the most...Ch. 21 - Prob. 73APCh. 21 - Peroxyacetyl nitrate (PAN) undergoes thermal...Ch. 21 - Prob. 75APCh. 21 - Prob. 76APCh. 21 - 21.77 The carbon dioxide level in the atmosphere...Ch. 21 - Prob. 78APCh. 21 - Prob. 79APCh. 21 - 21.80 A person was found dead of carbon monoxide...Ch. 21 - Prob. 81APCh. 21 - Prob. 82APCh. 21 - The molar heat capacity of a diatomic molecule is...Ch. 21 - Prob. 84APCh. 21 - Prob. 85APCh. 21 - Prob. 86APCh. 21 - Prob. 1SEPPCh. 21 - Prob. 2SEPPCh. 21 - Prob. 3SEPPCh. 21 - Prob. 4SEPP
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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