Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Question
Chapter 21, Problem 16QP
Interpretation Introduction
Interpretation:
The way in which
Concept introduction:
The layer of the earth above the troposphere is termed as the stratosphere.
When the number of hydrogen atomsis more in CFCs, it is more susceptible to oxidation.
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Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
Chapter 21 Solutions
Chemistry
Ch. 21.1 - Practice Problem ATTEMPT Calculate the wavelength...Ch. 21.1 - Practice Problem BUILD Which of the following...Ch. 21.1 - Prob. 1PPCCh. 21.1 - Prob. 1CPCh. 21.1 - Prob. 2CPCh. 21.2 - Practice Problem ATTEMPT which of the following is...Ch. 21.2 - Practice Problem BUILD Both O 2 and O 3 exhibit...Ch. 21.2 - Prob. 1PPCCh. 21.2 - 21.2.1 What maximum wavelength (in nm) of fight is...Ch. 21.2 - What process gives rise to the aurora borealis and...
Ch. 21.3 - Prob. 1PPACh. 21.3 - Practice Problem BUILD How long will it take for...Ch. 21.3 - Prob. 1PPCCh. 21.8 - Prob. 1CPCh. 21.8 - Prob. 2CPCh. 21 - Prob. 1QPCh. 21 - Prob. 2QPCh. 21 - Prob. 3QPCh. 21 - Prob. 4QPCh. 21 - Referring to Table 21.1, calculate the mole...Ch. 21 - Prob. 6QPCh. 21 - Prob. 7QPCh. 21 - Calculate the mass (in kg) of nitrogen, oxygen,...Ch. 21 - 21.9 What process gives rise to the aurora...Ch. 21 - Prob. 10QPCh. 21 - The highly reactive OH radical (a species with an...Ch. 21 - The green color observed in the aurora borealis is...Ch. 21 - Prob. 13QPCh. 21 - Prob. 14QPCh. 21 - Prob. 15QPCh. 21 - Prob. 16QPCh. 21 - What causes the polar ozone holes?Ch. 21 - How do volcanic eruptions contribute to ozone...Ch. 21 - Prob. 19QPCh. 21 - Discuss the effectiveness of some of the CFC...Ch. 21 - Prob. 21QPCh. 21 - Prob. 22QPCh. 21 - Prob. 23QPCh. 21 - Prob. 24QPCh. 21 - Prob. 25QPCh. 21 - Prob. 26QPCh. 21 - Prob. 27QPCh. 21 - Prob. 28QPCh. 21 - Prob. 29QPCh. 21 - Prob. 30QPCh. 21 - Prob. 31QPCh. 21 - Prob. 32QPCh. 21 - Describe three human activities that generate...Ch. 21 - Prob. 34QPCh. 21 - Prob. 35QPCh. 21 - Prob. 36QPCh. 21 - What effects do CFCs and their substitutes have on...Ch. 21 - Why are CFCs more effective greenhouse gases than...Ch. 21 - Prob. 39QPCh. 21 - Calcium oxide or quicklime ( CaO ) is used in...Ch. 21 - Prob. 41QPCh. 21 - 21.42 List three detrimental effects of acid...Ch. 21 - 21.43 Briefly discuss two industrial processes...Ch. 21 - Discuss ways to curb acid rain.Ch. 21 - Prob. 45QPCh. 21 - Prob. 46QPCh. 21 - Prob. 47QPCh. 21 - Identify the gas that is responsible for the brown...Ch. 21 - 21.49 The safety limits of ozone and carbon...Ch. 21 - Prob. 50QPCh. 21 - Prob. 51QPCh. 21 - 21.52 The gas-phase decomposition of peroxyacetyl...Ch. 21 - 21.53 On a smoggy day in a certain city. the ozone...Ch. 21 - Prob. 54QPCh. 21 - What is the best way to deal with indoor...Ch. 21 - Why is it dangerous to idle a car's engine in a...Ch. 21 - Prob. 57QPCh. 21 - Prob. 58QPCh. 21 - Prob. 59QPCh. 21 - Prob. 60APCh. 21 - Prob. 61APCh. 21 - Prob. 62APCh. 21 - Prob. 63APCh. 21 - Prob. 64APCh. 21 - 21.65 How are past temperatures determined from...Ch. 21 - The balance between SO 2 and SO 3 is important in...Ch. 21 - Prob. 67APCh. 21 - 21.68 A glass of water initially at pH 7.0 is...Ch. 21 - Prob. 69APCh. 21 - 21.70 Instead of monitoring carbon dioxide,...Ch. 21 - Describe the removal of SO 2 by CaO (to form CaSO...Ch. 21 - 21.72 Which of the following settings is the most...Ch. 21 - Prob. 73APCh. 21 - Peroxyacetyl nitrate (PAN) undergoes thermal...Ch. 21 - Prob. 75APCh. 21 - Prob. 76APCh. 21 - 21.77 The carbon dioxide level in the atmosphere...Ch. 21 - Prob. 78APCh. 21 - Prob. 79APCh. 21 - 21.80 A person was found dead of carbon monoxide...Ch. 21 - Prob. 81APCh. 21 - Prob. 82APCh. 21 - The molar heat capacity of a diatomic molecule is...Ch. 21 - Prob. 84APCh. 21 - Prob. 85APCh. 21 - Prob. 86APCh. 21 - Prob. 1SEPPCh. 21 - Prob. 2SEPPCh. 21 - Prob. 3SEPPCh. 21 - Prob. 4SEPP
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