Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Textbook Question
Chapter 21, Problem 43QP
Briefly discuss two industrial processes that lead to acid rain.
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Part 1. Draw monomer units of the following products and draw their reaction mechanism
1) Bakelite like polymer
Using: Resorcinol + NaOH + Formalin
2) Polyester fiber
Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol
B)pthalic anhydride + anhydrous sodium acetate + glycerol
3) Temporary cross-linked polymer
Using: 4% polyvinyl alcohol+ methyl red + 4% sodium borate
Using the table of Reactants and Products provided provide the correct letter that
corresponds with the Carboxylic acid that is formed in the reaction below.
6 M NaOH
Acid-workup
WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR
PHRASES
A)
Pool of Reagents for Part B
CI
B)
OH
C)
E)
CI
J)
racemic
F)
K)
OH
N)
OH
P)
G)
OH
D)
HO
H)
L)
M)
HO
Q)
R)
CI
A
In the table below, the exact chemical structures for Methyl salicylate can be
represented by the letter
WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR
PHRASES
CI
B)
A)
E)
Cl
racemic
F)
J)
CI
K)
N)
OH
P)
Pool of Reagents for Part B
OH
OH
G)
L)
OH
D)
HO
H)
M)
HO
Q)
R)
CI
Chapter 21 Solutions
Chemistry
Ch. 21.1 - Practice Problem ATTEMPT Calculate the wavelength...Ch. 21.1 - Practice Problem BUILD Which of the following...Ch. 21.1 - Prob. 1PPCCh. 21.1 - Prob. 1CPCh. 21.1 - Prob. 2CPCh. 21.2 - Practice Problem ATTEMPT which of the following is...Ch. 21.2 - Practice Problem BUILD Both O 2 and O 3 exhibit...Ch. 21.2 - Prob. 1PPCCh. 21.2 - 21.2.1 What maximum wavelength (in nm) of fight is...Ch. 21.2 - What process gives rise to the aurora borealis and...
Ch. 21.3 - Prob. 1PPACh. 21.3 - Practice Problem BUILD How long will it take for...Ch. 21.3 - Prob. 1PPCCh. 21.8 - Prob. 1CPCh. 21.8 - Prob. 2CPCh. 21 - Prob. 1QPCh. 21 - Prob. 2QPCh. 21 - Prob. 3QPCh. 21 - Prob. 4QPCh. 21 - Referring to Table 21.1, calculate the mole...Ch. 21 - Prob. 6QPCh. 21 - Prob. 7QPCh. 21 - Calculate the mass (in kg) of nitrogen, oxygen,...Ch. 21 - 21.9 What process gives rise to the aurora...Ch. 21 - Prob. 10QPCh. 21 - The highly reactive OH radical (a species with an...Ch. 21 - The green color observed in the aurora borealis is...Ch. 21 - Prob. 13QPCh. 21 - Prob. 14QPCh. 21 - Prob. 15QPCh. 21 - Prob. 16QPCh. 21 - What causes the polar ozone holes?Ch. 21 - How do volcanic eruptions contribute to ozone...Ch. 21 - Prob. 19QPCh. 21 - Discuss the effectiveness of some of the CFC...Ch. 21 - Prob. 21QPCh. 21 - Prob. 22QPCh. 21 - Prob. 23QPCh. 21 - Prob. 24QPCh. 21 - Prob. 25QPCh. 21 - Prob. 26QPCh. 21 - Prob. 27QPCh. 21 - Prob. 28QPCh. 21 - Prob. 29QPCh. 21 - Prob. 30QPCh. 21 - Prob. 31QPCh. 21 - Prob. 32QPCh. 21 - Describe three human activities that generate...Ch. 21 - Prob. 34QPCh. 21 - Prob. 35QPCh. 21 - Prob. 36QPCh. 21 - What effects do CFCs and their substitutes have on...Ch. 21 - Why are CFCs more effective greenhouse gases than...Ch. 21 - Prob. 39QPCh. 21 - Calcium oxide or quicklime ( CaO ) is used in...Ch. 21 - Prob. 41QPCh. 21 - 21.42 List three detrimental effects of acid...Ch. 21 - 21.43 Briefly discuss two industrial processes...Ch. 21 - Discuss ways to curb acid rain.Ch. 21 - Prob. 45QPCh. 21 - Prob. 46QPCh. 21 - Prob. 47QPCh. 21 - Identify the gas that is responsible for the brown...Ch. 21 - 21.49 The safety limits of ozone and carbon...Ch. 21 - Prob. 50QPCh. 21 - Prob. 51QPCh. 21 - 21.52 The gas-phase decomposition of peroxyacetyl...Ch. 21 - 21.53 On a smoggy day in a certain city. the ozone...Ch. 21 - Prob. 54QPCh. 21 - What is the best way to deal with indoor...Ch. 21 - Why is it dangerous to idle a car's engine in a...Ch. 21 - Prob. 57QPCh. 21 - Prob. 58QPCh. 21 - Prob. 59QPCh. 21 - Prob. 60APCh. 21 - Prob. 61APCh. 21 - Prob. 62APCh. 21 - Prob. 63APCh. 21 - Prob. 64APCh. 21 - 21.65 How are past temperatures determined from...Ch. 21 - The balance between SO 2 and SO 3 is important in...Ch. 21 - Prob. 67APCh. 21 - 21.68 A glass of water initially at pH 7.0 is...Ch. 21 - Prob. 69APCh. 21 - 21.70 Instead of monitoring carbon dioxide,...Ch. 21 - Describe the removal of SO 2 by CaO (to form CaSO...Ch. 21 - 21.72 Which of the following settings is the most...Ch. 21 - Prob. 73APCh. 21 - Peroxyacetyl nitrate (PAN) undergoes thermal...Ch. 21 - Prob. 75APCh. 21 - Prob. 76APCh. 21 - 21.77 The carbon dioxide level in the atmosphere...Ch. 21 - Prob. 78APCh. 21 - Prob. 79APCh. 21 - 21.80 A person was found dead of carbon monoxide...Ch. 21 - Prob. 81APCh. 21 - Prob. 82APCh. 21 - The molar heat capacity of a diatomic molecule is...Ch. 21 - Prob. 84APCh. 21 - Prob. 85APCh. 21 - Prob. 86APCh. 21 - Prob. 1SEPPCh. 21 - Prob. 2SEPPCh. 21 - Prob. 3SEPPCh. 21 - Prob. 4SEPP
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- Draw the stepwise mechanism for the reactionsarrow_forwardPart I. a) Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone (3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forward3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below: Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life). 2 CH3 H NO2 NO2 3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s) H a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.arrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
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